相关论文: Pseudorotations in Molecules: Electronic Orbital T…
A geometric representation is found for the previously obtained path integral reduction Jacobian in Wiener-type path integral when quantizing a model mechanical system, which is used to describe the motion of two interacting scalar…
Illumination of colloid sphere monolayers by circularly polarized beams enables the fabrication of concave patterns consisting of circular nanohole miniarrays that can be transferred into convex metal nanoparticle patterns via a lift-off…
We address the formation of topological edge solitons in rotating Su-Schrieffer-Heeger waveguide arrays. The linear spectrum of the non-rotating topological array is characterized by the presence of topological gap with two edge states…
We describe how to treat the interaction of travelling electrons with localised vibrational modes in nanojunctions. We present a multichannel scattering technique which can be applied to calculate the transport properties for realistic…
We study the low energy resolvent of the Hodge Laplacian on a manifold equipped with a fibred boundary metric. We determine the precise asymptotic behavior of the resolvent as a fibred boundary (aka $\phi$-) pseudodifferential operator when…
Rescattering electrons offer great potential as probes of molecular properties on ultrafast timescales. The most famous example is molecular tomography, in which high harmonic spectra of oriented molecules are mapped to ``tomographic…
We construct non-trivial continuous isospectral deformations of Riemannian metrics on the ball and on the sphere in $\R^n$ for every $n\geq 9$. The metrics on the sphere can be chosen arbitrarily close to the round metric; in particular,…
Electromagnetic wave propagation in three-dimensional space typically suffers omnidirectional scattering when encountering obstacles. In this study, we employed Chern vectors to construct a topological heterostructure, where large-volume…
Jahn-Teller effect in bivalley Si(100) MOSFET under conditions of quantum Hall effect at integer filling factors nu=1,2,3 is studied. This system is described by SU(4) hidden symmetry. At nu=2 static and dynamic lattice deformation creates…
The spectral shape of radiation due to Inverse Compton Scattering is analyzed, in the Thomson and the Klein-Nishina regime, for electron distributions with exponential cut-off. We derive analytical, asymptotic expressions for the spectrum…
The multi-order Raman scattering is studied up to a fourth order for a detwinned LaMnO_3 crystal. Based on a comprehensive data analysis of the polarisation-dependent Raman spectra, we show that the anomalous features in the multi-order…
A simple and yet powerful approach for modeling the structure of endohedrally confined diatomic molecules is introduced. The theory, based on a u(4)+u(3) dynamical algebra, combines u(4), the vibron model dynamical algebra, with a u(3)…
The semiclassical origins of the enhancement of shell effects in exotic-shape mean-field potentials are investigated by focusing attention on the roles of the local symmetries associated with the periodic-orbit bifurcations. The deformed…
The Jahn-Teller theorem constitutes one of the most popular and stringent concepts, applicable to all fields of chemistry. In open shell transition elements chemistry and physics, 3d4, 3d9, and 3d7(low-spin) configurations in octahedral…
A simple model of electron-vibron interactions in buckminsterfullerene ions is solved semiclassically. Electronic degeneracies of C$_{60}$$^{n-}$ induce dynamical Jahn-Teller distortions, which are unimodal for $n\!\ne\!3$ and bimodal for…
We undertake a semiclassical analysis of the spectral properties (modulations of photoabsorption spectra, energy level statistics) of a simple Rydberg molecule in static fields within the framework of Closed-Orbit/Periodic-Orbit theories.…
Band theory provides the foundation for understanding electronic structure in crystalline materials, but its reliance on exact translational symmetry limits its applicability to systems with defects, disorder, incommensurate modulations, or…
There has been much recent interest, initiated by work of the physicists Hatano and Nelson, in the eigenvalues of certain random non-Hermitian periodic tridiagonal matrices and their bidiagonal limits. These eigenvalues cluster along a…
The detection of vibrational excitations of individual molecules on surfaces by scanning tunneling spectroscopy does not obey strict selection rules but rather propensity rules. The experimental verification of these is challenging because…
The nucleon strange vector and isoscalar electromagnetic form factors are studied using a spectral decomposition. The K\bar{K} contribution to the electric and magnetic radii as well as the magnetic moment is evaluated to all orders in the…