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A new axiomatic characterization with a minimum of conditions for entropy as a function on the set of states in quantum mechanics is presented. Traditionally unspoken assumptions are unveiled and replaced by proven consequences of the…

数学物理 · 物理学 2014-07-02 Bernhard Baumgartner

In classical phenomenological thermodynamics the first and second laws can be regarded as independent statements. Statistical mechanics provides a microscopic substratum that explains thermodynamics in probabilistic terms via a microstate…

统计力学 · 物理学 2007-05-23 A. Plastino , E. M. F. Curado

We demonstrate that Shannon's information entropy and the thermodynamic entropy of Boltzmann and Gibbs are quantitatively equivalent for real condensed-matter systems. By interpreting atomic configurations as information sources, we compute…

统计力学 · 物理学 2025-12-03 Dallin Fisher , Qi-Jun Hong

The division by N! in the expression of statistical entropy is usually justified to students by the statement that classical particles should be counted as indistinguishable. Sometimes, quantum indistinguishability is invoked to explain it.…

统计力学 · 物理学 2023-05-24 Sergio Di Matteo

In this study, we present a reformulation of classical equilibrium thermodynamics by replacing the obscure and ambiguous concept of entropy with the clear and intuitive concept of information stored in a thermodynamic system. Specifically,…

统计力学 · 物理学 2025-01-15 Faical Barzi , Kaoutar Fethi

The basic notions of statistical mechanics (microstates, multiplicities) are quite simple, but understanding how the second law arises from these ideas requires working with cumbersomely large numbers. To avoid getting bogged down in…

物理教育 · 物理学 2015-02-27 Thomas A. Moore , Daniel V. Schroeder

The entropy production of an open system coupled to a reservoir initialized in a canonical state can be expressed as a sum of two microscopic information-theoretic contributions: the system-bath mutual information and the relative entropy…

统计力学 · 物理学 2023-05-18 Krzysztof Ptaszynski , Massimiliano Esposito

A system composed of identical spins and described by a quantum mechanical pure state is analyzed within the statistical framework presented in Part I of this work. We explicitly derive the typical values of the entropy, of the energy, and…

量子物理 · 物理学 2010-07-22 Barbara Fresch , Giorgio J. Moro

Thermodynamics and information have intricate interrelations. Often thermodynamics is considered to be the logical premise to justify that information is physical - through Landauer's principle -, thereby also linking information and…

Statistical thermodynamics delivers the probability distribution of the equilibrium state of matter through the constrained maximization of a special functional, entropy. Its elegance and enormous success have led to numerous attempts to…

统计力学 · 物理学 2023-06-22 Themis Matsoukas

Fluctuations in biochemical networks, e.g., in a living cell, have a complex origin that precludes a description of such systems in terms of bipartite or multipartite processes, as is usually done in the framework of stochastic and/or…

统计力学 · 物理学 2020-01-29 R. Chétrite , M. L. Rosinberg , T. Sagawa , G. Tarjus

During a spontaneous change, a macroscopic physical system will evolve towards a macro-state with more realizations. This observation is at the basis of the Statistical Mechanical version of the Second Law of Thermodynamics, and it provides…

统计力学 · 物理学 2020-04-22 Mengjie Zu , Arunkumar Bupathy , Daan Frenkel , Srikanth Sastry

An ensemble of classical subsystems interacting with surrounding particles has been considered. In general case, a phase volume of the subsystems ensemble was shown to be a function of time. The evolutional equations of the ensemble are…

统计力学 · 物理学 2015-06-24 S. R. Sharov

In these decades, it has been revealed that there is rich information-theoretic structure in thermodynamics of out-of-equilibrium systems in both the classical and quantum regimes. This has led to the fruitful interplay among statistical…

量子物理 · 物理学 2020-09-29 Takahiro Sagawa

The approach of an ideal gas to equilibrium is simulated through a generalization of the Ehrenfest ball-and-box model. In the present model, the interior of each box is discretized, {\it i.e.}, balls/particles live in cells whose occupation…

统计力学 · 物理学 2009-11-10 S. Prestipino

Stochastic thermodynamics as reviewed here systematically provides a framework for extending the notions of classical thermodynamics like work, heat and entropy production to the level of individual trajectories of well-defined…

统计力学 · 物理学 2015-06-05 Udo Seifert

In the process of analyzing the axiomatic principles underlying statistical physics, when modeling the most probable stationary macrostates of non-ergodic closed systems, a forecast was obtained about a possible limitation purview of the…

统计力学 · 物理学 2022-09-07 Vladimir Savukov

Several approximations are made to study the microcanonical formalism that are valid in the thermodynamics limit. Usually it is assumed that: 1)Stirling approximation can be used to evaluate the number of microstates; 2) the surface entropy…

综合物理 · 物理学 2015-10-07 E. N. Miranda , Dalia S. Bertoldi

Investigation on foundational aspects of quantum statistical mechanics recently entered a renaissance period due to novel intuitions from quantum information theory and to increasing attention on the dynamical aspects of single quantum…

量子物理 · 物理学 2010-07-22 Barbara Fresch , Giorgio J. Moro

New exact results about the nonequilibrium thermodynamics of open quantum systems at arbitrary timescales are obtained by considering all possible variations of initial conditions of a system, its environment, and correlations between them.…

统计力学 · 物理学 2021-05-05 Paul M. Riechers , Mile Gu