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Non-destructive characterization of lithium-ion batteries provides critical insights for optimizing performance and lifespan while preserving structural integrity. Optimizing electrolyte design in commercial LIBs requires consideration of…

Rechargeable lithium metal batteries (LMBs) with an ultrahigh theoretical energy density have attracted more and more attentions for their crucial applications of portable electronic devices, electric vehicles, and smart grids. However, the…

材料科学 · 物理学 2024-10-22 Yanchen Fana , Xiang Chenb , Dominik Legut , Qianfan Zhang

Nickel-rich layered oxides have been widely used as positive electrode materials for high-energy-density lithium-ion batteries, but their degradation has severely affected cell performance, in particular at a high voltage and temperature.…

材料科学 · 物理学 2023-04-04 Mingzhao Zhuo , Gregory Offer , Monica Marinescu

The morphologies of crystalline lithium peroxide (Li2O2) discharge products in Li-O2 batteries have been shown to exhibit a dependency on subtle variations within the battery cell-operating environment including exposure to ambient air,…

材料科学 · 物理学 2016-06-22 Hariharan Katharajan , Kumar Virwani , A. David Erpelding , Jeannette M. Garcia

Developing efficient anode materials with low electrode voltage, high specific capacity and superior rate capability is urgently required on the road to commercially viable sodium-ion batteries (SIBs). Aiming at finding a new SIB anode…

材料科学 · 物理学 2019-07-16 Song-Hyok Choe , Chol-Jun Yu , Kum-Chol Ri , Jin-Song Kim , Un-Gi Jong , Yun-Hyok Kye , Song-Nam Hong

In this work we analyse the local nonlinear electrochemical impedance spectroscopy (NLEIS) response of a lithium-ion battery and estimate model parameters from measured NLEIS data. The analysis assumes a single-particle model including…

化学物理 · 物理学 2023-04-24 T. L. Kirk , A. Lewis-Douglas , D. A. Howey , C. P. Please , S. J. Chapman

We review recent ab initio molecular dynamics studies of electrode/electrolyte interfaces in lithium ion batteries. Our goals are to introduce experimentalists to simulation techniques applicable to models which are arguably most faithful…

材料科学 · 物理学 2013-04-23 Kevin Leung

As the core determinant of lithium-ion battery performance, electrode materials play a crucial role in defining the battery's capacity, cycling stability, and durability. During charging and discharging, electrode materials undergo complex…

材料科学 · 物理学 2025-08-15 Liqi Wang , Ruijuan Xiao , Hong Li

High-performance anodes for rechargeable Li-ion battery are produced by nanostructuring of the transition metal oxides on a conductive support. Here, we demonstrate a hybrid material of MnO2 directly grown onto fabrics of carbon nanotube…

Understanding the phase stability of elemental lithium (Li) is crucial for optimizing its performance in lithium-metal battery anodes, yet this seemingly simple metal exhibits complex polymorphism that requires proper accounting for quantum…

材料科学 · 物理学 2025-02-24 Yiheng Shen , Wei Xie

This theoretical investigation delves into the structural, electronic, and electrochemical properties of two hexagonal iron-arsenide monolayers, 1T-FeAs and 1H-FeAs, focusing on their potential as anode materials for Lithium-ion batteries.…

材料科学 · 物理学 2025-01-28 Ajay Kumar , Prakash Parida

Accurately measuring the cycle lifetime of commercial lithium-ion batteries is crucial for performance and technology development. We introduce a novel hybrid approach combining a physics-based equation with a self-attention model to…

机器学习 · 计算机科学 2025-05-07 Constantin-Daniel Nicolae , Sara Sameer , Nathan Sun , Karena Yan

The performances of lithium-ion batteries are set by the electrodes materials capacity to exchange lithium ions and electrons faster and reversibly. To this goal Ni-rich layered metal oxides, especially LiNiO2, are attractive electrode…

The biggest challenge for the commercialization of layered structured nickel rich lithium transition metal oxide cathode is the capacity and voltage fading. Resolving this problem over the years follows an incremental progress. In this…

材料科学 · 物理学 2017-10-18 Pengfei Yan , Jianming Zheng , Jian Liu , Biqiong Wang , Xueliang Sun , Chongmin Wang , Ji-Guang Zhang

Thick Li-ion battery electrodes with high ion transport rates could enable batteries that cost less and that have higher gravimetric and volumetric energy density, because they require fewer inactive cell-components. Finding ways to…

材料科学 · 物理学 2015-05-14 V. Pavan Nemani , Stephen J. Harris , Kyle C. Smith

Battery electrode surfaces are generally coated with electronically insulating solid films of thickness 1-50 nm. Both electrons and Li+ can move at the electrode-surface film interface in response to the voltage, which adds complexity to…

材料科学 · 物理学 2015-07-10 Kevin Leung , Andrew Leenheer

Due to its exceptional lithium storage capacity silicon is considered as a promising candidate for anode material in lithium-ion batteries (LIBs). In the present work we demonstrate that methods of the soft X-ray emission spectroscopy…

Lithium-bismuth bimetallic cells are amongst the best explored liquid metal batteries. A simple and fast quasi-one-dimensional cell voltage model for such devices is presented. The equilibrium cell potential is obtained from a complex…

Predicting lithium-ion battery lifetime is one of the greatest unsolved problems in battery research right now. Recent years have witnessed a surge in lifetime prediction papers using physics-based, empirical, or data-driven models, most of…

Titanium dioxide materials have been studied intensively and extensively due to photocatalytic applications. A long-standing open question is the energy band alignment of rutile and anatase TiO2 phases, which can affect the photocatalytic…

材料科学 · 物理学 2015-11-10 Daoyu Zhang , Minnan Yang , Shuai Dong