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The capacity fade of modern lithium ion batteries is mainly caused by the formation and growth of the solid-electrolyte interphase (SEI). Numerous continuum models support its understanding and mitigation by studying SEI growth during…

化学物理 · 物理学 2020-10-29 Lars von Kolzenberg , Arnulf Latz , Birger Horstmann

Cycle life is critically important in applications of rechargeable batteries, but lifetime prediction is mostly based on empirical trends, rather than mathematical models. In practical lithium-ion batteries, capacity fade occurs over…

化学物理 · 物理学 2012-11-27 Matthew B. Pinson , Martin Z. Bazant

Silicon anodes promise high energy densities of next-generation lithium-ion batteries, but suffer from shorter cycle life. The accelerated capacity fade stems from the repeated fracture and healing of the solid-electrolyte interphase (SEI)…

化学物理 · 物理学 2022-12-01 Lars von Kolzenberg , Arnulf Latz , Birger Horstmann

This work proposes a semi-empirical model for the SEI growth process during the early stages of lithium-ion battery formation cycling and aging. By combining a full-cell model which tracks half-cell equilibrium potentials, a…

材料科学 · 物理学 2023-07-25 Andrew Weng , Everardo Olide , Iaroslav Kovalchuk , Jason B. Siegel , Anna Stefanopoulou

Parameterisation of coupled degradation mechanisms in lithium-ion batteries is a major challenge. Interactions between the mechanisms depend on usage conditions: C-rate, rest state-of-charge (SoC), depth-of-discharge (DoD) and temperature.…

材料科学 · 物理学 2026-04-13 Ganesh Madabattula

Battery aging is a natural process that contributes to capacity and power fade, resulting in a gradual performance degradation over time and usage. State of Charge (SOC) and State of Health (SOH) monitoring of an aging battery poses a…

系统与控制 · 电气工程与系统科学 2021-06-25 Anirudh Allam , Simona Onori

Continued growth of the solid electrolyte interphase (SEI) is the major reason for capacity fade in modern lithium-ion batteries. This growth is made possible by a yet unidentified transport mechanism that limits the passivating ability of…

化学物理 · 物理学 2018-12-12 Fabian Single , Arnulf Latz , Birger Horstmann

Capacity and coulombic efficiency are often used to assess the performance of Li-ion batteries, under the assumption that these quantities can provide direct insights about the rate of electron consumption due to growth of the solid…

化学物理 · 物理学 2022-11-11 Marco-Tulio Fonseca Rodrigues

Growth of the solid electrolyte interphase (SEI) is a primary driver of capacity fade in lithium-ion batteries. Despite its importance to this device and intense research interest, the fundamental mechanisms underpinning SEI growth remain…

材料科学 · 物理学 2019-03-06 Peter M. Attia , Supratim Das , Stephen J. Harris , Martin Z. Bazant , William C. Chueh

Electrolyte reduction products form the solid-electrolyte interphase (SEI) on negative electrodes of lithium-ion batteries. Even though this process practically stabilizes the electrode-electrolyte interface, it results in continued…

化学物理 · 物理学 2018-11-22 Birger Horstmann , Fabian Single , Arnulf Latz

The solid-electrolyte interphase (SEI) substantially influences the lifetime of lithium-ion batteries. Nevertheless, the transport mechanism responsible for the long-term growth of the SEI remains controversial. This study aims at…

化学物理 · 物理学 2023-11-09 Lukas Köbbing , Arnulf Latz , Birger Horstmann

Mathematical models of capacity fade can reduce the time and cost of lithium-ion battery development and deployment, and growth of the solid-electrolyte interphase (SEI) is a major source of capacity fade. Experiments in Part I reveal…

化学物理 · 物理学 2019-03-05 Supratim Das , Peter M. Attia , William C. Chueh , Martin Z. Bazant

The structure and growth of the Solid Electrolyte Interphase (SEI) region between an electrolyte and an electrode is one of the most fundamental, yet less-well understood phenomena in solid-state batteries. We present a parameter-free…

材料科学 · 物理学 2024-02-07 Gracie Chaney , Andrey Golov , Ambroise van Roekeghem , Javier Carrasco , Natalio Mingo

Batteries are dynamic systems with complicated nonlinear aging, highly dependent on cell design, chemistry, manufacturing, and operational conditions. Prediction of battery cycle life and estimation of aging states is important to…

系统与控制 · 电气工程与系统科学 2024-10-11 Joachim Schaeffer , Giacomo Galuppini , Jinwook Rhyu , Patrick A. Asinger , Robin Droop , Rolf Findeisen , Richard D. Braatz

Lithium-ion batteries degrade due to usage and exposure to environmental conditions, which affects their capability to store energy and supply power. Accurately predicting the capacity and power fade of lithium-ion battery cells is…

系统与控制 · 电气工程与系统科学 2021-12-28 Weihan Li , Haotian Zhang , Bruis van Vlijmen , Philipp Dechent , Dirk Uwe Sauer

Higher energy density and longer lifetime are the requirements for next-generation lithium-ion batteries. A promising anode material is silicon, which offers high specific capacity, but its significant volume change during lithiation and…

Predicting lithium-ion battery lifetime is one of the greatest unsolved problems in battery research right now. Recent years have witnessed a surge in lifetime prediction papers using physics-based, empirical, or data-driven models, most of…

Degradation prognosis for lithium-ion cells requires forecasting the state-of-health (SOH) trajectory over future cycles. Existing data-driven approaches can produce trajectory outputs through direct regression, but lack a mechanism to…

机器学习 · 计算机科学 2026-03-12 Kai Chin Lim , Khay Wai See

The existence of passivating layers at the interfaces is a major factor enabling modern lithium-ion (Li-ion) batteries. Their properties determine the cycle life, performance, and safety of batteries. A special case is the solid electrolyte…

化学物理 · 物理学 2021-06-07 Zeeshan Ahmad , Victor Venturi , Hasnain Hafiz , Venkatasubramanian Viswanathan

Non-invasive estimation of Li-ion battery state-of-health from operational data is valuable for battery applications, but remains challenging. Pure model-based methods may suffer from inaccuracy and long-term instability of parameter…

系统与控制 · 电气工程与系统科学 2025-07-01 Zihao Zhou , Antti Aitio , David Howey
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