相关论文: Rate constants from instanton theory via a microca…
This study address the computational determination of catalytic reaction rates by moving beyond traditional Transition State Theory (TST), addressing its limitations in complex systems. The Hill relation framework, integrated with Adaptive…
We present in this paper the main structural features and enthalpy details for the energy profiles of the title reactions, both for the exothermic (forward) path to NH$_{3}$ formation and for the endothermic (reverse) reaction to…
We construct a measure in the hamiltonian function level sets that is invariant under the hamiltonian flow for short times and flow preserving for arbitrarily long times. This allows a probabilistic approach to the study of hamiltonian…
We extend the worldline instanton technique to compute the vacuum pair production rate for spatially inhomogeneous electric background fields, with the spatial inhomogeneity being genuinely two or three dimensional, both for the magnitude…
The goal of this paper is to investigate the stability of the Helmholtz equation in the high- frequency regime with non-smooth and rapidly oscillating coefficients on bounded domains. Existence and uniqueness of the problem can be proved…
Instantons, semi-classical trajectories of quantum tunneling in imaginary time, have long been used to study thermodynamic and transport properties in a myriad of condensed matter and high energy systems. A recent experiment in…
A microcanonical first order transition, connecting a clustered to a homogeneous phase, is studied from both the thermodynamic and dynamical point of view for a N-body Hamiltonian system with infinite-range couplings. In the microcanonical…
A theory for stabilization of quantum resonances by a mechanism similar to one leading to classical resonances in nonlinear systems is presented. It explains recent surprising experimental results, obtained for cold Cesium atoms when driven…
We study the steady state of two coupled two-level atoms interacting with a non-equilibrium environment that consists of two heat baths at different temperatures. Specifically, we analyze four cases with respect to the configuration about…
We study a fractional reaction-diffusion system with two types of variables: activator and inhibitor. The interactions between components are modeled by cubical nonlinearity. Linearization of the system around the homogeneous state provides…
In an experimental study of single enzyme reactions, it has been proposed that the rate constants of the enzymatic reactions fluctuate randomly, according to a given distribution. To quantify the uncertainty arising from random rate…
A thermodynamically consistent particle-based model for fluid dynamics with continuous velocities and a non-ideal equation of state is presented. Excluded volume interactions are modeled by means of biased stochastic multiparticle…
We study the stability of holonomic quantum computations with respect to errors in assignment of control parameters. The general expression for fidelity is obtaned. In the small errors limit the simple formulae for the fidelity decrease…
Shortcuts to adiabaticity (STA) are techniques allowing rapid variation of the system Hamiltonian without inducing excess heating. Fast optical transfer of atoms between different locations is a prime example of an STA application. We show…
In this work, we consider the problem of online (real-time, single-shot) estimation of static or slow-varying parameters along quantum trajectories in quantum dynamical systems. Based on the measurement signal of a continuously-monitored…
Path integral implementation of the quantum instanton approximation currently belongs among the most accurate methods for computing quantum rate constants and kinetic isotope effects, but its use has been limited due to the rather high…
We study the stabilization of an unpredictable linear control system where the controller must act based on a rate-limited observation of the state. More precisely, we consider the system $X_{n+1} = A_n X_n + W_n - U_n$, where the $A_n$'s…
We propose a quantum algorithm for solving the following problem: given the Hamiltonian of a physical system and one of its eigenvalues, how to obtain the corresponding eigenstate? The algorithm is based on the resonance phenomena. For a…
We find classically stable solitons (instantons) in odd (even) dimensional scalar noncommutative field theories whose scalar potential, $V(\ph)$, has at least two minima. These solutions are bubbles of the false vacuum whose size is set by…
We consider non-relativistic systems in quantum mechanics interacting through the Coulomb potential, and discuss the existence of bound states which are stable against spontaneous dissociation into smaller atoms or ions. We review the…