相关论文: Ab initio Circular Dichroism with the Yambo code: …
The orbital angular momentum (OAM) of electron states is an essential ingredient for topological and quantum geometric quantities in solids. For example, Dirac surface states with helical spin- and orbital-angular momenta are a hallmark of…
Understanding the chirality of molecular reaction pathways is essential for a broad range of fundamental and applied sciences. However, the current ability to probe chirality on the time scale of chemical reactions remains very limited.…
Photoelectron circular dichroism (PECD) is a fascinating phenomenon both from a fundamental science aspect but also due to its emerging role as a highly sensitive analytic tool for chiral recognition in the gas phase. PECD has been studied…
We introduce meta-diastereomers, hybrid systems where molecular chirality ($\leq 10$\,nm) and nanoscale chirality ($>100$\,nm) combine to create a new hierarchical chiral state with emergent optical properties. By coupling chiral…
The theory of the method of magnetic circular dichroism spectroscopy in reflected light (RMCD) has been developed using a simplified scheme without an analyzer, with the use of an additional mirror in the optical system and with the…
Chiral discrimination of enantiomeric biomolecules is vital in chemistry, biology, and medicine. Conventional methods, relying on circularly polarized light, face weak chiroptical signals and potential photodamage. Despite extensive efforts…
Chiral molecules are widespread in nature, playing a fundamental role in bio-chemical processes and in the origin of life itself. The observation of dynamics in chiral molecules is crucial for the understanding and control of the chiral…
Measuring natural circular dichroism in the X-ray regime to extract stereochemical information from chiral molecules in solution remains a challenge. This is primarily due to technical limitations of the existing synchrotron sources. It…
Chirality, a fundamental concept describing an object cannot superpose with its mirror image, is crucial in optics and photonics and leads to various exotic phenomena, such as circular dichroism, and optical activity. Recent findings reveal…
Cavity ring-down (CRD) spectroscopy represents a direct absorption technique of sample absorption measurement. Instead of measuring the amount of the absorbed light, this technique determines the rate at which light intensity decays inside…
The calculations presented here reveal that an electron probe carrying orbital angular momentum is just a particular case of a wider class of electron beams that can be used to measure electron magnetic circular dichroism (EMCD) with atomic…
We propose a method to realize enantiodiscrimination of chiral molecules based on quantum correlation function in a driven cavity-molecule system, where the chiral molecule is coupled with a quantized cavity field and two classical light…
We study beryllium dihydride (BeH$_2$) and acetylene (C$_2$H$_2$) molecules using real-space diffusion Monte Carlo (DMC) method. The molecules serve as perhaps the simplest prototypes that illustrate the difficulties with biases in the…
Photoelectron circular dichroism (PECD) is a method where randomly oriented chiral molecules are photoionized due to irradiation by circularly-polarized lasers, yielding large chiral signals in the photoelectron momentum distribution.…
We propose a low complexity complex valued Sphere Decoding (CV-SD) algorithm, referred to as Circular Sphere Decoding (CSD) which is applicable to multiple-input multiple-output (MIMO) systems with arbitrary two dimensional (2D)…
All-dielectric metasurfaces can produce structural colors, but the most advantageous design criteria are still being investigated. This work numerically studies how the two-dimensional shape of nanoparticles affects the colorimetric…
The difference in the transmission for left and right circularly polarised light though thin films on substrates in a magnetic field is used to obtain the magnetic circular dichroism of the film. However there are reflections at all the…
Photoelectron circular dichroism in the one-photon detachment of a model methane-like chiral anionic system is studied theoretically by the single center method. The computed chiral asymmetry, characterized by the dichroic parameter…
Spectroscopy is an important tool for probing the properties of materials, chemicals and biological samples. We design a practical transmitter-receiver system that exploits entanglement to achieve a provable quantum advantage over all…
Stereoisomers have the same molecular formula and the same atom connectivity and their existence can be related to the presence of different three-dimensional arrangements. Stereoisomerism is of great importance in many different fields…