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Ultrathin passive films effectively prevent the chemical attack of stainless steel grades in corrosive environments; their stability critically depends on the interplay between structure and chemistry of the constituents Fe-Cr-Mo. In…

The durability of passivable metals and alloys is often limited by the stability of the surface oxide film, the passive film, providing self-protection against corrosion in aggressive environments. Improving this stability requires to…

材料科学 · 物理学 2019-07-26 Li Ma , Frederic Wiame , Vincent Maurice , Philippe Marcus

Understanding elemental corrosion currents and visualizing corroding topographies provide a detailed insight into corrosion mechanisms at the nano-scale. Here, we develop a strategy to understand the elemental composition, corrosion…

应用物理 · 物理学 2021-04-16 Dominik Dworschak , Marina Bishara , Hsiu-Wei Cheng , Markus Valtiner

Time of Flight Secondary Ion Mass Spectroscopy, X-Ray Photoelectron Spectroscopy, in situ Photo-Current Spectroscopy and electrochemical analysis were combined to characterize the physicochemical alterations induced by electrochemical…

If metal surfaces are exposed to sufficiently oxygen-rich environments, oxides start to form. Important steps in this process are the dissociative adsorption of oxygen at the surface, the incorporation of O atoms into the surface, the…

材料科学 · 物理学 2007-05-23 Karsten Reuter

Pitting corrosion is a much-studied and technologically relevant subject. However, the fundamental mechanisms responsible for the breakdown of the passivating oxide layer are still subjects of debate. Chloride anions are known to accelerate…

材料科学 · 物理学 2021-07-07 Kevin Leung

Hydrogen fuel cells offer a clean and sustainable energy conversion solution. The bipolar separator plate, a critical component in fuel cells, plays a vital role in preventing reactant gas cross-contamination and facilitating efficient ion…

材料科学 · 物理学 2023-08-31 Taemin Ahn , Tae-Hwan Kim

We report on the electrical characterisation of a series of thin chromium oxide films, grown by dc sputtering, to evaluate their suitability for use as on-chip resistors in nanoelectronics. By increasing the level of oxygen doping, the…

介观与纳米尺度物理 · 物理学 2015-06-22 C. R. Nash , J. C. Fenton , N. G. N. Constantino , P. A. Warburton

Equiatomic CoCrNi medium entropy alloys are known for their unique properties linked to chemical short-range order (CSRO), crucial in both percolation processes and/or nucleation and growth processes influencing alloy passivation in aqueous…

In recent years, many new materials have been developed and prepared to improve the performance of light-harvesting technologies and to develop new and attractive applications. The problem of stability of long-term operation of various…

应用物理 · 物理学 2023-09-28 O. Y. Semchuk , T. Gatti , S. Osella

This review covers the important advances in recent years in the physics of thin film ferroelectric oxides, the strongest emphasis being on those aspects particular to ferroelectrics in thin film form. We introduce the current state of…

材料科学 · 物理学 2009-11-11 M. Dawber , K. M. Rabe , J. F. Scott

A modeling approach, based on an analytical solution of the semiclassical multi-subband Boltzmann transport equation, is presented to study resistivity scaling in metallic thin films and nanowires due to grain boundary and surface roughness…

介观与纳米尺度物理 · 物理学 2017-01-26 Kristof Moors , Bart Sorée , Wim Magnus

Effective passivation of lithium metal surfaces, and prevention of battery-shorting lithium dendrite growth, are critical for implementing lithium-metal-anodes for batteries with increased power densities. Nanoscale surface heterogeneities…

材料科学 · 物理学 2017-10-03 Kevin Leung , Katherine L. Jungjohann

Resistive random-access memories, also known as memristors, whose resistance can be modulated by the electrically driven formation and disruption of conductive filaments within an insulator, are promising candidates for neuromorphic…

The low-temperature electrical resistivity of corrugated semiconductor films is theoretically considered. Nanoscale corrugation enhances the electron-electron scattering contribution to the resistivity, resulting in a stepwise resistivity…

介观与纳米尺度物理 · 物理学 2015-05-13 Shota Ono , Hiroyuki Shima

Some implants have approximately a lifetime of 15 years. The femoral stem, for example, should be made of 316L/316LN stainless steel. Fretting corrosion, friction under small displacements, should occur during human gait, due to repeated…

医学物理 · 物理学 2014-01-21 Jean Geringer , Mathew L. Taylor , Digby D. Macdonald

Nanocrystalline metals are promising radiation tolerant materials due to their large interfacial volume fraction, but irradiation-induced grain growth can eventually degrade any improvement in radiation tolerance. Therefore, methods to…

Oxide ceramics are sensitive to slow crack growth because adsorption of water can take place at the crack tip, leading to a strong decrease of the surface energy in humid (or air) conditions. This is a major drawback concerning demanding,…

Thin coatings of Chromium oxide have been used for applications as absorbing material in solar cells, as protections for magnetic data recording devices and as shields in flexible solar cells. Thin coatings of pure chromium were vacuum…

Manganite thin films are promising candidates for studying the strongly correlated electron systems. Understanding the growth-and morphology-driven changes in the physical properties of manganite thin films is vital for their applications…

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