相关论文: Foamability of aqueous solutions: Role of surfacta…
In this paper we study the dynamics of a layer of incompressible viscous fluid bounded below by a rigid boundary and above by a free boundary, in the presence of a uniform gravitational field. We assume that a mass of surfactant is present…
We present a model treating the kinetics of adsorption of soluble surface-active molecules at the interface between an aqueous solution and another fluid phase. The model accounts for both the diffusive transport inside the solution and the…
We review a new theoretical approach to the kinetics of surfactant adsorption at fluid-fluid interfaces. It yields a more complete description of the kinetics both in the aqueous solution and at the interface, deriving all equations from a…
The stability of a thin liquid film bounded by two free surfaces is examined in the presence of insoluble surface active agents. The surface active agents not only cause gradients in surface tension, but could also render surface viscosity…
The linear dynamics and instability mechanisms of double-layered weakly viscoelastic fluid flowing over an inclined plane are analyzed in the presence of insoluble surfactant at both the free surface and interface. The constitutive equation…
Understanding the behavior of nanobubbles (NBs) in various aqueous solutions is a challenging task. The present work investigates the effects of various surfactants (i.e., anionic, cationic, and nonionic) and pH medium on bulk NBs…
A horizontal flow of two immiscible fluid layers with different densities, viscosities and thicknesses, subject to vertical gravitational forces and with an insoluble surfactant present at the interface, is investigated. The base Couette…
Mass transfer of gaseous components from rising bubbles to the ambient liquid depends not only on the chemical potential difference of the transfer component but also on the interfacial free energy and composition. The latter is strongly…
The structure and stability of the convective flow generated by a source located at the water surface containing an insoluble surfactant layer are experimentally investigated. Application of a few types of source, which differ in the force…
The adsorption kinetics of the cationic surfactant dodecyltrimethylammonium bromide at the air-water interface has been studied by the maximum bubble pressure method at concentrations below the critical micellar concentration. At short…
We study the formation of the dynamic adsorption layer when a bubble is released in a tank containing water with a tiny amount of surfactant. The influence of the sorption kinetic constants is examined by comparing the experiments with…
We present a theory for the kinetics of surfactant adsorption at the interface between an aqueous solution and another fluid (air, oil) phase. The model relies on a free-energy formulation. It describes both the diffusive transport of…
The physico-chemistry of surfactants (amphiphilic surface active agents) is often used to control the dynamics of viscous drops and bubbles. Surfactant sorption kinetics has been shown to play a critical role in the deformation of drops in…
Chemical heterogeneity of solid surfaces disrupts the adsorption of surfactants from the bulk liquid. While its presence can hinder the performance of some formulations, bespoke chemical patterning could potentially facilitate controlled…
The unique surface properties of amphiphilic molecules have made them widely used in applications where foaming, emulsifying or coating processes are needed. Novel surfactant architectures with multi-cephalic and multi-tailed molecules have…
Adsorption of surfactants to fluid interfaces occurs in daily-life and technological contexts like dish washing and oil spill remediation. The surfactant surface coverage $\Gamma$ governs interface characteristics like tension $\gamma$,…
In this paper we propose several models that describe the dynamics of liquid films which are covered by a high concentration layer of insoluble surfactant. First, we briefly review the 'classical' hydrodynamic form of the coupled evolution…
We investigated the effect of surfactants on an interface between two kinds of liquid by molecular dynamics simulation. We adopted the simple bead-spring model with two atoms as the surfactants. We controlled the interfacial tension of the…
Surfactants are critical in natural processes and engineering, but measuring their concentrations in non-equilibrium conditions and in the presence of flow is difficult. Therefore, computational methods are a key tool for improving our…
The hydrodynamic stability behaviour of a two-layer falling film is explored with a floating flexible plate on the top surface. The stress balance at the surface is modeled using a modified membrane equation. There is an insoluble…