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The quantum reprojection method within the standard adiabatic Born-Oppenheimer approach is derived for multielectron collision systems. The method takes nonvanishing asymptotic nonadiabatic couplings into account and distinguishes…

化学物理 · 物理学 2015-05-20 Andrey K. Belyaev

Laser-induced molecular alignment is well understood within the framework of the Born-Oppenheimer (BO) approximation Without the BO approximation, however, the concept of molecular structure is lost, making alignment hard to define…

化学物理 · 物理学 2022-09-16 Ludwik Adamowicz , Simen Kvaal , Caroline Lasser , Thomas Bondo Pedersen

We propose a theoretical protocol to create the entanglement of two qubits via the Born-Oppenheimer (BO) approximation. In our scheme, each qubit is coupled to a faster data bus whose frequency is much larger than the energy spacing of the…

量子物理 · 物理学 2007-05-23 P. Zhang , Y. D. Wang , C. P. Sun

While the treatment of conical intersections in molecular dynamics generally requires nonadiabatic approaches, the Born-Oppenheimer adiabatic approximation is still adopted as a valid alternative in certain circumstances. In the context of…

化学物理 · 物理学 2020-09-16 Jonathan I. Rawlinson , Cesare Tronci

Molecular complexes are held together via a variety of bonds, but they all share the common feature that their individual entities are in contact. In this work, we introduce and demonstrate the concept of a \textit{molecular optical bond},…

介观与纳米尺度物理 · 物理学 2025-01-03 Jahangir Nobakht , André Pscherer , Jan Renger , Stephan Götzinger , Vahid Sandoghdar

We analyze the physics of accelerated particle detectors (such as atoms) crossing optical cavities. In particular we focus on the detector response as well as on the energy signature that the detectors imprint in the cavities. In doing so,…

量子物理 · 物理学 2018-11-27 Richard Lopp , Eduardo Martin-Martinez , Don N. Page

Motivated by a paper by B.T. Sutcliffe and R.G. Woolley, we present the main ideas used by mathematicians to show the accuracy of the Born-Oppenheimer approximation for molecules. Based on mathematical works on this approximation for…

数学物理 · 物理学 2026-05-15 Thierry Jecko

We consider theoretically the optomechanical interaction of several mechanical modes with a single quantized cavity field mode for linear and quadratic coupling. We focus specifically on situations where the optical dissipation is the…

量子物理 · 物理学 2014-10-24 H. Seok , L. F. Buchmann , S. Singh , P. Meystre

We theoretically examine photoassociation of a non-ideal Bose-Einstein condensate, focusing on evidence for a macroscopic superposition of atoms and molecules. This problem raises an interest because, rather than two states of a given…

软凝聚态物质 · 物理学 2009-11-07 John Calsamiglia , Matt Mackie , Kalle-Antti Suominen

We consider a hybrid atom-optomechanical system consisting of a mechanical membrane inside an optical cavity and an atomic Bose-Einstein condensate outside the cavity. The condensate is confined in an optical lattice potential formed by a…

量子气体 · 物理学 2021-03-03 Jia-Ming Cheng , Zheng-Wei Zhou , Guang-Can Guo , Han Pu , Xiang-Fa Zhou

The standard description of cavity-modified molecular reactions typically involves a single (resonant) mode, while in reality the quantum cavity supports a range of photon modes. Here we demonstrate that as more photon modes are accounted…

介观与纳米尺度物理 · 物理学 2020-07-15 Norah M. Hoffmann , Lionel Lacombe , Angel Rubio , Neepa T. Maitra

It has been assumed that it is possible to approximate the interactions of quantized BPS solitons by quantising a dynamical system induced on a moduli space of soliton parameters. General properties of the reduction of quantum systems by a…

高能物理 - 理论 · 物理学 2009-10-31 Ian G. Moss , Noriko Shiiki

Bose-Einstein condensates of sodium atoms have been prepared in optical and magnetic traps in which the energy-level spacing in one or two dimensions exceeds the interaction energy between atoms, realizing condensates of lower…

Optical cavities can induce photon-mediated interactions among intracavity-trapped atoms. Multimode cavities provide the ability to tune the form of these interactions, e.g., by inducing a nonlocal, sign-changing term to the interaction. By…

Coupling between molecules and vacuum photon fields inside an optical cavity has proven to be an effective way to engineer molecular properties, in particular reactivity. To ease the rationalization of cavity induced effects we introduce an…

化学物理 · 物理学 2022-04-06 Rosario R. Riso , Tor S. Haugland , Enrico Ronca , Henrik Koch

We consider the motion of the end mirror of a cavity inside which a two-level atom trapped. The fast vibrating mirror induces nonlinear couplings between the cavity field and the atom. We analyze this optical effect by showing the…

量子物理 · 物理学 2009-06-11 X. X. Yi , H. Y. Sun , L. C. Wang

Optical cavities are widely used to enhance the interaction between atoms and light. Typical designs using a geometrically symmetric structure in the near-concentric regime face a tradeoff between mechanical stability and high single-atom…

In pre-Born-Oppenheimer (pre-BO) theory a molecule is considered as a quantum system as a whole, including the electrons and the atomic nuclei on the same footing. This approach is fundamentally different from the traditional quantum…

化学物理 · 物理学 2019-02-20 Edit Matyus

Previous studies have used numerical methods to optimize the hyperpolarizability of a one-dimensional quantum system. These studies were used to suggest properties of one-dimensional organic molecules, such as the degree of modulation of…

光学 · 物理学 2015-05-18 Urszula B. Szafruga , Mark G. Kuzyk , David S. Watkins

We give a theoretical treatment of single atom detection in an compound, optical micro cavity. The cavity consists of a single mode semiconductor waveguide with a gap to allow atoms to interact with the optical field in the cavity. Optical…

光学 · 物理学 2016-04-27 Abdelkrim El Amili , Sébastien Gleyzes , Christoph I Westbrook