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The Stokes-Einstein (SE) relation is commonly regarded as being breakdown in supercooled water. However, this conclusion is drawn upon testing the validities of some variants of the SE relation rather than its original form, and it appears…

软凝聚态物质 · 物理学 2021-11-24 Gan Ren , Yanting Wang

The Stokes-Einstein-Debye (SED) relation is proposed to be breakdown in supercooled liquids by many studies. However, the conclusions are usually drawn by testing some variants of the SED relation rather than its original form. In this…

软凝聚态物质 · 物理学 2024-04-23 Gan Ren

The Stokes-Einstein (SE) relation has been widely applied to quantitatively describe the Brownian motion. Notwithstanding, here we show that even for a simple fluid, the SE relation may not be completely applicable. Namely, although the SE…

统计力学 · 物理学 2021-03-17 Hanqing Zhao , Hong Zhao

The Stokes-Einstein relation for the self-diffusion coefficient of a spherical particle suspended in an incompressible fluid is an asymptotic result in the limit of large Schmidt number, that is, when momentum diffuses much faster than the…

软凝聚态物质 · 物理学 2015-06-17 F. Balboa Usabiaga , X. Xie , R. Delgado-Buscalioni , A. Donev

The Stokes-Einstein relation, relating the diffusion and viscosity coefficients D and eta, is tested in two dimensions. An equilibrium molecular-dynamics simulation was used with a Yukawa pair potential. Regimes are identified where motion…

软凝聚态物质 · 物理学 2009-11-11 Bin Liu , J. Goree

Systems of spherical particles moving in Stokes flow are studied for a different particle internal structure and boundaries, including the Navier-slip model. It is shown that their hydrodynamic interactions are well described by treating…

软凝聚态物质 · 物理学 2015-06-18 Bogdan Cichocki , Maria L. Ekiel-Jezewska , Eligiusz Wajnryb

Molecular Dynamics simulations of high density hard sphere fluids clearly show a breakdown of the Stokes-Einstein equation (SE). This result has been conjectured to be due to the presence of mobile particles, i.e., ones which have the…

材料科学 · 物理学 2009-11-11 Sanat K. Kumar , Grzegorz Szamel , Jack F. Douglas

Hydrodynamic interactions are important for diverse fluids especially those with low Reynold's number such as microbial and particle-laden suspensions, and proteins diffusing in membranes. Unfortunately, while far-field (asymptotic)…

软凝聚态物质 · 物理学 2023-02-10 Noman Hanif Barbhuiya , A. G. Yodh , Chandan K. Mishra

It is demonstrated that self-diffusion and shear viscosity data for the TIP4P/Ice water model reported recently [L. Baran, W. Rzysko and L. MacDowell, J. Chem. Phys. {\bf 158}, 064503 (2023)] obey the microscopic version of the…

统计力学 · 物理学 2023-08-02 Sergay Khrapak , Alexey Khrapak

We show by inherent structure (IS) analysis that the sharp composition dependent breakdown of the Stokes-Einstein relation correlates surprisingly well with an equally sharp non-monotonic variation in the average inherent structure (IS)…

软凝聚态物质 · 物理学 2020-01-29 Shubham Kumar , Sarmistha Sarkar , Biman Bagchi

By confining water in nanopores, so narrow that the liquid cannot freeze, it is possible to explore its properties well below its homogeneous nucleation temperature TH ~ 235 K. In particular, the dynamical parameters of water can be…

The two functional forms, D~1/tau and D~T/tau, are usually adopted as the variants of the Stokes-Einstein relation; where D is the diffusion constant, tau the relaxation time and T the temperature. The self-consistent generalized Langevin…

软凝聚态物质 · 物理学 2023-03-09 Wanmei Zhang , Wenhan Zhang , Gan Ren

In this Research Note the Zwanzig's formulation of the Stokes-Einstein (SE) relation for simple atomistic fluids is re-examined. It is shown that the value of the coefficient in SE relation depends on the ratio of the transverse and…

软凝聚态物质 · 物理学 2020-04-22 Sergey Khrapak

We study the breakdown of the Stokes-Einstein (SE) and Debye-Stokes-Einstein (DSE) relations for translational and rotational motion in a prototypical model of a network-forming liquid, the ST2 model of water. We find that the emergence of…

软凝聚态物质 · 物理学 2009-11-11 Stephen R. Becker , Peter H. Poole , Francis W. Starr

The applicability of stochastic differential equations to thermodynamics is considered and a new form, different from the classical Ito and Stratonovich forms, is introduced. It is shown that the new presentation is more appropriate for the…

统计力学 · 物理学 2015-06-05 R. Tsekov

Water displays breakdown of the Stokes-Einstein relation at low temperatures. We hypothesize that the breakdown is a result of the structural changes and a sharp rise in dynamic heterogeneities that occurs low T upon crossing the Widom…

软凝聚态物质 · 物理学 2007-05-23 Pradeep Kumar

The Stokes-Einstein relation (SER) is one of the most robust and widely employed results from the theory of liquids. Yet sizable deviations can be observed for self-solvation, which cannot be explained by the standard hydrodynamic…

统计力学 · 物理学 2018-06-15 Benoit Charbonneau , Patrick Charbonneau , Grzegorz Szamel

We study the Stokes-Einstein (SE) and the Stokes-Einstein-Debye (SED) relations using molecular dynamics simulations of the extended simple point charge model of water. We find that both the SE and SED relations break down at low…

统计力学 · 物理学 2007-06-01 Marco G. Mazza , Nicolas Giovambattista , H. Eugene Stanley , Francis W. Starr

We investigate the heterogeneity of dynamics, the breakdown of the Stokes-Einstein relation and fragility in a model glass forming liquid, a binary mixture of soft spheres with a harmonic interaction potential, for spatial dimensions from 3…

软凝聚态物质 · 物理学 2021-08-20 Monoj Adhikari , Smarajit Karmakar , Srikanth Sastry

We consider a suspension of active rigid particles (swimmers) in a steady Stokes flow, where particles are distributed according to a stationary ergodic random process, and we study its homogenization in the macroscopic limit. A key point…

偏微分方程分析 · 数学 2023-03-15 Armand Bernou , Mitia Duerinckx , Antoine Gloria
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