相关论文: Exact fundamental limits of the first and second h…
Studies aimed at understanding the global properties of the hyperpolarizabilities have focused on identifying universal properties when the hyperpolarizabilities are at the fundamental limit. These studies have taken two complimentary…
The hyperpolarizability has been extensively studied to identify universal properties when it is near the fundamental limit. Here, we employ the Monte Carlo method to study the fundamental limit of the second hyperpolarizability. As was…
The Thomas-Reiche-Kuhn sum rule is a fundamental consequence of the position-momentum commutation relation for an atomic electron and it provides an important constraint on the transition matrix elements for an atom. Here we propose a TRK…
The off-resonant hyperpolarizability is calculated using the dipole-free sum-over-stats expression from a randomly chosen set of energies and transition dipole moments that are forced to be consistent with the sum rules. The process is…
The Thomas-Reiche-Kuhn optical (TRK) sum rules for bulk materials have customarily been obtained by combining the Kramers-Kronig relations with the high frequency limit of the optical susceptibility tensor $\chi_{ij}$. Also, a non-singular…
Using sum rules and a new dipole-free sum-over-states expression, we calculate the fundamental limits of the dispersion of the real and imaginary parts of all electronic nonlinear-optical susceptibilities. As such, these general results can…
We optimize the first and second intrinsic hyperpolarizabilities for a 1D piecewise linear potential dressed with Dirac delta functions for $N$ non-interacting electrons. The optimized values fall rapidly for $N>1$, but approach constant…
We investigate the efficacy of boosting the nonlinear-optical response by using novel systems such as those in an excited state or with a degenerate ground state. By applying the Three Level Ansatz (TLA) and using the Thomas-Reiche-Kuhn…
Almost four decades ago, Bergman and Milton independently showed that the isotropic effective electric permittivity of a two-phase composite material with a given volume fraction is constrained to lie within lens-shaped regions in the…
The Thomas Kuhn Reich sum rules and the sum-over-states (SOS) expression for the hyperpolarizabilities are truncated when calculating the fundamental limits of nonlinear susceptibilities. Truncation of the SOS expression can lead to an…
We present the first analysis of harmonic generation data where the full potential of the generalized nonlinear Kramers-Kronig (K-K) relations and sum rules is exploited. We consider two published sets of wide spectral range experimental…
The Kramers-Kronig relations and various oscillator strength sum rules represent strong constraints on the physical response of materials. In this work, taking inspiration from the well-established equivalence between $f-$sum rules and…
Using the recent reformulation for the Eliashberg theory of superconductivity in terms of a classical interacting Bloch spin chain model, rigorous upper and lower bounds on the critical temperature $T_c$ are obtained for the $\gamma$ model…
We have optimized the zero frequency first hyperpolarizability \beta of a one-dimensional piecewise linear potential well containing a single electron by adjusting the shape of that potential. With increasing numbers of parameters in the…
Inspired by the work of Pratt and coworkers on a sum rule for the polarization correlations in electron bremsstrahlung when the outgoing electron is not observed, we derive the corresponding sum rule for the elementary process of…
We determine the phase diagram of $N$ identical three-level systems interacting with a single photonic mode in the thermodynamical limit ($N \to \infty$) by accounting for the so-called diamagnetic term and the inequalities imposed by the…
Using the Dyson equation of motion for both the diagonal one-particle Green function, $G(\vec{k},\omega)$ and off--diagonal Green function, $F(\vec{k},\omega)$, at the level of the Hubbard--I decoupling scheme, we have found that they have…
In Part I we construct the upper bound, in the spirit of $\Gamma$- $\limsup$, achieved by multidimensional profiles, for some general classes of singular perturbation problems, with or without the prescribed differential constraint, taking…
Two simple bounds on the $T_c$ of conventional, phonon-mediated superconductors are derived within the framework of Eliashberg theory in the strong coupling regime. The first bound is set by the total electron-phonon coupling available…
The third moment frequency sum rule for the density-density correlation function is rederived in the presence of Umklapp processes. Upper and lower bounds on the electron-electron Coulomb energy are derived in two-dimensional and…