相关论文: Quantum shape effects and novel thermodynamic beha…
Can we change the shape of a domain without altering its sizes? By introducing a size-invariant shape transformation, we propose the existence and explore the consequences of a new type of physical effect appearing at the quantum scales,…
Quantum shape effect appears under the size-invariant shape transformations of strongly confined structures. Such a transformation distinctively influences the thermodynamic properties of confined particles. Due to their characteristic…
Size-invariant shape transformation gives rise to the so-called quantum shape effect in strongly confined systems. While quantum size and shape effects are often thought to be difficult to distinguish because of their coexistence, it is…
We propose a mechanism for nanoscale energy conversion, an electric voltage induced by a temperature gradient in a junction composed of the same material having exactly the same geometric sizes, but distinct shapes. The proposed effect…
This study presents a unified description of the thermodynamics of ideal quantum gases under nanoscale confinement using a Quantum Phase Space (QPS) formalism. We show that the statistical momentum variances B_ll capture quantum degeneracy:…
Size-invariant shape transformation is a geometric technique that allows for a clear separation between quantum size and shape effects by modifying the shape of the confinement domain without altering its size. The impact of shape on the…
Tailoring energy levels in quantum systems via Hamiltonian control parameters is essential for designing quantum thermodynamic devices and materials. However, conventional methods for manipulating finite-size systems, such as tuning…
Quantum size effects on the permittivity of metal nanoparticles are investigated using the quantum box model. Explicit upper and lower bounds are derived for the permittivity and relaxation rates due to quantum confinement effects. These…
Size-invariant shape transformation is a technique of changing the shape of a domain while preserving its sizes under the Lebesgue measure. In quantum confined systems, this transformation leads to so-called quantum shape effects in the…
We calculate the spatial entanglement between two electrons trapped in a nanostructure for a broad class of confinement potentials, including single and double quantum dots, and core-shell quantum dot structures. By using a parametrized…
In this work, we investigate the effects of rotation on the physical properties of a quantum dot described by a radial potential and subjected to a rotating reference frame. The interplay between rotation and confinement is analyzed by…
We analyze thermodynamics of water samples confined in nanopores and prove that although the freezing temperature can be dramatically lower, the suppression of the ice nucleation leading to the freezing temperature depression is a truly…
We formulate a geometric framework for quasistatic thermodynamics in open quantum systems by parameterizing the dynamics on a control manifold. In the quasistatic limit, the system follows a manifold of stationary states, and the work…
How the geometry of nano-sized confinement affects dynamics of biomaterials is interesting yet poorly understood. An elucidation of structural details upon nano-sized confinement may benefit manufacturing pharmaceuticals in biomaterial…
In this work, we study the thermodynamic functions of quantum gases confined to spaces of various shapes, namely, a sphere, a cylinder, and an ellipsoid. We start with the simplest situation, namely, a spinless gas treated within the…
The relationship between thermodynamics and statistical physics is valid in the thermodynamic limit - when the number of particles becomes very large. Here, we study thermodynamics in the opposite regime - at both the nano scale, and when…
In recent years the problem of correct description of quantum fluids in the confined geometry at nanoscale length has emerged. It has been recognized that the quantum fluids at these circumstances can be considered as a new state of quantum…
We consider a system of $N$ particles living on the noncommutative plane in the presence of a confining potential and study its thermodynamics properties. Indeed, after calculating the partition function, we determine the corresponding…
Quantum thermodynamics is a powerful theoretical tool for assessing the suitability of quantum materials as platforms for novel technologies. In particular, the modeling of quantum cycles allows us to investigate the heat changes and work…
We analyze the quantum melting of two-dimensional Wigner molecules (WM) in confined geometries with distinct symmetries and compare it with corresponding thermal melting. Our findings unfold complementary mechanisms that drive the quantum…