相关论文: Probing the link between residual entropy and visc…
It is shown that the residual entropy (entropy minus that of the ideal gas at the same temperature and density) is mostly synonymous with the independent variable of density scaling, identifying a direct link between these two approaches.…
Rosenfeld [Phys. Rev. A 15, 2545 (1977)] noticed that casting transport coefficients of simple monatomic, equilibrium fluids in specific dimensionless forms makes them approximately single-valued functions of excess entropy. This has…
Diffusion-a measure of dynamics, and entropy-a measure of disorder in the system, are found to be intimately correlated in many systems, and the correlation is often strongly non-linear. We explore the origin of this complex dependence by…
The residual multiparticle entropy (RMPE) of a fluid is defined as the difference, $\Delta s$, between the excess entropy per particle (relative to an ideal gas with the same temperature and density), $s_\text{ex}$, and the pair-correlation…
We use molecular dynamics simulation results on viscous binary Lennard-Jones mixtures to examine the correlation between the potential energy and the virial. In accord with a recent proposal [U. R. Pedersen et. al. Phys. Rev. Lett. 100,…
Anomalous behaviour of the excess entropy ($S_e$) and the associated scaling relationship with diffusivity are compared in liquids with very different underlying interactions but similar water-like anomalies: water (SPC/E and TIP3P models),…
Computer simulations are used to test whether a recently introduced generalization of Rosenfeld's excess-entropy scaling method for estimating transport coefficients in systems obeying molecular dynamics can be extended to predict long-time…
We show that the existence of the water-like anomalies in kinetic coefficients in the core-softened systems depends on the trajectory in $\rho-T$ plane along which the kinetic coefficients are calculated. In particular, it is shown that the…
Effects of dynamical long-range correlations over a fluid cell size scale on a relativistic fluid are discussed. It is shown that such correlations among the fluid elements introduced into hydrodynamical model induce some weak dissipation…
Several correlations between viscosity and surface tension for saturated normal fluids have been proposed in the literature. Usually, they include three or four adjustable coefficients for every fluid and give generally good results. In…
In the present article we carry out a molecular dynamics study of the core-softened system and show that the existence of the water-like anomalies in this system depends on the trajectory in $P-\rho-T$ space along which the behavior of the…
This paper discusses the possible relation between entropy and the relaxation time of liquids, in particular glass-forming systems, providing supplementing comments to the paper entitled "A brief critique of the Adam-Gibbs entropy model" by…
We analyze the applicability of the Rosenfeld entropy scaling relations to the systems with the core-softened potentials demonstrating the water-like anomalies. It is shown that the validity of the of Rosenfeld scaling relation for the…
The microscopic dynamics of objects suspended in a fluid determines the macroscopic rheology of a suspension. For example, as shown by Danker and Misbah [Phys. Rev. Lett. {\bf 98}, 088104 (2007)], the viscosity of a dilute suspension of…
The crucial problem for better understanding the nature of glass transition and related relaxation phenomena is to find proper interrelations between molecular dynamics and thermodynamics of viscous systems. To gain this aim the recently…
We explore the relationship between a machine-learned structural quantity (softness) and excess entropy in simulations of supercooled liquids. Excess entropy is known to scale well the dynamical properties of liquids, but this…
We discuss the validity and the outcome of a scaling hypothesis proposed by us some years ago, according to which the influence of the density on the slowing down of flow and relaxation in glassforming liquids and polymers is described…
The off-center collision of binary bouncing droplets of equal size was studied numerically by a volume-of-fluid (VOF) method with two marker functions, which has been validated by comparing with available experimental results. A…
Starting from relativistic quantum field theories, Kovtun et al. (2005) have quite recently proposed a lower bound eta/s >= hbar /(4 pi kB), where eta is the shear viscosity and s the volume density of entropy for dense liquids. If their…
In this perspective review, we present a concise yet multifaceted overview of the pivotal role played by the the shear viscosity to entropy density ratio across various physical contexts. After summarizing some of the main aspects of the…