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We present detailed multi frequency resonant Raman measurements of potassium graphite intercalation compounds (GICs). From a well controlled and consecutive in-situ intercalation and high temperature de-intercalation approach the response…

材料科学 · 物理学 2013-10-25 J. C. Chacon-Torres , L. Wirtz , T. Pichler

We demonstrate the possibility in quantifying the Raman intensities for both specimen and substrate layers in a common stacked experimental configuration and, consequently, propose a general and rapid thickness identification technique for…

介观与纳米尺度物理 · 物理学 2013-08-20 Song-Lin Li , Hisao Miyazaki , Haisheng Song , Hiromi Kuramochi , Shu Nakaharai , Kazuhito Tsukagoshi

Two-dimensional (2D) semiconducting transition metal dichalcogenides (TMDs) can withstand a large deformation without fracture or inelastic relaxation, making them attractive for application in novel strain-engineered and flexible…

材料科学 · 物理学 2016-01-18 Junwen Li , Nikhil V. Medhekar , Vivek B. Shenoy

Two-dimensional transition metal dichalcogenides (TMDs) usually exist in two or more structural phases with different physical properties, and can be repeatedly switched between these phases via different stimuli, making them potentially…

材料科学 · 物理学 2020-04-29 Priyanka Manchanda , Pankaj Kumar , Pratibha Dev

Transition metal dichalcogenides (TMDs) are layered materials which show excellent potential for nanoelectronic and optoelectronic applications. However, as many of the exciting features of these materials are controlled by the anharmonic…

材料科学 · 物理学 2021-08-13 Suvodeep Paul , Saheb Karak , Annie Mathew , Ankita Ram , Surajit Saha

Typical Raman spectra of transition metal dichalcogenides (TMDs) display two prominent peaks, E2g and A1g, that are well separated from each other. We find that these modes are degenerate in bulk WSe2 yielding one single Raman peak. As the…

材料科学 · 物理学 2013-04-10 H. Sahin , S. Tongay , S. Horzum , W. Fan , J. Zhou , J. Li , J. Wu , F. M. Peeters

ReS$_2$ has recently emerged as a new member in the rapidly growing family of two-dimensional materials. Unlike MoS$_2$ or WSe$_2$, the optical and electrical properties of ReS$_2$ are not isotropic due to the reduced symmetry of the…

介观与纳米尺度物理 · 物理学 2016-02-17 Philipp Nagler , Gerd Plechinger , Christian Schüller , Tobias Korn

2D layered materials have recently attracted tremendous interest due to their fascinating properties and potential applications. The interlayer interactions are much weaker than the intralayer bonds, allowing the as-synthesized materials to…

材料科学 · 物理学 2015-04-21 Xin Luo , Chunxiao Cong , Xin Lu , Ting Yu , Qihua Xiong , Su Ying Quek

We propose a scheme to achieve breathing kagome moir\'e superlattices using three twisted layers of transition metal dichalcogenides. In this scheme, the top and bottom layers are twisted relative to the middle layer by small angles…

介观与纳米尺度物理 · 物理学 2025-03-18 Adrian Fedorko , Chao-Xing Liu , Zhen Bi

Among the most common few-layers transition metal dichalcogenides (TMDs), WSe2 is the most challenging material from the lattice dynamics point of view. Indeed, for a long time the main two phonon modes (A1g and E12g) have been wrongly…

In this work, we report an ab initio investigation based on density functional theory of the structural, energetic and electronic properties of 2D layered chalcogenides compounds based in the combination of the transition-metals (Ti, Zr,…

材料科学 · 物理学 2019-04-17 Carlos M. O. Bastos , Rafael Besse , Juarez L. F. Da Silva , Guilherme M. Sipahi

We performed polarized Raman spectroscopy on mechanically exfoliated few-layer MoTe2 samples and observed both 1T' and Td phases at room temperature. Few-layer 1T' and Td MoTe2 exhibited a significant difference especially in interlayer…

介观与纳米尺度物理 · 物理学 2021-01-25 Yeryun Cheon , Soo Yeon Lim , Kangwon Kim , Hyeonsik Cheong

We report a study of long-range MoS2-substrate interaction using resonant Raman imaging. We observed a strong thickness-dependent peak shift of a Raman-forbidden mode that can be used as a new method of determining the thickness of…

材料科学 · 物理学 2016-12-13 Hongyuan Li , Dmitri V. Voronine

Raman spectroscopy is widely used to assess the quality of 2D materials thin films. This report focuses on $\rm{PtSe_2}$, a noble transition metal dichalcogenide which has the remarkable property to transit from a semi-conductor to a…

Stokes and anti-Stokes Raman scattering are performed on atomic layers of hexagonal molybdenum ditelluride (MoTe2), a prototypical transition metal dichalcogenide (TMDC) semiconductor. The data reveal all six types of zone center optical…

材料科学 · 物理学 2016-03-14 Thomas Goldstein , Shao-Yu Chen , Di Xiao , Ashwin Ramasubramaniam , Jun Yan

We present first-principles calculations of the vibrational properties of the transition metal dichalcogenide 1T-TaS$_2$ for various thicknesses in the high-temperature (undistorted) phase and the low-temperature commensurate charge density…

We study by Raman scattering the shear and layer breathing modes in multilayer MoS2. These are identified by polarization measurements and symmetry analysis. Their positions change with the number of layers, with different scaling for odd…

介观与纳米尺度物理 · 物理学 2013-05-28 X. Zhang , W. P. Han , J. B. Wu , S. Milana , Y. Lu , Q. Q. Li , A. C. Ferrari , P. H. Tan

Two-dimensional (2D) layered materials have been extensively studied owing to their fascinating and technologically relevant properties. Their functionalities can be often tailored by the interlayer stacking pattern. Low-frequency (LF)…

介观与纳米尺度物理 · 物理学 2017-10-06 Liangbo Liang , Alexander A. Puretzky , Bobby G. Sumpter , Vincent Meunier

Strain is ubiquitous in solid-state materials, but despite its fundamental importance and technological relevance, leveraging externally applied strain to gain control over material properties is still in its infancy. In particular, strain…

We report the evolution of charge density wave states under pressure for two NbS3 phases triclinic (phase I) and monoclinic (phase II) at room temperature. Raman and X-ray diffraction (XRD) techniques are applied. The x-ray studies on the…