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We use large-scale molecular dynamics simulations to study the kinetics of the liquid-gas phase separation if the temperature is lowered across the glass transition of the dense phase. We observe a gradual change from phase separated…

统计力学 · 物理学 2011-06-01 Vincent Testard , Ludovic Berthier , Walter Kob

We use large-scale molecular dynamics simulations of a simple glass-forming system to investigate how its liquid-gas phase separation kinetics depends on temperature. A shallow quench leads to a fully demixed liquid-gas system whereas a…

无序系统与神经网络 · 物理学 2014-05-16 Vincent Testard , Ludovic Berthier , Walter Kob

We investigate a binary Lennard-Jones mixture with molecular dynamics simulations. We consider first a system cooled linearly in time with the cooling rate gamma. By varying gamma over almost four decades we study the influence of the…

统计力学 · 物理学 2015-06-25 K. Vollmayr-Lee , W. Kob , K. Binder , A. Zippelius

Motivated by recent experimental studies probing i) the existence of a mobile layer at the free surface of glasses, and ii) the capillary leveling of polymer nanofilms, we study the evolution of square-wave patterns at the free surface of a…

软凝聚态物质 · 物理学 2019-09-18 Ioannis Tanis , Kostas Karatasos , Thomas Salez

The classic Kob-Andersen (KA) binary Lennard-Jones mixtures which are designed to prevent crystallization has been extensively studied in simulation of slow dynamics. Although crystallization can occur if a liquid system is cooled slowly,…

软凝聚态物质 · 物理学 2017-03-10 Penghui Cao

The physical behavior of glass-forming liquids presents complex features of both dynamic and thermodynamic nature. Some studies indicate the presence of thermodynamic anomalies and of crossovers in the dynamic properties, but their origin…

统计力学 · 物理学 2018-06-08 Daniele Coslovich , Misaki Ozawa , Walter Kob

In a companion paper, we put forth a thermodynamic model for complex formation via a chemical reaction involving multiple macromolecular species, which may subsequently undergo liquid-liquid phase separation and a further transition into a…

生物物理 · 物理学 2024-07-26 Ruoyao Zhang , Sheng Mao , Mikko P. Haataja

The relationship between glasses and gels has been intensely debated for decades; however, the transition between these two phases remains elusive. To investigate a gel formation process in the zero-temperature limit and its relation to the…

软凝聚态物质 · 物理学 2022-10-27 Masanari Shimada , Norihiro Oyama

Differences in activities in colloidal particles are sufficient to drive phase separation between active and passive (or less active) particles, even if they have only excluded volume interactions. In this paper, we study the phase…

软凝聚态物质 · 物理学 2020-05-27 Efe Ilker , Jean-François Joanny

Experimental studies of the glassy slowdown in molecular liquids indicate that the high-temperature activation energy $E_{\infty}$ of glass-forming liquids is directly related to their glass transition temperature $T_{\text{g}}$. To further…

软凝聚态物质 · 物理学 2021-03-02 L. Hecht , R. Horstmann , B. Liebchen , M. Vogel

We simulate the compression of a two-component Lennard-Jones liquid at a variety of constant temperatures using a molecular dynamics algorithm in an isobaric-isothermal ensemble. The viscosity of the liquid increases with pressure,…

chem-ph · 物理学 2009-10-22 Shelly L. Shumway , Andrew S. Clarke , Hannes Jónsson

Glass-forming liquids have only a modest tendency to crystallize and hence their dynamics can be studied even below the melting temperature. The relaxation dynamics of most of these liquids shows at a temperature $T_c$, somewhat above the…

软凝聚态物质 · 物理学 2025-01-17 Francesco Rusciano , Raffaele Pastore , Francesco Greco , Walter Kob

We investigate the calorimetric liquid-glass transition by performing simulations of a binary Lennard-Jones mixture in one through four dimensions. Starting at a high temperature, the systems are cooled to T=0 and heated back to the ergodic…

无序系统与神经网络 · 物理学 2009-01-01 Ralf Brüning , Denis A. St-Onge , Steve Patterson , Walter Kob

We investigate the quantum phases of monodispersed bosonic gases confined to a triangular lattice and interacting via a class of soft-shoulder potentials. The latter correspond to soft-core potentials with an additional hard-core onsite…

量子气体 · 物理学 2016-04-06 Adriano Angelone , Fabio Mezzacapo , Guido Pupillo

Molecular dynamics simulations are performed to investigate heterogeneous dynamics in amorphous glassy materials under oscillatory shear strain. We consider three-dimensional binary Lennard-Jones mixture well below the glass transition…

软凝聚态物质 · 物理学 2013-05-10 Nikolai V. Priezjev

Colloid-polymer mixtures may undergo either fluid-fluid phase separation or gelation. This depends on the depth of the quench (polymer concentration) and polymer-colloid size ratio. We present a real-space study of dynamics in phase…

软凝聚态物质 · 物理学 2012-09-19 Isla Zhang , C. Patrick Royall , Paul Bartlett , Malcolm A. Faers

We numerically investigate the competition between phase separation and dynamical arrest in a colloidal system interacting via a short ranged attractive potential. Equilibrium fluid configurations are quenched at two different temperatures…

软凝聚态物质 · 物理学 2007-05-23 G. Foffi , C. De Michele , F. Sciortino , P. Tartaglia

Molecular dynamics computer simulations of a binary Lennard-Jones glass under shear are presented. The mechanical response of glassy states having different thermal histories is investigated by imposing a wide range of external shear rates,…

软凝聚态物质 · 物理学 2016-12-14 Gaurav Prakash Shrivastav , Pinaki Chaudhuri , Jürgen Horbach

We present results from Langevin dynamics simulations of a glassy active-passive mixture of soft-repulsive binary colloidal disks. Activity on the smaller particles is applied according to the quorum sensing scheme, in which a smaller…

软凝聚态物质 · 物理学 2020-12-10 Jalim Singh , A. V. Anil Kumar

Using a modified Lennard-Jones model for anisotropic particles, we present results of molecular dynamics simulation in two dimensions. In one-component systems, we find crystallization, a Berezinskii-Kosterlitz-Thouless phase, and a…

软凝聚态物质 · 物理学 2011-12-23 Kyohei Takae , Akira Onuki
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