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There has been interest in finding a general variational principle for non-equilibrium statistical mechanics. We give evidence that Maximum Caliber (Max Cal) is such a principle. Max Cal, a variant of Maximum Entropy, predicts dynamical…

统计力学 · 物理学 2015-09-02 Michael J. Hazoglou , Valentin Walther , Purushottam D. Dixit , Ken A. Dill

We review here {\it Maximum Caliber} (Max Cal), a general variational principle for inferring distributions of paths in dynamical processes and networks. Max Cal is to dynamical trajectories what the principle of {\it Maximum Entropy} (Max…

We investigate the maximum caliber variational principle as an inference algorithm used to predict dynamical properties of complex nonequilibrium, stationary, statistical systems in the presence of incomplete information. Specifically, we…

统计力学 · 物理学 2016-12-28 Carlo Cafaro , Sean Alan Ali

A theory to predict the steady state position of a dissipative, flow-controlled system, as defined by a control volume, is developed based on the Maximum Entropy (MaxEnt) principle of Jaynes, involving minimisation of a generalised free…

经典物理 · 物理学 2015-05-13 Robert K. Niven

We introduce the new concept of maximal dissipative solutions for a general class of isothermal GENERIC systems. Under certain assumption, we show that maximal dissipative solutions are well posed as long as the bigger class of dissipative…

偏微分方程分析 · 数学 2023-12-22 Robert Lasarzik

Jaynes' maximum entropy (MaxEnt) principle was recently used to give a conditional, local derivation of the ``maximum entropy production'' (MEP) principle, which states that a flow system with fixed flow(s) or gradient(s) will converge to a…

流体动力学 · 物理学 2015-05-13 Robert K. Niven

Application of the information-theoretic Maximum Caliber principle to the microtrajectories of a two-state system shows that the determination of key dynamical quantities can be mapped onto the evaluation of properties of the 1-D Ising…

生物物理 · 物理学 2010-08-17 Sarah Marzen , Dave Wu , Mandar Inamdar , Rob Phillips

We identify a class maximal dissipative solutions to models of compressible viscous fluids that maximize the energy dissipation rate. Then we show that any maximal dissipative solution approaches an equilibrium state for large times.

偏微分方程分析 · 数学 2021-05-26 Eduard Feireisl , Young-Sam Kwon , Antonin Novotny

Markov models are widely used to describe processes of stochastic dynamics. Here, we show that Markov models are a natural consequence of the dynamical principle of Maximum Caliber. First, we show that when there are different possible…

统计力学 · 物理学 2015-05-28 Hao Ge , Steve Presse , Kingshuk Ghosh , Ken Dill

Important models of nonequilibrium statistical physics (NESP) are limited by a commonly used, but often unrecognized, near-equilibrium approximation. Fokker-Planck and Langevin equations, the Einstein and random-flight diffusion models, and…

统计力学 · 物理学 2023-03-09 Jonathan Asher Pachter , Ken A. Dill

Computer simulations generate microscopic trajectories of complex systems at a single thermodynamic state point. We recently introduced a Maximum Caliber (MaxCal) approach for dynamical reweighting. Our approach mapped these trajectories to…

统计力学 · 物理学 2021-04-14 Marius Bause , Tristan Bereau

This study examines a new formulation of non-equilibrium thermodynamics, which gives a conditional derivation of the ``maximum entropy production'' (MEP) principle for flow and/or chemical reaction systems at steady state. The analysis uses…

种群与进化 · 定量生物学 2009-08-25 Robert K. Niven

In this paper, we study the problem of extremum seeking control for mechanical systems in dissipation-free environments. This includes attitude control of satellites in space and displacement control of rigid bodies in ideal fluids. The…

最优化与控制 · 数学 2022-11-30 Raik Suttner , Miroslav Krstic

Statistical physics aims to describe properties of macroscale systems in terms of distributions of their microscale agents. Its central tool is the maximization of entropy, a variational principle. We review the history of this principle,…

统计力学 · 物理学 2023-10-11 Jonathan Asher Pachter , Ying-Jen Yang , Ken A. Dill

A statistical, path-dependent framework to describe time-dependent macroscopic theories using the Principle of Maximum Caliber is presented. By means of this procedure, it is possible to infer predictive non-equilibrium statistical…

统计力学 · 物理学 2023-03-20 Ignacio Tapia , Gonzalo Gutiérrez , Sergio Davis

We introduce the concept of maximal dissipative measure-valued solution to the complete Euler system. These are solutions that maximize the entropy production rate. We show that these solutions exist under fairly general hypotheses imposed…

偏微分方程分析 · 数学 2017-12-14 Jan Brezina , Eduard Feireisl

The maximum entropy principle (MEP) apparently allows us to derive, or justify, fundamental results of equilibrium statistical mechanics. Because of this, a school of thought considers the MEP as a powerful and elegant way to make…

统计力学 · 物理学 2015-12-09 Gennaro Auletta , Lamberto Rondoni , Angelo Vulpiani

We present a principled approach for estimating the matrix of microscopic rates among states of a Markov process, given only its stationary state population distribution and a single average global kinetic observable. We adapt Maximum…

统计力学 · 物理学 2014-02-17 Purushottam D. Dixit , Ken A. Dill

We investigate the three-dimensional compressible Euler-Maxwell system, a model for simulating the transport of electrons interacting with propagating electromagnetic waves in semiconductor devices. First, we show the global well-posedness…

偏微分方程分析 · 数学 2024-07-02 Timothée Crin-Barat , Yue-Jun Peng , Ling-Yun Shou , Jiang Xu

In the last few decades, some hypotheses for entropy production (EP) principles have been forwarded as possible candidates for organizational principles in non-linear non- equilibrium systems. Two important hypotheses will be studied: the…

化学物理 · 物理学 2007-05-23 Stijn Bruers
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