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The issue of the stability of Pickering emulsions is tackled at a mesoscopic level using dissipative particle dynamics simulations within the Adiabatic Biased Molecular Dynamics framework. We consider the early stage of the coalescence…
The stability of shapes formed by three viscoelastic droplets during their arrested coalescence has been investigated using micromanipulation experiments. Addition of a third droplet to arrested droplet doublets is shown to be controlled by…
Combining high-speed photography with electric current measurement, we investigate the electrocoalescence of Pickering emulsion droplets. Under high enough electric field, the originally-stable droplets coalesce via two distinct approaches:…
We study the stability of a model Pickering emulsion system. A special counter-flow microfluidics set-up was used to prepare monodisperse Pickering emulsions, with oil droplets in water. The wettability of the monodisperse silica…
We present a quantitative confocal-microscopy study of the transient and final microstructure of particle-stabilised emulsions formed via demixing in a binary liquid. To this end, we have developed an image-analysis method that relies on…
Drop coalescence is central to diverse processes involving dispersions of drops in industrial, engineering and scientific realms. During coalescence, two drops first touch and then merge as the liquid neck connecting them grows from…
Droplet coalescence is ubiquitous in nature and the same time key to various technologies, such as inkjet printing. Here, we report on the coalescence of polymer droplets with different chain lengths coalescing on substrates of different…
A mixture of hard-sphere particles and model emulsion droplets is studied with a Brownian dynamics simulation. We find that the addition of nonwetting emulsion droplets to a suspension of pure hard spheres can lead to both gas-liquid and…
The stable configurations formed by two viscoelastic, ellipsoid-shaped droplets during their arrested coalescence has been investigated using micromanipulation experiments. Ellipsoidal droplets are produced by millifluidic emulsification of…
Phase separation in passive systems leads to uncontrolled droplet growth, limiting structural control in soft materials and cells. We identify a generic mechanism to arrest coarsening based on chemical interconversion between molecular…
The dynamical perspectives of bubble in a liquid droplet on smooth solid substrate can be revealed by investigating interfacial self-assembly phenomena. Moreover, the complexity in such system can be scaled down into a transparent immobile…
There is a large debate on the destabilization mechanism of emulsions. We present a simple technique using mechanical compression to destabilize oil-in-water emulsions. Upon compression of the emulsion, the continuous aqueous phase is…
The coalescence of droplets plays a crucial role in nature and modern technology. Various experimental and theoretical studies explored droplet dynamics in 3D and on 2D solid or liquid substrates. In this paper, we demonstrate the…
Drying a droplet of colloidal dispersion can result in complex pattern formation due to both development and deformation of a skin at the drop surface. The present study focus on the drying process of droplets of colloidal dispersions in a…
The coalescence of water drops on a substrate is studied experimentally. We focus on the rapid growth of the bridge connecting the two drops, which very quickly after contact ensues from a balance of surface tension and liquid inertia. For…
Particle-stabilized emulsions are commonly used in various industrial applications. These emulsions can present in different forms, such as Pickering emulsions or bijels, which can be distinguished by their different topologies and…
The thermodynamic stability of emulsions of liquid crystal in water (glycerol) matrices is demonstrated for a wide range of materials and concentrations. Coalescence is prevented by an energy barrier for a topological ring defect formation…
The breakup and coalescence of drops are elementary topological transitions in interfacial flows. The breakup of a drop changes dramatically when polymers are added to the fluid. With the strong elongation of the polymers during the…
We investigate the 3D structure and drying dynamics of complex mixtures of emulsion droplets and colloidal particles, using confocal microscopy. Air invades and rapidly collapses large emulsion droplets, forcing their contents into the…
We consider an emulsion whose droplets contain a trapped species (insoluble in the continuous phase), and study the emulsion's stability against coarsening via Lifshitz-Slyozov dynamics (Ostwald Ripening). Extending an earlier treatment by…