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For macroscopic systems, the second law of thermodynamics establishes an inequality between the amount of work performed on a system in contact with a thermal reservoir, and the change in its free energy. For microscopic systems, this…

统计力学 · 物理学 2010-02-08 Eliran Boksenbojm , Bram Wynants , Christopher Jarzynski

Recently, there has been a considerable progress on the issue of the thermodynamic second law, which is known as the law of entropy increase or irreversibility. In particular, a novel symmetry known as the Gallavotti-Cohen symmetry is found…

统计力学 · 物理学 2018-08-01 Hyunggyu Park

We proved when random-variable fluctuations obey the central limit theorem the equality of the uncertainty relation corresponds to the thermodynamic equilibrium state. The inequality corresponds to the thermodynamic non-equilibrium state.…

量子物理 · 物理学 2007-05-23 You-gang Feng

We reconsider a well-known relationship between the fluctuation theorem and the second law of thermodynamics by evaluating a probability measure-valued process. In order to establish a bridge between microscopic and macroscopic behaviors,…

统计力学 · 物理学 2015-03-19 Yuki Sughiyama , Masayuki Ohzeki

Fluctuation theorems are fundamental extensions of the second law of thermodynamics for small nonequilibrium systems. While work and heat are equally important forms of energy exchange, fluctuation relations have not been experimentally…

Thermodynamic systems involving reversible and non-reversible heat transfer are used to derive integral inequalities expected from the Second of Law of Thermodynamics. Then, the inequalities are proved and generalized to higher dimensions…

经典分析与常微分方程 · 数学 2019-01-01 Anuj S. Apte

We investigate non-equilibrium nature of fluctuations of black hole horizons by applying the fluctuation theorems and the Jarzynski equality developed in the non-equilibrium statistical physics. These theorems applied to space-times with…

广义相对论与量子宇宙学 · 物理学 2015-05-19 Satoshi Iso , Susumu Okazawa , Sen Zhang

At the dawn of thermodynamics, Carnot's constraint on efficiency of heat engines stimulated the formulation of one of the most universal physical principles, the second law of thermodynamics. In recent years, the field of heat engines…

统计力学 · 物理学 2021-12-23 Viktor Holubec , Artem Ryabov

We investigate the connection between recent results in quantum thermodynamics and fluctuation relations by adopting a fully quantum mechanical description of thermodynamics. By including a work system whose energy is allowed to fluctuate,…

量子物理 · 物理学 2017-03-27 Álvaro M. Alhambra , Lluis Masanes , Jonathan Oppenheim , Christopher Perry

The crucial condition in the derivation of the Jarzynski equality (JE) from the fluctuation theorem is that the time integral of the phase space contraction factor can be exactly expressed as the entropy production resulting from the heat…

统计力学 · 物理学 2015-06-25 Z. C. Tu , Zicong Zhou

Fluctuations of thermodynamic observables, such as heat and work, contain relevant information on the underlying physical process. These fluctuations are however not taken into account in the traditional laws of thermodynamics. While the…

量子物理 · 物理学 2022-05-25 Timo Kerremans , Peter Samuelsson , Patrick P. Potts

For a two-level quantum mechanical system, we derive microscopically the exact expression for the fluctuation of microscopic work in a multi-step non-equilibrium process, and we rigorously prove that in an isothermal process, the…

统计力学 · 物理学 2008-08-19 H. T. Quan , S. Yang , C. P. Sun

All presently available results lead to the conclusion that nonextensivity, in the sense of nonextensive statistical mechanics (i.e., $q \ne 1$), does {\it not} modify anything to the second principle of thermodynamics, which therefore…

统计力学 · 物理学 2017-08-23 Constantino Tsallis

The Jarzynski equality, which relates equilibrium free-energy difference to an average of non-equilibrium work, plays a central role in modern non-equilibrium statistical thermodynamics. In this paper, we study a weaker consequence of this…

统计力学 · 物理学 2026-01-06 Dani R. Castellanos , Petr Jizba

The fluctuation theorem is the fundamental equality in nonequilibrium thermodynamics that is used to derive many important thermodynamic relations, such as the second law of thermodynamics and the Jarzynski equality. Recently, the…

统计力学 · 物理学 2019-09-16 Yoshihiko Hasegawa , Tan Van Vu

There are two related theorems which hold even in far from equilibrium, namely fluctuation theorem and Jarzynski equality. Fluctuation theorem states the existence of symmetry of fluctuation of entropy production, while Jarzynski equality…

统计力学 · 物理学 2009-11-10 T. Monnai

The Fluctuation Theorem describes the probability ratio of observing trajectories that satisfy or violate the second law of thermodynamics. It has been proved in a number of different ways for thermostatted deterministic nonequilibrium…

统计力学 · 物理学 2009-10-31 Debra J. Searles , Denis J. Evans

Fluctuation theorems are fundamental extensions of the second law of thermodynamics for small systems. Their general validity arbitrarily far from equilibrium makes them invaluable in nonequilibrium physics. So far, experimental studies of…

Materials that are constantly driven out of thermodynamic equilibrium, such as active and living systems, typically violate the Einstein relation. This may arise from active contributions to particle fluctuations which are unrelated to the…

统计力学 · 物理学 2025-01-07 Benjamin Sorkin , Haim Diamant , Gil Ariel , Tomer Markovich

We consider a time-dependent quantum linear oscillator coupled to a bath at an arbitrary strength. We then introduce a generalized Jarzynski equality (GJE) which includes the terms reflecting the system-bath coupling. This enables us to…

统计力学 · 物理学 2014-03-03 Ilki Kim
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