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Alkali metal intercalation of graphene layers has been of particular interest due to potential applications in electronics, energy storage, and catalysis. Rubidium (Rb) is one of the largest alkali metals and the one less investigated as…

Graphene - a monolayer of carbon atoms densely packed into a hexagonal lattice - has one of the strongest possible atomic bonds and can be viewed as a robust atomic-scale scaffold, to which other chemical species can be attached without…

Angle resolved photoelectron spectroscopy (ARPES) is extensively used to characterize the dependence of the electronic structure of graphene on Ir(111) on the preparation process. ARPES findings reveal that temperature programmed growth…

材料科学 · 物理学 2011-08-10 M. Kralj , I. Pletikosic , M. Petrovic , P. Pervan , M. Milun , A. T. N'Diaye , C. Busse , T. Michely , J. Fujii , I. Vobornik

Graphene nanoelectronics potential was limited by the lack of an intrinsic bandgap[1] and attempts to tailor a bandgap either by quantum confinement or by chemical functionalization failed to produce a semiconductor with a large enough band…

After the pioneering investigations into graphene-based electronics at Georgia Tech (GT), great strides have been made developing epitaxial graphene on silicon carbide (EG) as a new electronic material. EG has not only demonstrated its…

We have performed electron energy-loss spectroscopy (EELS) studies of Ni(111), graphene/Ni(111), and the graphene/Au/Ni(111) intercalation-like system at different primary electron energies. A reduced parabolic dispersion of the \pi plasmon…

材料科学 · 物理学 2011-09-13 A. V. Generalov , Yu. S. Dedkov

Making devices with graphene necessarily involves making contacts with metals. We use density functional theory to study how graphene is doped by adsorption on metal substrates and find that weak bonding on Al, Ag, Cu, Au and Pt, while…

材料科学 · 物理学 2009-11-13 G. Giovannetti , P. A. Khomyakov , G. Brocks , V. M. Karpan , J. van den Brink , P. J. Kelly

It has been shown that the first C layer on the SiC(0001)(2{\times}2)C surface already exhibits graphene-like electronic structure, with linear pi bands near the Dirac point. Indeed, the (2{\times}2)C reconstruction, with a Si adatom and C…

介观与纳米尺度物理 · 物理学 2015-05-27 F. Hiebel , P. Mallet , J. -Y. Veuillen , L. Magaud

It is demonstrated that the electric dipole layer due to the overlapping of electron wavefunctions at metal/graphene contact results in negative Fermi-level pinning effect on the region of GaAs surface with low interface-trap density in…

介观与纳米尺度物理 · 物理学 2022-08-18 Hoon Hahn Yoon , Wonho Song , Sungchul Jung , Junhyung Kim , Kyuhyung Mo , Gahyun Choi , Hu Young Jeong , Jong Hoon Lee , Kibog Park

Man-made artificial graphene has attracted significant attention in the past few years due to the possibilities to construct designer Dirac fermions with unexpected topological properties and applications in nanoelectronics. Here we use a…

材料科学 · 物理学 2014-12-10 Matti Ropo , Sami Paavilainen , Jaakko Akola , Esa Räsänen

The nucleation of graphene on a transition metal (TM) surface, either on a terrace or near a step edge, is systematically explored using density functional theory (DFT) calculations and applying the two-dimensional (2D) crystal nucleation…

材料科学 · 物理学 2011-04-04 Junfeng Gao , Joanne Yip , Jijun Zhao , Boris I. Yakobson , Feng Ding

Confinement epitaxy beneath graphene stabilizes exotic material phases by restricting vertical growth and altering lateral diffusion, conditions unattainable on bare substrates. However, achieving long-range interfacial order while…

介观与纳米尺度物理 · 物理学 2026-02-19 Zamin Mamiyev , Niclas Tilgner , Narmina O. Balayeva , Dietrich R. T. Zahn , Thomas Seyller , Christoph Tegenkamp

Ab initio calculations are performed to study consecutive reconstruction of a zigzag graphene edge. According to the obtained energy profile along the reaction pathway, the first reconstruction step, formation of the first pentagon-heptagon…

介观与纳米尺度物理 · 物理学 2022-11-07 Yulia G. Polynskaya , Irina V. Lebedeva , Andrey A. Knizhnik , Andrey M. Popov

When epitaxial graphene layers are formed on SiC(0001), the first carbon layer (known as the "buffer layer"), while relatively easy to synthesize, does not have the desirable electrical properties of graphene. The conductivity is poor due…

材料科学 · 物理学 2015-05-18 S. Oida , F. R. McFeely , J. B. Hannon , R. M. Tromp , M. Copel , Z. Chen , Y. Sun , D. B. Farmer , J. Yurkas

The decay dynamics of excited carriers in graphene have attracted wide scientific attention, as the gapless Dirac electronic band structure opens up relaxation channels that are not allowed in conventional materials. We report…

介观与纳米尺度物理 · 物理学 2021-06-09 Laura Kim , Seyoon Kim , Pankaj K. Jha , Victor W. Brar , Harry A. Atwater

Understanding the coupling of graphene with its local environment is critical to be able to integrate it in tomorrow's electronic devices. Here we show how the presence of a metallic substrate affects the properties of an atomically…

介观与纳米尺度物理 · 物理学 2015-05-27 M. M. Ugeda , D. Fernández-Torre , I. Brihuega , P. Pou , A. J. Martínez-Galera , R. Pérez , J. M. Gómez-Rodríguez

Using atomic resolved scanning tunneling microscopy, we present here the experimental evidence of a silicene sheet (graphene like structure) epitaxially grown on a close-packed silver surface (Ag(111)). This has been achieved via direct…

We address the stability of the surface phases that occur on the C-side of 3C-SiC($\bar{1} \bar{1} \bar{1}$) at the onset of graphene formation. In this growth range, experimental reports reveal a coexistence of several surface phases. This…

材料科学 · 物理学 2015-05-20 Lydia Nemec , Florian Lazarevic , Patrick Rinke , Matthias Scheffler , Volker Blum

Quasi-free standing epitaxial graphene is obtained on SiC(0001) by hydrogen intercalation. The hydrogen moves between the 6root3 reconstructed initial carbon layer and the SiC substrate. The topmost Si atoms which for epitaxial graphene are…

材料科学 · 物理学 2009-12-11 C. Riedl , C. Coletti , T. Iwasaki , A. A. Zakharov , U. Starke

Free-standing exfoliated monolayer graphene is an ultra-thin flexible membrane, which exhibits out of plane deformation or corrugation. In this paper, a technique is described to measure the band structure of such free-standing graphene by…