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BiFeO3 (BFO) multiferroic oxide has a complex phase diagram that can be mapped by appropriately substrate-induced strain in epitaxial films. By using Raman spectroscopy, we conclusively show that films of the so-called supertetragonal T-BFO…

材料科学 · 物理学 2011-08-16 J. Kreisel , P. Jadhav , O. Chaix-Pluchery , M. Varela , N. Dix , F. Sanchez , J. Fontcuberta

Temperature-dependent dielectric permittivity of lead-free (LixNa1-x)NbO3 for nominal x = 0.04-0.20, prepared by solid state reaction followed by sintering, was studied to resolve often debated issue pertaining to exactness of morphotropic…

材料科学 · 物理学 2014-01-15 S. Mitra , A. R. Kulkarni , Om. Prakash

We report investigation of structural phase transitions in technologically important material sodium niobate as a function of temperature on heating over 300-1075 K. Our high resolution powder neutron diffraction data show variety of…

材料科学 · 物理学 2015-05-20 S. K. Mishra , R. Mittal , V. Yu. Pomjakushin , S. L. Chaplot

Dielectric permittivity measurements show that (1-x)NaNbO3-(x)Gd1/3NbO3 crystals, at $x=0.09$, exhibit a first order phase transition near 150 C which is diffuse over a wide temperature interval. The area of the \epsilon(T) thermal…

The NaNO$_{2}$ nanocomposite ferroelectric material in porous glass was studied by neutron diffraction. For the first time the details of the crystal structure including positions and anisotropic thermal parameters were determined for the…

In this paper we study the size effects of the ferroelectric nanotube and nanowire phase diagrams and polar properties allowing for radial stress and depolarization field influence. The approximate analytical expression for the…

材料科学 · 物理学 2009-05-09 Anna N. Morozovska , Maya D. Glinchuk , Eugene A. Eliseev

We report the temperature-dependent synchrotron based X-ray diffraction analysis of NASICON type Na$_3$FeCr(PO$_4$)$_3$ sample, which undergoes a symmetry-lowering structural transition from a monoclinic ($C2/c$) phase with long-range…

材料科学 · 物理学 2026-04-15 Madhav Sharma , Archna Sagdeo , Rajendra S. Dhaka

In-plane temperature dependent dielectric behavior of BiFeO3 (BFO) as-grown thin films show diffuse but prominent phase transitions near 450 (+/-10) K and 550 K with dielectric loss temperature dependences that suggest skin layer effects.…

材料科学 · 物理学 2015-06-04 Ashok Kumar , J. F. Scott , R. Martinez , G. Srinivasan , R. S. Katiyar

The structural phase transition in hexagonal BaMnO$_3$ occurring at $T_c$=130 K was studied in ceramic samples using electron and X-ray diffraction, second harmonic generation as well as by dielectric and lattice dynamic spectroscopies. The…

The microstructure and phase transition in relaxor ferroelectric Pb(Mg1/3Nb2/3)O3 (PMN) and its solid solution with PbTiO3 (PT), PMN-xPT, remain to be one of the most puzzling issues of solid state science. In the present work we have…

材料科学 · 物理学 2009-11-07 Z. -G. Ye , Y. Bing , J. Gao , A. A. Bokov , P. Stephens , B. Noheda , G. Shirane

We present molecular dynamics simulations of a realistic model of an ultrathin film of BaTiO$_3$ sandwiched between short-circuited electrodes to determine and understand effects of film thickness, epitaxial strain and the nature of…

材料科学 · 物理学 2009-11-13 Jaita Paul , Takeshi Nishimatsu , Y. Kawazoe , Umesh V. Waghmare

Polycrystalline sample of (Ba_{0.90}Pb_{0.10})(Ti_{0.90}Sn_{0.10})O_3 was obtained by means of a conventional ceramic technology. The dielectric measurements were performed depending on temperature and frequency of electric measuring field.…

材料科学 · 物理学 2013-09-25 C. Kajtoch , W. Bąk , B. Garbarz-Glos

Pure NaNbO$_{3}$ is an antiferroelectric material at room temperature that irreversibly transforms to a ferroelectric polar state when subjected to an external electrical field or lattice strain. Experimentally, it has been observed that…

材料科学 · 物理学 2023-11-28 Kisung Kang , Saud Bin Anooz , Jutta Schwarzkopf , Christian Carbogno

The sol-gel prepared (1-x) Na0.5Bi0.5TiO3- (x) CaMnO3 (x=0, 0.03, 0.06, 0.12) compositions show a Rhombohedral (R3c) phase for x=0.06 while a mixed Rhombohedral (R3c) and orthorhombic (Pnma) phases for the x=0.12. The lattice volume…

We report results of a comprehensive study of the phase transition at T_N (~643 K) as a function of particle size in multiferroic BiFeO3 system. We employed electrical, thermal, and temperature dependent X-ray diffraction (XRD) studies in…

The nonstoichiometric NaxCoO2 system exhibits extraordinary physical properties that correlate with temperature and Na concentration in its layered lattice without evident long-range structure modification when conventional crystallographic…

强关联电子 · 物理学 2009-11-10 H. X. Yang , C. J. Nie , Y. G. Shi , H. C. Yu , S. Ding , Y. L. Liu , D. Wu , N. L. Wang , J. Q. Li

Raman Spectroscopic measurements are carried out to investigate the structural phase transitions as a function of composition in modified sodium niobate [(1-x) NaNbO3-xBaTiO3:NNBTx] for x=0.0 to 0.15 at room temperature. The characteristic…

材料科学 · 物理学 2019-09-04 Mrinal Jauhari , S. K. Mishra , R. Mittal , S. L. Chaplot

We present here the results of frequency dependent dielectric, polarization and powder X-ray powder diffraction studies in the 300 to 100K temperature range for Ba_0.55Sr_0.45TiO_3. The dielectric results indicate a succession of three…

材料科学 · 物理学 2007-09-24 Satyendra Singh , Satendra Pal Singh , Dhananjai Pandey

Controlling the Mott transition through strain engineering is crucial for advancing the development and application of memristive and neuromorphic computing devices. Yet, Mott insulators are heterogeneous due to intrinsic phase boundaries…

Thin films and heterostructures of hexagonal manganites as promising multiferroic materials have attracted a considerable interest recently. We report structural transformations of high quality epitaxial h-TMO/YSZ(111) films, analyzed by…

强关联电子 · 物理学 2020-09-23 R. Mandal , M. Hirsbrunner , V. Roddatis , L. Schüler , U. Roß , S. Merten , V. Moshnyaga