相关论文: Charge Transfer Effect under Odd-Parity Crystallin…

Electron transfer with changing occupation in the 4f subshell poses a considerable challenge for quantitative predictions in quantum chemistry. Using the example of cerium oxide, we identify the main deficiencies of common…

The charge-transfer (CT) together with the polarization energy appears at second and higher orders in symmetry-adapted perturbation theory (SAPT). At present there is no theoretically compelling way of isolating the charge-transfer energy…

A growing list of Ce-based magnets have shown an extra and heretofore unexplained crystal electric field (CEF) mode at high energies. We describe a process whereby an optical phonon can produce a split CEF mode well above the phonon energy.…

We analyze a possibility for odd-frequency pairing near a quantum critical point(QCP) in a metal. We consider a model with dynamical pairing interaction $V(\Omega_n)\sim 1/|\Omega_n|^\gamma$ (the $\gamma$-model). This interaction gives rise…

For Sn$_2$P$_2$S$_6$ ferroelectrics the second order phase transitions line is observed until reaching the tricritical point at transition temperature lowering to 250 K by compression. Observed temperature-pressure phase diagram agrees with…

Effects of superconducting fluctuation (SCF) on thermodynamic properties of electron systems in the so-called BCS-BEC-crossover regime are studied. As the attractive interaction between electrons becomes stronger upon approaching the…

We discuss various mechanisms for the creation of an asymmetric charge fluctuation with respect to the reaction plane among hadrons emitted in relativistic heavy-ion collisions. We show that such mechanisms exist in both, the hadronic gas…

A general theory of electric charge is proposed. It is based on two phenomenologies. Electric charge mutation and conservation law. Three charges $\{ +, - ,0\}$ transformations physics succeeds. Quantum field theory underlies corresponding…

We investigate low-temperature electronic states of the series of organic conductors $\beta^{\prime\prime}$-(BEDT-TTF)$_4$[(H$_3$O)M(C$_2$O$_4$)$_3$]G, where BEDT-TTF is bis(ethylenedithio)tetrathiafulvalene, and M and G represent trivalent…

An existence of the charge-induced instability is well known for the 4He crystal surface in the rough state. Much less is known about charge-induced instability at the 4He crystal surface in the smooth well-faceted state below the…

We use inelastic neutron scattering to study the crystalline electric field (CEF) excitations of Ce$^{3+}$ in CeFeAsO$_{1-x}$F$_{x}$($x=0,0.16$). For nonsuperconducting CeFeAsO, the Ce CEF levels have three magnetic doublets in the…

CeCd$_3$P$_3$ and CeCd$_3$As$_3$ compounds adopt the hexagonal ScAl$_3$C$_3$-type structure, where magnetic Ce ions on a triangular lattice order antiferromagnetically below $T_\text{N} \sim$0.42~K. Their crystalline electric field (CEF)…

Experiments with $\Omega^{\pm}$ baryons moving in a crystal at LHC in addition to EDM measurement open possibility to study electric quadrupole moment, to observe birefringence effect (spin oscillations and spin dichroism) for…

Polar antiferromagnetic metals have recently garnered increasing interests due to their combined traits of both ferromagnets and antiferromagnets for spintronic applications. However, the inherently incompatible nature of antiferromagnet,…

The concept of charge-transfer (CT) transitions in ferrites is based on the cluster approach and takes into account the relevant interactions as the low-symmetry crystal field, spin-orbital, Zeeman, exchange and exchange-relativistic…

The energy shift in molecular spectra due to interaction of nuclear magnetic quadrupole moment ($M$) with electrons is equal to $\delta E_M = MW_M P_{ M}$, where $W_M$ is a constant determined by the electronic structure of the molecule and…

The interplay of magnetic correlations, crystal electric field interactions, and spin-orbit coupling in low-dimensional frustrated magnets fosters novel ground states with unusual excitations. Here, we report the magnetic properties and…

Two-dimensional electron gases are predicted to possess an anomalous ''tomographic'' transport regime that is marked by an odd-even effect in the relaxation times, with odd-parity deformations of the Fermi surface becoming long-lived in…

We perform model calculations for a stretched LiF molecule, demonstrating that nonadiabatic charge transfer effects can be accurately and seamlessly described within a density functional framework. In alkali halides like LiF, there is an…

To elucidate a novel pressure-temperature phase diagram of the quasi-one-dimensional mixed-stack charge-transfer (CT) complex TTF-CA, we study the quasi-one-dimensional spin-1 Blume-Emery-Griffith (BEG) model. In addition to the local…