相关论文: Generalized single-parameter aging tests and their…
A high-resolution calorimetric spectroscopy study has been performed on pure glycerol and colloidal dispersions of an aerosil in glycerol covering a wide range of temperatures from 300 K to 380 K, deep in the liquid phase of glycerol. The…
Experiments performed on a wide range of glassy materials display many interesting phenomena, such as aging behavior. In recent years, a large body of experiments probed this nonequilibrium glassy dynamics through elaborate protocols, in…
We present the results of aging experiments on a variety of glass formers, including xylitol, glycerol, propylene carbonate, and [Ca(NO3)2]0.4[KNO3]0.6 (CKN). In addition, broadband dielectric spectra of xylitol and CKN are provided. We…
Dielectric data on glycerol and propylene carbonate covering 18 decades of frequency are presented and compared to each other. Both materials exhibit qualitatively similar behavior except for marked differences in the high-frequency region…
Molecular dynamics simulations are used to investigate the connection between thermal history and physical aging in polymer glasses, in particular the effects of a temperature square step. Measurements of two-time correlation functions show…
Glycerol acts as a natural cryoprotectant by depressing the temperature of ice nucleation and slowing down the dynamics of water mixtures. In this work we characterize dynamics -- diffusion, viscosity, and hydrogen-bond dynamics -- as well…
Low frequency dielectric measurements on plexiglass (PMMA) show that cooling and heating the sample at constant rate give an hysteretic dependence on temperature of the dielectric constant $\epsilon$. A temporary stop of cooling produces a…
Dielectric spectroscopy is one of the most commonly used techniques for the investigation of the dynamic response of glass-forming materials. The tremendous slow-down of the particle motions when approaching the glass transition and…
Intriguing phenomena such as subrecoil laser cooling of atoms, or aging phenomenon in glasses, have in common that the systems considered do not reach a steady-state during the experiments, although the experimental time scales are very…
We search for a Gardner transition in glassy glycerol, a standard molecular glass, measuring the third harmonics cubic susceptibility $\chi_3^{(3)}$ from slightly below the usual glass transition temperature down to $10K$. According to the…
The frequency dependent specific heat has been measured under pressure for the molecular glass forming liquid 5-polyphenyl-4-ether in the viscous regime close to the glass transition. The temperature and pressure dependence of the…
In the present work, we employ broadband dielectric spectroscopy to study the molecular dynamics of the prototypical glass former glycerol confined in two microporous zeolitic imidazolate frameworks (ZIF-8 and ZIF-11) with well-defined pore…
The aging of aggregated structures of monoglycerides in hydrophobic medium is described by a set of different techniques. Polarized microscopy was used to study the mesomorphic behavior as a function of time. Differential scanning…
Mean square displacements of hydrogen atoms in glass-forming materials and proteins, as reported by incoherent elastic neutron scattering, show kinks in their temperature dependence. This crossover, known as the dynamical transition,…
We introduce a new quantity to probe the glass transition. This quantity is a linear generalized compressibility which depends solely on the positions of the particles. We have performed a molecular dynamics simulation on a glass forming…
Experiments performed in the last years demonstrated slow relaxations and aging in the conductance of a large variety of materials. Here, we present experimental and theoretical results for conductance relaxation and aging for the…
We assess the relative importance of spatial congestion and lowered temperature in the slowing dynamics of supercooled glycerol near the glass transition. We independently vary both volume, V, and temperature, T, by applying high pressure…
Using molecular dynamics computer simulations we investigate the out-of-equilibrium dynamics of a Lennard-Jones system after a quench from a high temperature to one below the glass transition temperature. By studying the radial distribution…
We have measured, as a function of the age $t_a$, the aging of the nonlinear dielectric susceptibility $\chi_3$ of glycerol below the glass transition. Whereas the linear susceptibility can be accurately accounted for in terms of an age…
This paper presents data for the physical aging of the three monoalcohols 2-ethyl-1-butanol, 5-methyl-2-hexanol, and 1-phenyl-1-propanol. Aging is studied by monitoring the dielectric loss at a fixed frequency in the kHz range following…