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We present an extensive experimental study of mode-I, steady, slow crack dynamics in gelatin gels. Taking advantage of the sensitivity of the elastic stiffness to gel composition and history we confirm and extend the model for fracture of…

软凝聚态物质 · 物理学 2009-11-11 Tristan Baumberger , Christiane Caroli , David Martina

We propose and analyze a mathematical model of the mechanics of gels, consisting of the laws of balance of mass and linear momentum. We consider a gel to be an immiscible and incompressible mixture of a nonlinearly elastic polymer and a…

偏微分方程分析 · 数学 2012-10-17 Brandon Chabaud , Maria-Carme Calderer

We investigate the universality of entanglement kinetics in polymer melts. We compare predictions of a recently developed constitutive equation for disentanglement to molecular dynamics simulations of both united-atom polyethylene and…

软凝聚态物质 · 物理学 2024-07-09 Benjamin E. Dolata , Marco A Galvani Cunha , Thomas O'Connor , Austin Hopkins , Peter D. Olmsted

We introduce a microscopically realistic model of a physical gel and use computer simulations to study its static and dynamic properties at thermal equilibrium. The phase diagram comprises a sol phase, a coexistence region ending at a…

软凝聚态物质 · 物理学 2015-06-25 Pablo I. Hurtado , Ludovic Berthier , Walter Kob

Biomolecular condensates form by phase separation of biological polymers and have important functions in the cell $-$ functions that are inherently connected to their physical properties. A remarkable aspect of such condensates is that…

The asymptotic limit-cycle analysis of mathematical models for oscillating chemical reactions is presented. In this work, after a brief presentation of mathematical preliminaries applied to the biased Van der Pol oscillator, we consider a…

化学物理 · 物理学 2021-05-05 Alain J. Brizard , Samuel M. Berry

We consider a microscopic model of a polymer blend that is prone to phase separation. Permanent crosslinks are introduced between randomly chosen pairs of monomers, drawn from the Deam-Edwards distribution. Thereby, not only density but…

软凝聚态物质 · 物理学 2009-11-11 Christian Wald , Paul M. Goldbart , Annette Zippelius

Boehmite, an aluminum oxide hydroxide $\gamma$-AlO(OH), is broadly used in the form of particulate dispersions in industrial applications, e.g., for the fabrication of ceramics and catalyst supports or as a binder for extrusion processes.…

The experimental control of synergistic chemomechanical dynamics of catalytically active microgels (microreactors) is a key prerequisite for the design of adaptive and biomimetic materials. Here, we report a minimalistic model of…

软凝聚态物质 · 物理学 2023-06-09 Sebastian Milster , Abeer Darwish , Nils Göth , Joachim Dzubiella

Inorganic nanocrystal gels retain distinct properties of individual nanocrystals while offering tunable, network structure-dependent characteristics. We review different mechanisms for assembling gels from colloidal nanocrystals including…

In this study we use non-equilibrium thermodynamics to systematically derive a phase-field model of a polyelectrolyte gel coupled to a hydrodynamic model for a salt solution surrounding the gel. The governing equations for the gel account…

软凝聚态物质 · 物理学 2022-03-02 Giulia L. Celora , Matthew G. Hennessy , Andreas Münch , Barbara Wagner , Sarah L. Waters

Hydrogels have had a profound impact in the fields of tissue engineering, drug delivery, and materials science as a whole. Due to the network architecture of these materials, imbibement with water often results in uniform swelling and…

Diffusion of particles in complex fluids and gels is difficult to describe and often lies beyond the scope of the classical Stokes-Einstein relation. One of the main lines of research over the past few decades has sought to relate…

软凝聚态物质 · 物理学 2025-12-25 Władysław Sokołowski , Huma Jamil , Karol Makuch

Oscillatory Zoning (OZ) is a phenomenon exhibited by many geologically formed crystals. It is characterized by quasi periodic oscillations in the composition of a solid solution, caused by self-organization. We present a new model for OZ.…

材料科学 · 物理学 2009-11-11 Felix Kalischewski , Ihor Lubashevsky , Andreas Heuer

Vortex-based single-beam tweezers have the ability to precisely and selectively move a wide range of objects, including particles, bubbles, droplets, and cells with sizes ranging from the millimeter to micrometer scale. In 2017, Karlsen and…

Realistic models of amorphous ZrO2 are generated in a ``melt-and-quench'' fashion using ab-initio molecular dynamics in a plane-wave pseudopotential formulation of density-functional theory. The structural properties of the resulting…

材料科学 · 物理学 2013-05-29 Xinyuan Zhao , Davide Ceresoli , David Vanderbilt

A plethora of active matter models exist that describe the behavior of self-propelled particles (or swimmers), both with and without hydrodynamics. However, there are few studies that consider shape-anisotropic swimmers and include…

Osmotic pressure is the driving force for the swelling of hydrogels. The hydrogel osmotic pressure can be decomposed into two parts: the mixing part due to polymer-solvent interaction and the elastic part due to polymer chain stretching.…

软凝聚态物质 · 物理学 2025-09-09 Zefan Shao , Qihan Liu

Low-density "equilibrium" gels that consist of a percolated, kinetically arrested network of colloidal particles and are resilient to aging can be fabricated by restricting the number of effective bonds that form between the colloids.…

We present a Lattice-Boltzmann method for simulating self-propelling (active) colloidal particles in two-dimensions. Active particles with symmetric and asymmetric force distribution on its surface are considered. The velocity field…

软凝聚态物质 · 物理学 2009-11-11 Sanoop Ramachandran , P. B. Sunil Kumar , I. Pagonabarraga