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相关论文: Driving chemical reactions with polariton condensa…

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Polaritons, mixed light-matter quasiparticles, undergo a transition to a condensed, macroscopically coherent state at low temperatures or high densities. Recent experiments show that coupling light to organic molecules inside a microcavity…

量子气体 · 物理学 2014-03-06 Justyna A. Cwik , Sahinur Reja , Peter B. Littlewood , Jonathan Keeling

Collective strong coupling between a disordered ensemble of $N$ localized molecular vibrations and a resonant optical cavity mode gives rise to 2 polariton and $N-1\gg2$ dark modes. Thus, experimental changes in thermally-activated reaction…

量子物理 · 物理学 2022-03-14 Matthew Du , Joel Yuen-Zhou

Vibrational polaritons, hybrid light-matter states formed between molecular vibrations and infrared (IR) cavity modes, provide a novel approach for modifying chemical reaction pathways and energy transfer processes. For vibrational…

化学物理 · 物理学 2025-05-16 Xinwei Ji , Tao E. Li

In the regime of ensemble vibrational strong coupling (VSC), a macroscopic number $N$ of molecular transitions couple to each resonant cavity mode, yielding two hybrid light-matter (polariton) modes, and a reservoir of $N-1$ dark states…

化学物理 · 物理学 2020-04-03 Jorge Campos-Gonzalez-Angulo , Raphael F. Ribeiro , Joel Yuen-Zhou

In this work, we develop an optomechanical formalism for macroscopic quantum states in exciton-polariton systems with strong exciton-phonon interactions. We show that polariton optomechanical interactions induce dynamical backaction,…

量子气体 · 物理学 2024-10-31 Vladislav Yu. Shishkov , Evgeny S. Andrianov , Anton V. Zasedatelev

Molecular polaritons are the optical excitations which emerge when molecular transitions interact strongly with confined electromagnetic fields. Increasing interest in the hybrid molecular-photonic materials that host these excitations…

介观与纳米尺度物理 · 物理学 2018-02-26 Raphael F. Ribeiro , Luis A. Martínez-Martínez , Matthew Du , Jorge Campos-Gonzalez-Angulo , Joel Yuen-Zhou

Strong coupling between excitons and confined modes of light presents a promising pathway to tunable and enhanced energy transport in organic materials. By forming hybrid light-matter quasiparticles, exciton-polaritons, electronic…

化学物理 · 物理学 2024-11-01 Niclas Krupp , Gerrit Groenhof , Oriol Vendrell

Polariton chemistry exploits the strong interaction between quantized excitations in molecules and quantized photon states in optical cavities to affect chemical reactivity. Molecular polaritons have been experimentally realized by the…

化学物理 · 物理学 2023-09-06 Jonathan J. Foley , Jonathan F. McTague , A. Eugene DePrince

We demonstrate a macro-coherent regime in exciton-polariton systems, where nonequilibrium polariton Bose--Einstein condensation coexists with macroscopically occupied vibrational states. Strong exciton-vibration coupling induces an…

Quantum mixtures of moir\'e excitons have arisen as a platform for realizing novel phases of light and matter. Here, we study moir\'e polaritons coupled to a Bose-Einstein condensate of dark-state excitons confined to a moir\'e…

Recent experiments have demonstrated that molecular polaritons, hybrid states of light and matter formed by the strong coupling between molecular electronic or vibrational excitations and an optical cavity, can substantially modify the…

化学物理 · 物理学 2021-07-08 Nguyen Thanh Phuc

We explore nonlinear transitions of polariton wavepackets, first, to a soliton and then to a standing wave polariton condensate in a multi-mode microwire system. At low polariton density we observe ballistic propagation of the multi-mode…

A quantum model of Bose-Einstein condensation based on processes involving polaritons excited in an intracavity absorbing cell with resonance atoms, which is manifested in the spectral characteristics of the system, is considered. It is…

In vibrational strong coupling (VSC), molecular vibrations strongly interact with the modes of an optical cavity to form hybrid light-matter states known as vibrational polaritons. Experiments show that the kinetics of thermally activated…

量子物理 · 物理学 2021-05-04 Matthew Du , Jorge A. Campos-Gonzalez-Angulo , Joel Yuen-Zhou

Condensation of bosons causes spectacular phenomena such as superfluidity or superconductivity. Understanding the nature of the condensed particles is crucial for active control of such quantum phases. Fascinating possibilities emerge from…

We report on polariton condensation in photonic molecules formed by two coupled micropillars. We show that the condensation process is strongly affected by the interaction with the cloud of uncondensed excitons. Depending on the spatial…

For a small fraction of hot CO2 molecules immersed in a liquid-phase CO2 thermal bath, classical cavity molecular dynamics simulations show that forming collective vibrational strong coupling (VSC) between the C=O asymmetric stretch of CO2…

化学物理 · 物理学 2021-05-11 Tao E. Li , Abraham Nitzan , Joseph E. Subotnik

Intramolecular energy transfer driven by near-field effects plays an important role in applications ranging from biophysics and chemistry to nano-optics and quantum communications. Advances in strong light-matter coupling in molecular…

介观与纳米尺度物理 · 物理学 2025-07-14 Kristin B. Arnardottir , Piper Fowler-Wright , Christos Tserkezis , Brendon W. Lovett , Jonathan Keeling

The optical hybridization of the electronic states in strongly coupled molecule-cavity systems have revealed unique properties such as lasing, room temperature polariton condensation, and the modification of excited electronic landscapes…

Polaritonic states arise when a bright optical transition of a molecular ensemble is resonantly matched to an optical cavity mode frequency. Here, we lay the groundwork to study the behavior of polaritons in clean, isolated systems by…

化学物理 · 物理学 2023-10-20 Adam D. Wright , Jane C. Nelson , Marissa L. Weichman
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