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Nonequilibrium steady state of isothermal biochemical cycle kinetics has been extensively studied, but much less investigated under non-isothermal conditions. However, once the heat exchange between subsystems is rather slow, the isothermal…

化学物理 · 物理学 2016-10-11 Xiao Jin , Hao Ge

In this paper a reaction-diffusion type equation is the starting point for setting up a genuine thermodynamic reduction, i.e. involving a finite number of parameters or collective variables, of the initial system. This program is carried…

数学物理 · 物理学 2016-11-17 Franco Cardin , Marco Favretti , Alberto Lovison

A reaction-diffusion equation with power nonlinearity formulated either on the half-line or on the finite interval with nonzero boundary conditions is shown to be locally well-posed in the sense of Hadamard for data in Sobolev spaces. The…

偏微分方程分析 · 数学 2018-10-15 A. Alexandrou Himonas , Dionyssios Mantzavinos , Fangchi Yan

We extend the energetic variational approach so it can be applied to a chemical reaction system with general mass action kinetics. Our approach starts with an energy-dissipation law. We show that the chemical equilibrium is determined by…

化学物理 · 物理学 2021-01-04 Yiwei Wang , Chun Liu , Pei Liu , Bob Eisenberg

Large time dynamics of reaction-diffusion systems modeling some irreversible reaction networks are investigated. Depending on initial masses, these networks possibly possess boundary equilibria, where some of the chemical concentrations are…

偏微分方程分析 · 数学 2024-11-04 Thi Lien Nguyen , Bao Quoc Tang

In this paper, we provide a graphic formulation of non-isothermal reaction systems and show that a non-isothermal detailed balanced network system converges (locally) asymptotically to the unique equilibrium within the invariant manifold…

动力系统 · 数学 2020-10-01 Zhou Fang , Arjan van der Schaft , Chuanhou Gao

A space discrete approximation to a highly nonlinear reaction-diffusion system endowed with a stochastic dynamical boundary condition is analyzed and the convergence of the discrete scheme to the solution to the corresponding continuum…

We set up a rigorous thermodynamic description of reaction-diffusion systems driven out of equilibrium by time-dependent space-distributed chemostats. Building on the assumption of local equilibrium, nonequilibrium thermodynamic potentials…

统计力学 · 物理学 2018-09-12 Gianmaria Falasco , Riccardo Rao , Massimiliano Esposito

We consider solvability of the generalized reaction-diffusion equation with both space- and time-dependent diffusion and reaction terms by means of the similarity method. By introducing the similarity variable, the reaction-diffusion…

数学物理 · 物理学 2016-01-20 C. -L. Ho , C. -C. Lee

We consider a reaction-diffusion system which may serve as a model for a ferment catalytic reaction in chemistry. The model consists of a system of reaction diffusion equations with unbounded time dependent coefficients and different…

偏微分方程分析 · 数学 2022-06-14 Mohamed Majdoub , Nasser-eddine Tatar

In equilibrium systems with short-ranged interactions, the relative stability of different thermodynamic states generally does not depend on system size (as long as this size is larger than the interaction range). Here, we use a large…

统计力学 · 物理学 2013-05-30 Sorin Tanase-Nicola , David K. Lubensky

Motivated by compartmental analysis in engineering and biophysical systems, we present a variational framework for the nonequilibrium thermodynamics of systems involving both distributed and discrete (finite dimensional) subsystems by…

统计力学 · 物理学 2022-04-07 François Gay-Balmaz , Hiroaki Yoshimura

In this paper we develop a generalized formalism for equilibrium thermodynamic systems when an information is shared between the system and the reservoir. The information results in a correction to the entropy of the system. This extension…

统计力学 · 物理学 2013-05-10 Alessio Gagliardi , Aldo Di Carlo

In this work we prove a global well-posedness result for a tridimensional rescaled Boussinesq system, with positive full viscosity and diffusivity parameters in the framework of critical Fourier-Besov spaces. This rescaled approach permits…

偏微分方程分析 · 数学 2022-07-14 Leithold L. Aurazo-Alvarez

Stochastic chemical systems with diffusion are modeled with a reaction-diffusion master equation. On a macroscopic level, the governing equation is a reaction-diffusion equation for the averages of the chemical species. On a mesoscopic…

数值分析 · 数学 2009-03-06 Stefan Engblom , Lars Ferm , Andreas Hellander , Per Lötstedt

In this paper we study a fractional diffusion Boussinesq model which couples the incompressible Euler equation for the velocity and a transport equation with fractional diffusion for the temperature. We prove global well-posedness results.

偏微分方程分析 · 数学 2015-05-13 Taoufik Hmidi , Sahbi Keraani , Frederic Rousset

Nonequilibrium thermodynamics has shown its applicability in a wide variety of different situations pertaining to fields such as physics, chemistry, biology, and engineering. As successful as it is, however, its current formulation…

凝聚态物理 · 物理学 2009-11-07 J. M. G. Vilar , J. M. Rubi

We establish global-in-time existence results for thermodynamically consistent reaction-(cross-)diffusion systems coupled to an equation describing heat transfer. Our main interest is to model species-dependent diffusivities, while at the…

偏微分方程分析 · 数学 2022-02-11 Julian Fischer , Katharina Hopf , Michael Kniely , Alexander Mielke

We briefly review the recently developed, Markov process based isothermal chemical thermodynamics for nonlinear, driven mesoscopic kinetic systems. Both the instantaneous Shannon entropy {\boldmath $S[p_{\alpha}(t)]$} and relative entropy…

统计力学 · 物理学 2017-01-10 David B. Saakian , Hong Qian

We consider a system of reaction-diffusion equations in a bounded interval of the real line, with emphasis on the metastable dynamics, whereby the time-dependent solution approaches its steady state in an asymptotically exponentially long…

偏微分方程分析 · 数学 2016-06-27 Marta Strani
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