相关论文: Improved Lieb-Oxford bound on the indirect and exc…

We prove a new lower bound on the indirect Coulomb energy in quantum mechanics in terms of the single particle density of the system. The new universal lower bound is an alternative to the classical Lieb--Oxford bound (with a smaller…

We prove a Lieb-Oxford-type inequality on the indirect part of the Coulomb energy of a general many-particle quantum state, with a lower constant than the original statement but involving an additional gradient correction. The result is…

The Lieb-Oxford bound, a nontrivial inequality for the indirect part of the many-body Coulomb repulsion in an electronic system, plays an important role in the construction of approximations in density functional theory. Using the…

Universal properties of the Coulomb interaction energy apply to all many-electron systems. Bounds on the exchange-correlation energy, inparticular, are important for the construction of improved density functionals. Here we investigate one…

We investigate and prove Lieb-Oxford bounds in one dimension by studying convex potentials that approximate the ill-defined Coulomb potential. A Lieb-Oxford inequality establishes a bound of the indirect interaction energy for electrons in…

Lieb and Oxford (1981) derived rigorous lower bounds, in the form of local functionals of the electron density, on the indirect part of the Coulomb repulsion energy. The greatest lower bound for a given electron number N depends…

We prove a new lower bound on the indirect Coulomb energy in two dimensional quantum mechanics in terms of the single particle density of the system. The new universal lower bound is an alternative to the Lieb--Solovej--Yngvason bound with…

In the framework of density-functional theory, several popular density functionals for exchange and correlation have been constructed to satisfy a local form of the Lieb-Oxford bound. In its original global expression, the bound represents…

The Lieb-Oxford bound is a constraint upon approximate exchange-correlation functionals. We explore a non-empirical tightening of that bound in both universal and electron-number-dependent form. The test functional is PBE. Regarding both…

Density-functional theory requires ever better exchange-correlation (xc) functionals for the ever more precise description of many-body effects on electronic structure. Universal constraints on the xc energy are important ingredients in the…

Lewin and Lieb have recently proven several new bounds on the exchange-correlation energy that complement the Lieb-Oxford bound. We test these bounds for atoms, for slowly-varying gases, and for Hooke's atom, finding them usually less…

We review and illustrate with several examples the connection between the search for lower bounds for the optimal constant in the Lieb-Oxford inequality and the optimal transport limit (or strictly-correlated-electrons limit) of density…

We study the energetic properties of finite but internally homogeneous D-dimensional electron droplets in the strict-correlation limit. The indirect Coulomb interaction is found to increase as a function of the electron number, approaching…

We propose a simple gradient-dependent bound for the exchange-correlation energy (sLL), based on the recent non-local bound derived by Lewin and Lieb. We show that sLL is equivalent to the original Lieb-Oxford bound in rapidly-varying…

A simple and completely general representation of the exact exchange-correlation functional of density-functional theory is derived from the universal Lieb-Oxford bound, which holds for any Coulomb-interacting system. This representation…

Recently, Gilmer proved the first constant lower bound for the union-closed sets conjecture via an information-theoretic argument. The heart of the argument is an entropic inequality involving the OR function of two i.i.d.\ binary vectors,…

We consider an analogue of the Lieb-Thirring inequality for quantum systems with homogeneous repulsive interaction potentials, but without the antisymmetry assumption on the wave functions. We show that in the strong-coupling limit, the…

We discuss the Lieb-Thirring inequality for periodic systems, which has the same optimal constant as the original inequality for finite systems. This allows us to formulate a new conjecture about the value of its best constant. To…

We prove an upper bound on the excess charge for non-relativistic atomic systems, independent of the particle statistics. This result improves Lieb's bound of 1984 for any $Z \ge 12$.

The effect of long-ranged Coulomb interaction on the low energy properties (momentum distribution function, density of states, electron spectral function, and $4k_F$ correlation function) of one-dimensional electron systems is determined…