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Few-layer selenium and tellurium films have been recently prepared, and they provide a new platform to explore novel properties of two-dimensional (2D) elemental materials. In this work, we have performed a systematic first-principles study…

光学 · 物理学 2021-06-23 Meijuan Cheng , Zi-Zhong Zhu , Guang-Yu Guo

Trigonal selenium and tellurium crystalize in helical chain-like structures and thus possess interesting properties such as current-induced spin polarization, gyrotropic effects and nonlinear optical responses. By performing systematic ab…

计算物理 · 物理学 2019-07-17 Meijuan Cheng , Shunqing Wu , Zi-Zhong Zhu , Guang-Yu Guo

Recently, atomically thin PdSe$_2$ semiconductors with rare pentagonal Se-Pd-Se monolayers were synthesized and were also found to possess superior properties such as ultrahigh air stability, and high carrier mobility, thus offering a new…

材料科学 · 物理学 2021-09-21 Vijay Kumar Gudelli , Guang-Yu Guo

Tellurium (Te) is an elemental semiconductor with a simple chiral crystal structure. Te in a two-dimensional (2D) form synthesized by solution-based method shows excellent electrical, optical, and thermal properties. In this work, the…

材料科学 · 物理学 2023-09-13 Chang Niu , Gang Qiu , Yixiu Wang , Pukun Tan , Mingyi Wang , Jie Jian , Haiyan Wang , Wenzhuo Wu , Peide D. Ye

Two-dimensional (2D) elemental semiconductors have great potential for device applications, but their performance is limited by the lack of efficient doping methods. Here, combining molecular beam epitaxy, scanning tunneling…

Tellurium (Te) is an intrinsically p-type doped narrow bandgap semiconductor with excellent electrical conductivity and low thermal conductivity. Bulk trigonal Te has been theoretically predicted and experimentally demonstrated to be an…

Contemporary science is witnessing a rapid expansion of the two-dimensional (2D) materials family, each member possessing intriguing emergent properties of fundamental and practical importance. Using the particle-swarm optimization method…

介观与纳米尺度物理 · 物理学 2017-09-13 Zhili Zhu , Xiaolin Cai , Chunyao Niu , Seho Yi , Zhengxiao Guo , Feng Liu , Jun-Hyung Cho , Yu Jia , Zhenyu Zhang

In 2016, bulk tellurium was experimentally observed as a remarkable thermoelectric material. Recently, two-dimensional (2D) tellurium, called tellurene, has been synthesized and has exhibited unexpected electronic properties compared with…

计算物理 · 物理学 2019-06-05 Zhibin Gao , Gang Liu , Jie Ren

Bulk tellurium (Te) is composed of one-dimensional (1D) helical chains which have been considered to be coupled by van der Waals (vdW) interactions. However, based on first-principles density-functional theory calculations, we here propose…

材料科学 · 物理学 2017-12-05 Seho Yi , Zhili Zhu , Xiaolin Cai , Yu Jia , Jun-Hyung Cho

The second-order nonlinear optical (NLO) processes, such as the photogalvanic effect and second-order harmonic generation (SHG), play crucial roles in probing and controlling light-matter interactions for energy and device applications. To…

材料科学 · 物理学 2020-08-05 Ruixiang Fei , Wenshen Song , Li Yang

Selenium has attracted intensive attention as a promising material candidate for future optoelectronic applications. However, selenium has a strong tendency to grow into nanowire forms due to its anisotropic atomic structure, which has…

In$_2$Se$_3$ in the three-dimensional (3D) hexagonal crystal structure with space group $P6_1$ ($\gamma$-In$_2$Se$_3$) has a direct band gap of $\sim$1.8 eV and high absorption coefficient, making it a promising semiconductor material for…

We have computed second and third nonlinear optical susceptibilities of two crystalline bulk tellurium oxide polymorphs: $\alpha$-TeO$_{2}$ (the most stable crystalline bulk phase) and $\gamma$-TeO$_{2}$ (the crystalline phase that…

材料科学 · 物理学 2011-07-15 Nabil Berkaine , Emmanuelle Orhan , Olivier Masson , Philippe Thomas , Javier Junquera

We present a comprehensive first-principles investigation of the structural, electronic, vibrational, and topological properties of tellurium across its dimensional hierarchy, including bulk trigonal Te-I, two-dimensional tellurene…

材料科学 · 物理学 2026-02-17 Gabriel Elyas Gama Araujo , Andreia Luisa da Rosa

Chirality arises from the asymmetry of matters, where two counterparts are the mirror image of each other. The interaction between circular-polarization light and quantum materials is enhanced in chiral space groups due to the structural…

介观与纳米尺度物理 · 物理学 2023-09-13 Chang Niu , Shouyuan Huang , Neil Ghosh , Pukun Tan , Mingyi Wang , Wenzhuo Wu , Xianfan Xu , Peide D. Ye

Tellurium (Te) is a narrow bandgap semiconductor with a unique chiral crystal structure. The topological nature of electrons in the Te conduction band can be studied by realizing n-type doping using atomic layer deposition (ALD) technique…

介观与纳米尺度物理 · 物理学 2021-10-04 Chang Niu , Gang Qiu , Yixiu Wang , Mengwei Si , Wenzhuo Wu , Peide D. Ye

In this work, the polar tetrahedron [PN$_2$O$_2$] was revealed as a new deep-ultraviolet (deep-UV) nonlinear optically active unit. Accordingly, a thermodynamically stable compound (PNO) consisting of the polar [PN$_2$O$_2$] units was…

光学 · 物理学 2022-08-29 Congwei Xie , Abudukadi Tudi , Artem R. Oganov

Second harmonic (SH) radiation can only be generated in non-centrosymmetric bulk crystals under the electric-dipole approximation. Nonlinear thin films made from bulk crystals are technologically challenging because of complex and high…

Monolayer transition-metal dichalcogenides (TMDCs) present high second-order optical nonlinearity, which is extremely desirable for, e.g., frequency conversion in nonlinear photonic devices. On the other hand, the atomic thickness of 2D…

介观与纳米尺度物理 · 物理学 2020-11-17 Pilar G. Vianna , Aline dos S. Almeida , Rodrigo M. Gerosa , Dario A. Bahamon , Christiano J. S. de Matos

Monolayer transition metal dichalcogenides (TMDs) exhibit high nonlinear optical (NLO) susceptibilities. Experiments on MoS$_2$ have indeed revealed very large second-order ($\chi^{(2)}$) and third-order ($\chi^{(3)}$) optical…

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