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While lot of measurements describe the relaxation dynamics of the liquid state, experimental data of the glass dynamics at high temperatures are much scarcer. We use ultrafast scanning calorimetry to expand the timescales of the glass to…

Generic glass formers exhibit at least two characteristic changes in their relaxation behavior, first to an Arrhenius-type relaxation at some characteristic temperature, and then at a lower characteristic temperature to a super-Arrhenius…

无序系统与神经网络 · 物理学 2012-03-08 H. George E. Hentschel , Smarajit Karmakar , Itamar Procaccia , Jacques Zylberg

The phenomenon of the glass transition is an unresolved problem of condensed matter physics. Its prominent feature, the super-Arrhenius temperature dependence of the transport coefficients remains a challenge to be described over the full…

软凝聚态物质 · 物理学 2015-06-04 B. Schmidtke , N. Petzold , R. Kahlau , M. Hofmann , E. A. Rossler

The dynamical behavior of a kind of models with hierarchically constrained dynamics is investigated. The models exhibit many properties resembling real structural glasses. In particular, we focus on the study of time-dependent temperature…

统计力学 · 物理学 2009-11-07 A. Prados , J. J. Brey

A major mystery of glass-forming liquids is the non-Arrhenius temperature-dependence of the average relaxation time. This paper briefly reviews the classical phenomenological models for this phenomenon - the free-volume model and the…

凝聚态物理 · 物理学 2015-06-25 Jeppe C. Dyre

We study the nature of the glass transition by cooling model atomistic glass formers at constant rate from a temperature above the onset of glassy dynamics to $T=0$. Motivated by the East model, a kinetically constrained lattice model with…

统计力学 · 物理学 2018-04-16 Alexander Hudson , Kranthi K. Mandadapu

We simulate the compression of a two-component Lennard-Jones liquid at a variety of constant temperatures using a molecular dynamics algorithm in an isobaric-isothermal ensemble. The viscosity of the liquid increases with pressure,…

chem-ph · 物理学 2009-10-22 Shelly L. Shumway , Andrew S. Clarke , Hannes Jónsson

The frequency and temperature dependence of the dielectric constant, electric modulus and electrical conductivity of the transparent glasses in the composition 0.5Li2O-0.5Na2O-2B2O3 (LNBO) were investigated in the 100 Hz - 10 MHz frequency…

材料科学 · 物理学 2010-07-13 Rahul Vaish , K. B. R. Varma

Glass-forming liquids have only a modest tendency to crystallize and hence their dynamics can be studied even below the melting temperature. The relaxation dynamics of most of these liquids shows at a temperature $T_c$, somewhat above the…

软凝聚态物质 · 物理学 2025-01-17 Francesco Rusciano , Raffaele Pastore , Francesco Greco , Walter Kob

We introduce a coarse-grained model for atomic glass formers. Its elements are physically motivated local microscopic dynamical rules parameterized by observables. Results of the model are established and used to interpret the measured…

统计力学 · 物理学 2009-11-10 Juan P. Garrahan , David Chandler

After a strong electric bias field was applied to a glass sample at temperatures in the millikelvin range its AC-dielectric constant increases and then decays logarithmically with time. For the polyester glass mylar we have observed the…

无序系统与神经网络 · 物理学 2009-11-07 S. Ludwig , P. Nalbach , D. Rosenberg , D. Osheroff

We analyze the effect of temperature on the yielding transition of amorphous solids using different coarse-grained model approaches. On one hand we use an elasto-plastic model, with temperature introduced in the form of an Arrhenius…

无序系统与神经网络 · 物理学 2021-11-12 Ezequiel E. Ferrero , Alejandro B. Kolton , Eduardo A. Jagla

The principal theme of this paper is that anomalously slow, super-Arrhenius relaxations in glassy materials may be activated processes involving chains of molecular displacements. As pointed out in a preceding paper with A. Lemaitre, the…

材料科学 · 物理学 2009-11-11 J. S. Langer

In this work, we present a new model for the interpretation of the local dynamic behavior and the mechanical reinforcement mechanism in polymer nanocomposites. The temperature dependence of the dynamics in the glassy region is described by…

软凝聚态物质 · 物理学 2019-05-16 Georgios Kritikos , Kostas Karatasos

We show the existence of intermittent dynamics in one of the simplest model of a glassy system: the two-state model, which has been used to explain the origin of the violation of the fluctuation-dissipation theorem. The dynamics is analyzed…

统计力学 · 物理学 2009-11-10 M. Naspreda , D. Reguera , A. Perez-Madrid , J. M. Rubi

We introduce a new quantity to probe the glass transition. This quantity is a linear generalized compressibility which depends solely on the positions of the particles. We have performed a molecular dynamics simulation on a glass forming…

无序系统与神经网络 · 物理学 2009-11-07 Herve M. Carruzzo , Clare C. Yu

Recently [3] predicted the existence of an intriguing new phenomenon. It was shown that if temperature is suddenly raised at the surface of a sphere the temperature in the interior initially decreases. The authors of [3] gave a thorough…

软凝聚态物质 · 物理学 2011-05-11 J. J. Papini

A picture for thermodynamics of the glassy state was introduced recently by us (Phys. Rev. Lett. {\bf 79} (1997) 1317; {\bf 80} (1998) 5580). It starts by assuming that one extra parameter, the effective temperature, is needed to describe…

无序系统与神经网络 · 物理学 2007-05-23 Th. M. Nieuwenhuizen

The Arrhenius crossover temperature, $T_{A}$, corresponds to a thermodynamic state wherein the atomistic dynamics of a liquid becomes heterogeneous and cooperative; and the activation barrier of diffusion dynamics becomes…

材料科学 · 物理学 2023-01-31 Bulat N. Galimzyanov , Maria A. Doronina , Anatolii V. Mokshin

Dielectric relaxation spectroscopy (1 Hz - 20 GHz) has been performed on supercooled glass-formers from the temperature of glass transition (T_g) up to that of melting. Precise measurements particularly in the frequencies of MHz-order have…

无序系统与神经网络 · 物理学 2009-11-07 Takuya Fujima , Hiroshi Frusawa , Kohzo Ito
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