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In this paper we analyze the band-structure of two-dimensional (2D) halide perovskites by considering structures related to the simpler case of the series, (BA)$_2$PbI$_4$, in which PbI$_4$ layers are intercalated with butylammonium…

材料科学 · 物理学 2023-07-24 Efstratios Manousakis

The electronic structure and energetic stability of A$_2$BX$_6$ halide compounds with the cubic and tetragonal variants of the perovskite-derived K$_2$PtCl$_6$ prototype structure are investigated computationally within the frameworks of…

Density functional theory (DFT) calculations are performed to predict the structural, electronic and magnetic properties of electrically neutral or charged few-atomic-layer (AL) oxides whose parent systems are based on polar perovskite…

In this work, density functional theory (DFT) is used to find out the ground state structures of A2AuScX6 (A= Cs, Rb; X= Cl, Br, I) double Perovskite (DP) halides for the first time. The DP A2AuScX6 halides were studied for their structural…

材料科学 · 物理学 2023-10-03 S. Mahmud , M. A. Ali , M. M. Hossain , M. M. Uddin

The outstanding optoelectronics and photovoltaic properties of metal halide perovskites, including high carrier motilities, low carrier recombination rates, and the tunable spectral absorption range are attributed to the unique electronic…

材料科学 · 物理学 2020-08-14 Shuxia Tao , Xi Cao , Peter Bobbert

This paper presents the phase stability, opto-electronic and thermo-electric behavior of X2AuYZ6 (X = Cs, Rb; Z = Cl/Br/I) double perovskite halides by using the DFT method. The compounds belong to the cubic arrangement and are verified by…

材料科学 · 物理学 2024-04-25 S. Mahmud , M. A. Ali , M. M. Hossain , M. M. Uddin

Chalcogenide perovskites have emerged as non-toxic and stable photovoltaic materials, acting as an alternative to lead halide hybrid perovskites having similar optoelectronic properties. In the present work, we report the electronic and…

材料科学 · 物理学 2021-06-03 Manish Kumar , Arunima Singh , Deepika Gill , Saswata Bhattacharya

The excellent optoelectronic properties, straightforward synthesis, and robust material stability of quasi-2D metal halide perovskites have made them a hot research topic for optoelectronic devices. In layered organic-inorganic perovskites,…

材料科学 · 物理学 2025-10-31 Brindhu Malani S , Eugen Klein , Rostyslav Lesyuk , Christian Klinke

Organic-inorganic halide perovskite solar cells have recently attracted much attention due to their low-cost fabrication, flexibility, and high-power conversion efficiency. The reduction from three- to two-dimension (2D) promises an…

材料科学 · 物理学 2018-07-24 Rahul Singh , Prashant Singh , Ganesh Balasubramanian

The structural, electrical, optical, and mechanical characteristics of the lead-free halide double perovskites Cs2NaTlX6 X = F, Cl, Br are calculated by utilizing PBE functional within generalized gradient approximation GGA under the…

材料科学 · 物理学 2023-02-07 Mohammed Mehedi Hasan , Nazmul Hasan , Alamgir Kabir

2D Ruddlesden Popper perovskites have been extensively studied for their exceptional optical and electronic characteristics while only a few studies have shed light on their mechanical properties. The existing literature mainly discusses…

应用物理 · 物理学 2021-06-10 Yashika Gupta , Sudharm Rathore , Aparna Singh , Anshuman Kumar

We present a computational investigation, in conjunction with synthesis and experimental characterization, into the structural, electronic, and optical properties of layered 2D organic lead bromide perovskites. We contrast materials based…

材料科学 · 物理学 2025-10-29 Md Mehdi Masud , Jarek Viera , Azza Ben-Akacha , Biwu Ma , David A. Strubbe

In the present work, we study the structural, electronic and optical properties of Sodium Based Cubic Fluoro-perovskites: NaBF$_3$ (B= Ca, Mg or Zn) using DFT and TDDFT methods. We performed the density functional theory DFT calculations…

材料科学 · 物理学 2024-08-20 S. Idrissi , A. Jabar , H. Labrim , L. Bahmad , S. Benyoussef

Ruddlesden-Popper hybrid halide perovskite are quasi-two-dimensional materials with a layered structure and structural dynamics that are determined by the interplay between the organic and inorganic layers. While their optical properties…

The great tunability of the properties of halide perovskites presents new opportunities for optoelectronic applications as well as significant challenges associated with exploring combinatorial chemical spaces. In this work, we develop a…

材料科学 · 物理学 2021-09-23 Arun Mannodi-Kanakkithodi , Maria K. Y. Chan

In this study, we investigate the structural properties, chemical stability, and electronic, optical, and thermoelectric properties of $\mathrm{Sr_2PrSbO_6}$ using first-principles calculations based on Density Functional Theory (DFT). The…

材料科学 · 物理学 2025-10-22 Md. Mohiuddin , Alamgir Kabir

Density Functional Tight-Binding (DFTB), an approximative approach derived from Density Functional Theory (DFT), has the potential to pave the way for simulations of large periodic or non-periodic systems. We have specifically tailored DFTB…

Metal halide perovskite semiconductors have outstanding optoelectronic properties. Although these perovskites are defect-tolerant electronically, defects hamper their long-term stability and cause degradation. Density functional theory…

材料科学 · 物理学 2021-09-02 Haibo Xue , Geert Brocks , Shuxia Tao

Novel halide perovskites with improved stability and optoelectronic properties can be designed via composition engineering at cation and/or anion sites. Data-driven methods, especially high-throughput first principles computations and…

材料科学 · 物理学 2023-02-13 Jiaqi Yang , Panayotis Manganaris , Arun Mannodi-Kanakkithodi

Materials with low work functions are critical for an array of applications requiring the facile removal or efficient transport of electrons through a device. Perovskite oxides are a promising class of materials for finding low work…

材料科学 · 物理学 2021-09-07 Tianyu Ma , Ryan Jacobs , John Booske , Dane Morgan
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