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相关论文: Frenkel biexcitons in hybrid HJ photophysical aggr…

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Frenkel excitons are the primary photoexcitations in organic semiconductors and are ultimately responsible for the optical properties of such materials. They are also predicted to form \emph{bound} exciton pairs, termed biexcitons, which…

材料科学 · 物理学 2022-03-10 Eric R. Bittner , Carlos Silva-Acuna

Bound and unbound Frenkel-exciton pairs are essential transient precursors for a variety of photophysical and biochemical processes. In this work, we identify bound and unbound {Frenkel}-exciton complexes in an electron push-pull polymer…

In this work electronic structures and optical properties of organic-inorganic exciton and polaritons in two-dimensional heterostructures combining both organic and semiconductor materials are studied. In those systems, Wannier-Frenkel…

介观与纳米尺度物理 · 物理学 2019-12-18 David W. Facemyer , Nguyen Que Huong

The photophysics of $\pi$-conjugated polymers has been of considerable interest over the last three decades because of their organic semiconductor properties. Primary photoexcitations, Frenkel excitons, can be probed optically by means of…

The theoretical description and the properties of Frenkel excitons in non-covalently bonded molecular aggregates are reviewed from a multi-exciton perspective of dissipative quantum dynamics. First, the photophysical and quantum chemical…

化学物理 · 物理学 2012-04-23 Oliver Kühn , Stefan Lochbrunner

Two-dimensional transition metal dichalcogenides (TMDs) and organic semiconductors (OSCs) have emerged as promising material platforms for next-generation optoelectronic devices. The combination of both is predicted to yield emergent…

Charge transfer states in organic semiconductors play crucial roles in processes such as singlet fission and exciton dissociation at donor/acceptor interfaces. Recently, a time-resolved spectroscopy study of…

化学物理 · 物理学 2016-02-19 Takatoshi Fujita , Sule Atahan-Evrenk , Nicolas P. D. Sawaya , Alan Aspuru-Guzik

We present a many-body theory for Frenkel excitons which takes into account their composite nature exactly. Our approach is based on four commutators similar to the ones we previously proposed for Wannier excitons. They allow us to…

介观与纳米尺度物理 · 物理学 2009-09-29 M. Combescot , W. V. Pogosov

The concept of \textit{optical} exciton - a photo-excited bound electron-hole pair within a crystal - is routinely used to interpret and model a wealth of excited-state phenomena in semiconductors. Beside originating sub-band gap signatures…

材料科学 · 物理学 2022-09-21 Fulvio Paleari , Andrea Marini

We have developed a model accounting for the photo-excitation dynamics and the photoluminescence of strongly coupled J-aggregate microcavities. Our model is based on a description of the J-aggregate film as a disordered Frenkel exciton…

其他凝聚态物理 · 物理学 2010-07-01 P. Michetti , G. C. La Rocca

Excitons and their correlated complexes underpin the rich photophysics of quantum-confined semiconductors. Among these, biexcitons -- bound states of two electrons and two holes -- provide a sensitive probe of Coulomb correlations,…

材料科学 · 物理学 2026-01-23 Katherine A. Koch , Carlos Silva-Acuña , Ajay Ram Srimath Kandada

Excitons are key quasiparticles determining the optical properties of solids. As such, they can be utilized to coherently control the electronic structure of materials using optical femtosecond pulses. Identifying the decoherence mechanism…

Harnessing the optoelectronic response of organic semiconductors requires a thorough understanding of the fundamental light-matter interaction that is dominated by the excitation of correlated electron-hole pairs, i.e. excitons. The nature…

Organic molecules store the energy of absorbed light in the form of charge-neutral molecular excitations -- Frenkel excitons. Usually, in amorphous organic materials, excitons are viewed as quasiparticles, localized on single molecules,…

介观与纳米尺度物理 · 物理学 2013-04-02 Semion K. Saikin , Alexander Eisfeld , Stéphanie Valleau , Alán Aspuru-Guzik

Excitons - the particle-hole bound states - composed of localized electron-hole states in semiconducting systems are crucial to explaining the optical spectrum. Spectroscopic measurements can contain signatures of these two particle bound…

介观与纳米尺度物理 · 物理学 2018-06-19 Avinash Rustagi , Alexander F. Kemper

Optical measurements and first-principles calculations of the band structure and exciton states in direct-gap bulk and few-layer PbI2 indicate that the n = 1 exciton is Frenkel-like in nature in that its energy exhibits a weak dependence on…

介观与纳米尺度物理 · 物理学 2015-05-20 Alexis S. Toulouse , Benjamin P. Isaacoff , Guangsha Shi , Marie Matuchová , Emmanouil Kioupakis , Roberto Merlin

A phenomenological coupled exciton model is proposed in order to characterize optical excitations in extended dendrimers. An onsite exciton state is assigned at each phenyl rings and a nearest neighbor hopping integral which obeys the…

材料科学 · 物理学 2016-08-31 Kikuo Harigaya

Excitons -- two-particle correlated electron-hole pairs -- are the dominant low-energy optical excitation in the broad class of semiconductor materials, which range from classical silicon to perovskites, and from two-dimensional to organic…

材料科学 · 物理学 2025-11-25 Marcel Reutzel , G. S. Matthijs Jansen , Stefan Mathias

Semiconductor quantum light sources are favorable for a wide range of quantum photonic tasks, particularly quantum computing and quantum information processing. Here we theoretically investigate the properties of quantum emitters (QEs) as a…

量子物理 · 物理学 2024-05-29 Kobra N. Avanaki , George C. Schatz

The light-mediated interaction of fermionic and bosonic excitations governs the optoelectronic properties of condensed matter systems. In photoexcited semiconductors, the coupling of electron-hole pairs (excitons) to coherent optical…

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