相关论文: Pseudorotations in Molecules: Electronic Orbital T…
The Jahn-Teller effect is a fascinating and ubiquitous phenomenon in modern quantum physics and chemistry. We propose a class of oxides with melilite structure Ba$_2$TGe$_2$O$_7$ (T=V,Ni) where Jahn-Teller distortions are the main…
We characterize the angular polyspectra, of arbitrary order, associated with isotropic fields defined on the sphere S^2. Our techniques rely heavily on group representation theory, and specifically on the properties of Wigner matrices and…
By a recent observation, the Laplacians on the Riemannian manifolds the author used for isospectrality constructions are nothing but the Zeeman-Hamilton operators of free charged particles. These manifolds can be considered as prototypes of…
The trigonometric P\"oschl-Teller (PT) potential describes the diatomic molecular vibration. We have obtained the approximate solutions of the radial Schr\"odinger equation (SE) for the rotating trigonometric PT potential using the…
In this thesis, we studied certain mathematical issues related to the computation of the Chamseddine--Connes spectral action on some fundamental noncommutative spectral triples, such as the noncommutative torus and the quantum 3-sphere…
Non-local order parameters in space-time are proposed to characterize the unconventional orbital-selective conducting state in fulleride superconductors, called the Jahn-Teller metal. In previous works, it has been argued that this state…
We construct spectral triples in a sense of noncommutative differential geometry, associated with a Riemannian foliation on a compact manifold, and describe its dimension spectrum.
This paper describes a very general approach to the calculation of the Zeeman splitting effect produced by an external magnetic field on the rotational levels of diatomic molecules. The method is valid for arbitrary values of the total…
Calculation of the rotation-vibration spectrum of H3+, as well as of its deuterated isotopologues, with near-spectroscopic accuracy requires the development of sophisticated theoretical models, methods, and codes. The present paper reviews…
We propose a basic theory of nonrelativistic spinful electrons on curves and surfaces. In particular, we discuss the presence and effects of spin connections, which describe how spinors and vectors couple to the geometry of curves and…
In this contribution a geometric approach to describe a rotating fullerene molecule with Ih symmetry is developed. We analyze the quantum dynamics of quasiparticles in continuum limit considering a description of fullerene in a spherical…
For the Jacobian resulting from the previously considered problem of the path integral reduction in Wiener path integrals for a mechanical system with symmetry describing the motion of two interacting scalar particles on a manifold that is…
The properties of cyclic structures (toroidal oscillators) based on classical tripolar (colour) fields are discussed, in particular, of a cyclic structure formed of three colour-singlets spinning around a ring-closed axis. It is shown that…
Shell structures in single-particle energy spectra are investigated against regular tetrahedral type deformation using radial power-law potential model. Employing a natural way of shape parametrization which interpolates sphere and regular…
We have developed a theoretical method for interpretation of photoionization experiments with the H_3 molecule. In the present study we give a detailed description of the method, which combines multichannel quantum defect theory, the…
A formalism is developed which allows to determine the locations of all local symmetry axes of three-dimensional particles with overall icosahedral symmetry. It relies on the fact that the root system of the non-crystallographic Coxeter…
We analyze two simple model planar molecules: an ionic molecule with D3 symmetry and a covalent molecule with D6 symmetry. Both symmetries allow the existence of chiral molecular orbitals and normal modes that are coupled to each other in a…
Tunneling of electrons through rotor-stator anthracene aldehyde molecular interfaces is studied with a combined ab initio and model approach. Molecular electronic structure calculated from first principles is utilized to model different…
We show how shape transitions in the neutron-rich exotic Si and S isotopes occur in terms of shell-model calculations with a newly constructed Hamiltonian based on V_MU interaction. We first compare the calculated spectroscopic-strength…
We prove a variant of the Chance-McDuff conjecture for pseudo-rotations: under certain additional conditions, a closed symplectic manifold which admits a Hamiltonian pseudo-rotation must have deformed quantum product and, in particular,…