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The structural and nanochemical properties of thin $AlO_x$ layers are decisive for the performance of advanced electronic devices. For example, they are frequently used as tunnel barriers in Josephson junction-based superconducting devices.…

材料科学 · 物理学 2019-11-27 S. Fritz , L. Radtke , R. Schneider , M. Luysberg , M. Weides , D. Gerthsen

We study the adsorption geometry of 3,4,9,10-perylene-tetracarboxylic-dianhydride (PTCDA) on Ag(111) and Cu(111) using X-ray standing waves. The element-specific analysis shows that the carbon core of the molecule adsorbs in a planar…

材料科学 · 物理学 2011-04-13 A. Gerlach , S. Sellner , F. Schreiber , N. Koch , J. Zegenhagen

Atomically precise thiolate-stabilized gold nanoclusters are currently of interest for many cross-disciplinary applications in chemistry, physics and molecular biology. Very recently, synthesis and electronic properties of "nanoalloy"…

原子与分子团簇 · 物理学 2011-09-05 Sami Malola , Hannu Häkkinen

Physical property of a single quantum object is governed by its precise atomic arrangement. The direct correlation of localized physical properties with the atomic structures has been therefore strongly desired but still limited in the…

原子物理 · 物理学 2021-01-29 Ryosuke Senga , Thomas Pichler , Kazu Suenaga

The adsorption geometry of perfluorinated copper-phthalocyanine molecules (F_{16}CuPc) on Cu(111) and Ag(111) is studied using X-ray standing waves. A detailed, element-specific analysis taking into account non-dipolar corrections to the…

软凝聚态物质 · 物理学 2009-11-11 A. Gerlach , F. Schreiber , S. Sellner , H. Dosch , I. A. Vartanyants , B. C. C. Cowie , T. -L. Lee , J. Zegenhagen

Nano-composite films of Tin Sulfide (SnS) and silver (Ag) fabricated by thermal evaporation showed two prominent peaks in the visible region of their extinction spectra. Theoretical modeling of the extinction spectra suggest that these two…

材料科学 · 物理学 2015-06-19 Priyal Jain , P. Arun

We simulate the liquid silicon surface with first-principles molecular dynamics in a slab geometry. We find that the atom-density profile presents a pronounced layering, similar to those observed in low-temperature liquid metals like Ga and…

软凝聚态物质 · 物理学 2009-10-31 G. Fabricius , E. Artacho , D. Sanchez-Portal , P. Ordejon , D. A. Drabold , J. M. Soler

Using Kohn-Sham wave functions and their energy levels obtained by density-functional-theory total-energy calculations, the electronic structure of the two c(2x2) phases of Na on Al(001) are analysed; namely, the metastable hollow-site…

材料科学 · 物理学 2009-10-31 C. Stampfl , K. Kambe , R. Fasel , P. Aebi , M. Scheffler

Electronic structure of nickel nanoparticles encapsulated in carbon was characterized by photoelectron, X-ray absorption, and X-ray emission spectroscopies. Experimental spectra are compared with the density of states calculated in the…

We present a simple method to prove the presence of an organic shell around silver nanoparticles. This method is based on the comparison between optical extinction measurements of isolated nanoparticles and Mie calculations predicting the…

介观与纳米尺度物理 · 物理学 2013-04-29 T. Maurer , N. Abdellaoui , A. Gwiazda , P. -M. Adam , A. Vial , J. -L. Bijeon , D. Chaumont , M. Bourezzou

Interfaces between aqueous electrolytes and nanoporous carbons are involved in a number of technological applications such as energy storage and capacitive deionization. The disordered nature of the carbon materials makes it challenging to…

材料科学 · 物理学 2022-07-21 Anagha Sasikumar , John M. Griffin , Céline Merlet

Molecular dynamics simulations of the liquid-vapour interfaces in simple sp-bonded liquid metals have been performed using first principles methods. Results are presented for liquid Li, Na, K, Rb, Cs, Mg, Ba, Al, Tl, and Si at thermodynamic…

无序系统与神经网络 · 物理学 2009-11-11 David J. Gonzalez Luis E. Gonzalez , Malcolm J. Stott

In situ Electro-Chemical Scanning Tunneling Microscopy (ECSTM) and Electron Back-Scatter Diffraction analysis of the same local microstructural region were combined to study the relationships between grain boundary (GB) type and structure…

Control of atomic-scale interfaces between materials with distinct electronic structures is crucial for the design and fabrication of most electronic devices. In the case of two-dimensional (2D) materials, disparate electronic structures…

This paper reports state-of-the-art electronic structure calculations of La adsorption on the Si(001) surface. We predict La chains in the low coverage limit, which condense in a stable phase at a coverage of 1/5 monolayer. At 1/3 monolayer…

材料科学 · 物理学 2007-05-23 Christopher R. Ashman , Clemens J. Foerst , Karlheinz Schwarz , Peter E. Bloechl

Two-dimensional materials composed of transition metal carbides and nitrides (MXenes) are poised to revolutionize energy conversion and storage. In this work, we used density functional theory (DFT) to investigate adsorption of Mg and Na…

材料科学 · 物理学 2021-12-01 G. Chaney , D. Çakır , F. M. Peeters , C. Ataca

We report high resolution transmission electron microscopy and classical molecular dynamics simulation results of mechanically stretching copper nanowires conducting to linear atomic suspended chains (LACs) formation. In contrast with some…

材料科学 · 物理学 2013-05-29 F. Sato , A. S. Moreira , J. Bettini , P. Z. Coura , S. O. Dantas , D. Ugarte , D. S. Galvao

We calculate theoretical population ratios of the ground fine-structure levels of some atoms/ions which typically exhibit UV lines in the spectra of QSO absorbers redward the Ly-alpha forest: C0, C+, O0, Si+ and Fe+. The most reliable…

天体物理学 · 物理学 2009-10-31 A. I. Silva , S. M. Viegas

We report on total-energy electronic structure calculations in the density-functional theory performed for the ultra-thin atomic layers of Si on Ag(111) surfaces. We find several distinct stable silicene structures:…

介观与纳米尺度物理 · 物理学 2015-05-05 Zhi-Xin Guo , Atsushi Oshiyama

The infrared range optical absorption mechanism of Carbon-Copper composite thin layer coated on the Diamond-Like Carbon (DLC) buffer layer has been investigated. By consideration of weak interactions between copper nanoparticles in their…