相关论文: The van der Waals idea of pseudo associations and …
It is shown that the ratio of the Boyle temperature to the product of critical temperature and critical compressibility factor is equal to the number 9 with high accuracy for 21 real substances as predicted from Van-der-Waals equation of…
The relation between the critical compressibility factors $Z_{c}$ of the Lennard-Jones fluid and the Lattice Gas (Ising model) is derived within the global isomorphism approach. On this basis we obtain the alternative form for the value of…
We obtain families of generalised van der Waals equations characterised by an even number $n=2,4,6$ and a continuous free parameter which is tunable for a critical compressibility factor. Each equation features two adjacent critical points…
In the framework of the van-der-Waals model, analytical expressions for the locus of extrema (ridges) for heat capacity, thermal expansion coefficient, compressibility, density fluctuation, and sound velocity in the supercritical region…
We show how to obtain the critical compressibility factor $Z_c$ for simple and associative Lennard-Jones fluids using the critical characteristics of the Ising model on different lattices. The explanation for the results on the critical…
The empirical formula of Timmermanns connecting the density of the crystal at zero absolute temperature with the parameters of the critical point of the gas-liquid phase transition is derived theoretically from the Van der Waals equation of…
This article reviews a new and general theory of nonuniform fluids that naturally incorporates molecular scale information into the classical van der Waals theory of slowly varying interfaces. The method optimally combines two standard…
The isothermal compressibility of water is essential to understand its anomalous properties. We compute it by ab initio molecular dynamics simulations of 200 molecules at five densities, using two different van der Waals density…
We analyze the properties of a generic cosmological fluid described by the van der Waals equation of state. Exact solutions for the energy density evolution are found as implicit functions of the scale factor for a flat…
Isothermal interfacial zones are investigated starting from a local energy which can be considered as the sum of two terms: one corresponding to a medium with a uniform composition equal to the local one and a second one associated with the…
In the present work, the critical temperature, critical pressure and critical density, known as the critical parameters related to the liquid-gas phase transition are calculated for 34 relativistic mean-field models, which were shown to…
The celebrated van der Waals model describes simple fluids in the thermodynamic limit and predicts the existence of a critical point associated to the gas-liquid phase transition. However the behaviour of critical isotherms according to the…
We present a dynamic van der Waals theory. It is useful to study phase separation when the temperature varies in space. We show that if heat flow is applied to liquid suspending a gas droplet at zero gravity, a convective flow occurs such…
We have developed a new and general theory of nonuniform fluids that naturally incorporates molecular scale information into the classical van der Waals theory of slowly varying interfaces. Here the theory is applied to the liquid-vapor…
In a one-component fluid, we investigate evaporation of a small axysymmetric liquid droplet in the partial wetting condition on a heated wall at $T\sim 0.9 T_c$. In the dynamic van der Waals theory (Phys. Rev. E {\bf 75}, 036304 (2007)), we…
In recent works, we proposed a theory of turbulence creation via the second coefficient of the virial expansion (i.e. the van der Waals effect). This theory relies, in part, on the empirically observed "equilibrated" behavior of pressure in…
A simple kinetic model, which is presumably minimum, for the phase transition of the van der Waals fluid is presented. In the model, intermolecular collisions for a dense gas has not been treated faithfully. Instead, the expected…
Recently we have proposed (J. Chem. Phys. 128 (2008) 134508) a new rescaling of fluid density $\rho $ by its critical value $\rho_c^{2/3}$ to apply the corresponding states law for the attractive Yukawa fluids study. Analysis of precise…
The non-Gaussian measures of the particle number fluctuations -- skewness $S\sigma$ and kurtosis $\kappa \sigma^2$ -- are calculated in a vicinity of the critical point. This point corresponds to the end point of the first-order liquid-gas…
We find a thermodynamic description of gas-liquid criticality that is different from van der Waals and mean-field theories. At the critical temperature there is no critical point; a liquid phase coexists with a vapor phase with densities…