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Electron-hole bound pairs, or excitons, are common excitations in semiconductors. They can spontaneously form and ``condense'' into a new insulating ground state -- the so-called excitonic insulator -- when the energy of electron-hole…

The excitonic insulator is an intriguing correlated electron phase formed of condensed excitons. A promising candidate is the small band gap semiconductor Ta2NiSe5. Here we investigate the quasiparticle and coherent phonon dynamics in…

The excitonic insulator is an elusive electronic phase exhibiting a correlated excitonic ground state. Materials with such a phase are expected to have intriguing properties such as excitonic high-temperature superconductivity. However,…

强关联电子 · 物理学 2021-12-07 Dominik Christiansen , Malte Selig , Mariana Rossi , Andreas Knorr

Excitonic insulators host a condensate of electron-hole pairs at equilibrium, giving rise to collective many-body effects. Although several materials have emerged as excitonic insulator candidates, evidence of long-range coherence is…

Ta$_2$NiSe$_5$ became one of the most investigated candidate materials for hosting an excitonic insulator ground state. Many studies describe the corresponding phase transition as a condensation of excitons breaking a continuous symmetry.…

强关联电子 · 物理学 2021-03-04 Min-Jae Kim , Armin Schulz , Tomohiro Takayama , Masahiko Isobe , Hidenori Takagi , Stefan Kaiser

The excitonic insulator is an intriguing electronic phase of quasi-condensed excitons. A prominent candidate is the small bandgap semiconductor Ta2NiSe5, in which excitons are believed to undergo a BEC-like transition. But experimental…

The excitonic insulator is an electronically-driven phase of matter that emerges upon the spontaneous formation and Bose condensation of excitons. Detecting this exotic order in candidate materials is a subject of paramount importance, as…

An excitonic insulator phase is expected to arise from the spontaneous formation of electron-hole pairs (excitons) in semiconductors where the exciton binding energy exceeds the size of the electronic band gap. At low temperature, these…

强关联电子 · 物理学 2022-09-02 Selene Mor , Marc Herzog , Claude Monney , Julia Stähler

The high-temperature phase of Ta$_\mathrm{2}$NiSe$_\mathrm{5}$, a near-zero-gap semiconductor ($E_G$ = 0), is a promising candidate for an excitonic insulator. Given the dome-like evolution expected for an excitonic insulator around $E_G$,…

Coulomb attraction between electrons and holes in a narrow-gap semiconductor or a semimetal is predicted to lead to an elusive phase of matter dubbed 'excitonic insulator'. However, direct observation of such electronic instability remains…

强关联电子 · 物理学 2021-08-09 Kwangrae Kim , Hoon Kim , Jonghwan Kim , Changil Kwon , Jun Sung Kim , B. J. Kim

Excitonic insulators are electronically-driven phases of matter characterized by the spontaneous condensation of electron-hole pairs. Here we show that La$_3$Cd$_2$As$_6$ undergoes a transition at $T_{0}=278$ K to a highly insulating state…

The formation of excitonic insulator phases in quantum materials is often masked by structural distortions caused by the coupling between electronic and phononic order parameters. Here we show that the candidate material Ta$_2$NiSe$_5$ is…

强关联电子 · 物理学 2026-02-02 Giacomo Mazza

Excitonic insulator (EI) was proposed in 60's as a distinct insulating state originating from pure electronic interaction, but its material realization has been elusive with extremely few material candidates and with only limited evidence…

材料科学 · 物理学 2019-03-06 Jinwon Lee , Chang-Jong Kang , Man Jin Eom , Jun Sung Kim , Byung Il Min , Han Woong Yeom

Realizing an excitonic insulator phase from narrow-gap semiconductors remains challenging, as unambiguous experimental signatures are difficult to establish. Ta$_2$NiSe$_5$ has been widely regarded as a leading candidate, yet the nature of…

材料科学 · 物理学 2025-12-11 Keyu Wei , Yixuan Luo , Kenji Watanabe , Takashi Taniguchi , Yanfeng Guo , Xiaoxiang Xi

We study the electronic phase diagram of the excitonic insulator candidates Ta$_2$Ni(Se$_{1-x}$S$_x$)$_5$ [x=0, ... ,1] using Raman spectroscopy. Critical excitonic fluctuations are observed, that diminish with $x$ and ultimately shift to…

强关联电子 · 物理学 2021-12-30 Pavel A. Volkov , Mai Ye , Himanshu Lohani , Irena Feldman , Amit Kanigel , Girsh Blumberg

Bound electron-hole pairs in semiconductors known as excitons can form a coherent state at low temperatures akin to a BCS condensate. The resulting phase is known as the excitonic insulator and has superfluid properties. Here we…

强关联电子 · 物理学 2025-06-06 L. Maisel Licerán , H. T. C. Stoof

We explore the collective response in an excitonic insulator phase in Ta$_2$NiSe$_5$ using a semirealistic model including relevant lattice and electronic instabilities. We calculate order-parameter susceptibility and Raman response within…

强关联电子 · 物理学 2025-08-19 Banhi Chatterjee , Jernej Mravlje , Denis Golež

Tuning many-body electronic phases by an external handle is of both fundamental and practical importance in condensed matter science. The tunability mirrors the underlying interactions, and gigantic electric, optical and magnetic responses…

强关联电子 · 物理学 2021-10-04 Q. He , X. Que , L. Zhou , M. Isobe , D. Huang , H. Takagi

The influence of phonons on the formation of the excitonic insulator has hardly been analyzed so far. Recent experiments on $\rm Ta_2NiSe_5$, 1$T$-$\rm TiSe_2$, and $\rm TmSe_{0.45}Te_{0.55}$, being candidates for realizing the…

强关联电子 · 物理学 2015-06-22 B. Zenker , H. Fehske , H. Beck

Many-body interactions can produce novel ground states in a condensed-matter system. For example, interacting electrons and holes can spontaneously form excitons, a neutral bound state, provided that the exciton binding energy exceeds the…

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