相关论文: Jensen Inequality and the Second Law
The Jarzynski equality (JE) is a remarkable statement relating transient irreversible processes to infinite-time free energy differences. Although twenty years old, the JE remains unfamiliar to many; nevertheless it is a robust and powerful…
The purpose of this work is to discuss recent progress in deriving the fundamental laws of thermodynamics (0th, 1st and 2nd-law) from nonequilibrium quantum statistical mechanics. Basic thermodynamic notions are clarified and different…
The Jarzynski equality is generalized to situations in which nonequilibrium systems are subject to a feedback control. The new terms that arise as a consequence of the feedback describe the mutual information content obtained by measurement…
The second law of thermodynamics is a statement about the statistics of the entropy production, $\langle \Sigma \rangle \geq 0$. For small systems, it is known that the entropy production is a random variable and negative values ($\Sigma <…
Fluctuation theorems impose constraints on possible work extraction probabilities in thermodynamical processes. These constraints are stronger than the usual second law, which is concerned only with average values. Here, we show that such…
This chapter reviews an information theoretic approach to deriving quantum fluctuation theorems. When a thermal system is driven from equilibrium, random quantities of work are required or produced: the Crooks equality is a classical…
The nonequilibrium work relation, or Jarzynski equality, establishes a statistical relationship between a series of nonequilibrium experiments on a system subjected to thermal fluctuations and a hypothetical experiment at thermodynamic…
In a recent work, Jarzynski and Wojcik (2004 Phys. Rev. Lett. 92, 230602) have shown by using the properties of Hamiltonian dynamics and a statistical mechanical consideration that, through contact, heat exchange between two systems…
The housekeeping heat $Q\hk$ is the dissipated heat necessary to maintain the violation of detailed balance in nonequilibrium steady states. By analyzing the evolution of its probability distribution, we prove an integral fluctuation…
The example of macroscopic thermodynamical system violating the Clausius inequality is presented.
A.E. Allahverdyan and Th. M. Nieuwenhuizen [1] in their paper "A mathematical theorem as a basis for the second law: Thomson's formulation applied to equilibriium" present a proof of the second law of thermodynamics based on quantum…
Characterizing fluctuations of work in coherent quantum systems is notoriously problematic. Here we reveal the ultimate source of the problem by proving that ($\mathfrak{A}$) energy conservation and ($\mathfrak{B}$) the Jarzynski…
In a thermodynamic process with measurement and feedback, the second law of thermodynamics is no longer valid. In its place, various second-law-like inequalities have been advanced that each incorporate a distinct additional term accounting…
We study the thermodynamics of quantum projective measurements by using the set up for the Jarzynski equality. We prove the fluctuations of energy change induced by measurements satisfy the Jarzynski equality, revealing that the quantum…
The second law of thermodynamics is a fundamental law of Nature. It is almost universally associated with the Clausius inequality that lower bounds a change in entropy by the ratio of supplied heat and temperature. However, this result…
The Clausius inequality (CI) form of the second law of thermodynamics relates information changes (entropy) to changes in the first moment of the energy (heat and indirectly also work). Are there similar relations between other moments of…
We establish quantum thermodynamics for open quantum systems weakly coupled to their reservoirs when the system exhibits degeneracies. The first and second law of thermodynamics are derived, as well as a finite-time fluctuation theorem for…
For a small driven system coupled strongly to a heat bath, internal energy and exchanged heat are identified such that they obey the usual additive form of the first law. By identifying this exchanged heat with the entropy change of the…
In a thermodynamical process, the dissipation or production of entropy can only be positive or zero according to the second law of thermodynamics. However the laws of thermodynamics are applicable to large systems in the thermodynamic…
We study two non-equilibrium work fluctuation theorems, the Crooks' theorem and the Jarzynski equality, for a test system coupled to a spatially extended heat reservoir whose degrees of freedom are explicitly modeled. The sufficient…