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Excitonic effects in optical spectra and electron-hole pair excitations are described by solutions of the Bethe-Salpeter equation (BSE) that accounts for the Coulomb interaction of excited electron-hole pairs. Although for the computation…

其他凝聚态物理 · 物理学 2008-08-20 F. Fuchs , C. Rödl , A. Schleife , F. Bechstedt

The Bethe-Salpeter Equation (BSE) can be applied to compute from first-principles optical spectra that include the effects of screened electron-hole interactions. As input, BSE calculations require single-particle states, quasiparticle…

材料科学 · 物理学 2020-01-01 Joshua Elliott , Nicola Colonna , Margherita Marsili , Nicola Marzari , Paolo Umari

We present a method for computing optical absorption spectra by means of a Bethe-Salpeter equation approach, which is based on a conserving linear response calculation for electron-hole coherences in the presence of an external…

材料科学 · 物理学 2010-12-21 George Pal , Yaroslav Pavlyukh , Wolfgang Hübner , Hans Christian Schneider

We present a computational approach for exciton calculations in two-dimensional (2D) materials within the Bethe-Salpeter equation (BSE) framework, employing an atomistic description with point-like orbitals. Unlike widespread efficient…

介观与纳米尺度物理 · 物理学 2026-03-12 P. Ninhos , A. J. Uría-Álvarez , C. Tserkezis , N. A. Mortensen , J. J. Palacios

We present a highly efficient method for the extraction of optical properties of very large molecules via the Bethe-Salpeter equation. The crutch of this approach is the calculation of the action of the effective Coulombic interaction, $W$,…

化学物理 · 物理学 2022-08-10 Nadine Bradbury , Minh Nguyen , Justin R Caram , Daniel Neuhauser

The Bethe-Salpeter equation (BSE) is currently the state of the art in the description of neutral electron excitations in both solids and large finite systems. It is capable of accurately treating charge-transfer excitations that present…

The Bethe-Salpeter equation (BSE) is a powerful theoretical approach that is capable to accurately treat electron-hole interactions in materials in an excited state. We developed an ab initio framework based on the BSE to describe a…

材料科学 · 物理学 2026-05-19 Nasrin Farahani , Daria Popova-Gorelova

In order to realize the significant potential of optical materials such as metal halides, computational techniques which give accurate optical properties are needed, which can work hand-in-hand with experiments to generate high efficiency…

材料科学 · 物理学 2021-03-04 Jamie M. Booth , Mike V. Klymenko , Jared H. Cole , Salvy P. Russo

We present an efficient way to solve the Bethe-Salpeter equation (BSE), a model for the computation of absorption spectra in molecules and solids that includes electron-hole excitations. Standard approaches to construct and diagonalize the…

The Bethe-Salpeter equation (BSE) can provide an accurate description of low-energy optical spectra of insulating crystals - even when excitonic effects are important. However, due to high computational costs it is only possible to include…

We present a massively parallel, GPU-accelerated implementation of the Bethe-Salpeter equation (BSE) for the calculation of the vertical excitation energies (VEEs) and optical absorption spectra of condensed and molecular systems, starting…

材料科学 · 物理学 2024-12-25 Victor Wen-zhe Yu , Yu Jin , Giulia Galli , Marco Govoni

It is well known that the ambient environment can dramatically renormalize the quasiparticle gap and exciton binding energies in low-dimensional materials, but the effect of the environment on the energy splitting of the spin-singlet and…

材料科学 · 物理学 2021-02-03 Diana Y. Qiu , Felipe H. da Jornada , Steven G. Louie

In this work we present a new procedure to compute optical spectra including excitonic effects and approximated quasiparticle corrections with reduced computational effort. The excitonic effects on optical spectra are included by solving…

材料科学 · 物理学 2020-08-26 Filipe Matusalem , Marcelo Marques , Ivan Guilhon , Lara K. Teles

Here we describe an efficient numerical implementation of the Bethe-Salpeter equation to obtain the excitonic spectrum of semiconductors. This is done on the electronic structure calculated either at the simplest tight-binding level or…

We present a screened exact-exchange (SXX) method for the efficient and accurate calculation of the optical properties of solids, where the screening is achieved through the zero-wavevector limit of the inverse dielectric function. The SXX…

材料科学 · 物理学 2015-01-23 Zeng-hui Yang , Francesco Sottile , Carsten A. Ullrich

The lowest electronic excitations of benzene and a set of donor-acceptor molecular complexes are calculated for the gas phase and on the Al(111) surface using the many-body Bethe-Salpeter equation (BSE). The energy of the charge-transfer…

介观与纳米尺度物理 · 物理学 2015-05-27 J. M. Garcia-Lastra , K. S. Thygesen

The Bethe-Salpeter equation (BSE) formalism is a computationally affordable method for the calculation of accurate optical excitation energies in molecular systems. Similar to the ubiquitous adiabatic approximation of time-dependent…

化学物理 · 物理学 2020-09-22 Pierre-François Loos , Xavier Blase

We present an efficient implementation of the Bethe-Salpeter equation (BSE) method for obtaining core-level spectra including x-ray absorption (XAS), x-ray emission (XES), and both resonant and non-resonant inelastic x-ray scattering…

We present an energy-specific Bethe-Salpeter equation (BSE) implementation for efficient core and valence optical spectrum calculations. In energy-specific BSE, high-lying excitation energies are obtained by constructing trial vectors and…

材料科学 · 物理学 2025-01-29 Christopher Hillenbrand , Jiachen Li , Tianyu Zhu

Many-body effects are known to play a crucial role in the electronic and optical properties of solids and nano-structures. Nevertheless the majority of theoretical and numerical approaches able to capture the influence of Coulomb…

材料科学 · 物理学 2015-05-30 C. Attaccalite , M. Grüning , A. Marini
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