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The metaphor of a clock in physics describes near-equilibrium reversible phenomena such as an oscillating spring. It is surprising that for chemical and biological clocks the focus has been exclusively on the far-from-equilibrium…

化学物理 · 物理学 2021-12-07 Thomas Heimburg

We study the thermodynamics of open systems weakly driven out-of-equilibrium by nonconservative and time-dependent forces using the linear regime of stochastic thermodynamics. We make use of conservation laws to identify the potential and…

统计力学 · 物理学 2022-10-13 Danilo Forastiere , Riccardo Rao , Massimiliano Esposito

We consider viscous, heat conducting mixtures of molecularly miscible chemical species forming a fluid in which the constituents can undergo chemical reactions. Assuming a common temperature for all components, we derive a closed system of…

流体动力学 · 物理学 2016-04-01 Dieter Bothe , Wolfgang Dreyer

A unified thermodynamic framework for characterization of functional materials is developed. This framework encompasses linear reversible and irreversible processes with thermal, electrical, magnetic, and/or mechanical effects coupled. The…

材料科学 · 物理学 2016-10-07 Sushma Santapuri

We prove the equivalence among symmetricity, time reversibility, and zero entropy production of the stationary solutions of linear stochastic differential equations. A sufficient and necessary reversibility condition expressed in terms of…

数学物理 · 物理学 2007-05-23 Hong Qian

The characterization of finite-time thermodynamic processes is of crucial importance for extending equilibrium thermodynamics to nonequilibrium thermodynamics. The central issue is to quantify responses of thermodynamic variables and…

统计力学 · 物理学 2023-09-15 Yuki Izumida

The linear laws of transport phenomena are central in our description of irreversible processes in systems across the physical sciences. Linear irreversible thermodynamics allows for the identification of the underlying forces driving…

统计力学 · 物理学 2025-06-02 Yu-Jen Chiu , Eric M. Weiner , Ahmad K. Omar

We study irreversible processes for nonlinear oscillators networks described by complex-valued Langevin equations that account for coupling to different thermo-chemical baths. Dissipation is introduced via non-Hermitian terms in the…

统计力学 · 物理学 2017-08-02 Simone Borlenghi , Stefano Iubini , Stefano Lepri , Jonas Fransson

Modeling of physical systems must be based on their suitability to unavoidable physical laws. In this work, in the context of classical, isothermal, finite-time, and weak drivings, I demonstrate that physical systems, driven simultaneously…

统计力学 · 物理学 2024-06-07 Pierre Nazé

Non-equilibrium thermodynamics of Onsager and Machlup and of Hashitsume is reformulated as a gravity analog model, in which thermodynamic variables, kinetic coefficients and generalized forces form, respectively, coordinates, metric tensor…

Irreversible thermodynamics of single-molecule experiments subject to external constraining forces of a mechanical nature is presented. Extending Onsager's formalism to the non-linear case of systems under non-equilibrium external…

生物物理 · 物理学 2016-10-31 I. Santamaria-Holek , N. J. Lopez-Alamilla , M. Hidalgo-Soria , A. Perez-Madrid

We develop the stochastic approach to thermodynamics based on the stochastic dynamics, which can be discrete (master equation) continuous (Fokker-Planck equation), and on two assumptions concerning entropy. The first is the definition of…

统计力学 · 物理学 2015-06-11 Tânia Tomé , Mário J. de Oliveira

We introduce a general framework for analyzing the thermodynamics of small systems that are driven by both a periodic temperature variation and some external parameter modulating their energy. This set-up covers, in particular, periodic…

统计力学 · 物理学 2015-09-15 Kay Brandner , Keiji Saito , Udo Seifert

Entropy production for a system not in the thermodynamic limit is formulated using Hill's nanothermodynamics, in which a macroscopic ensemble of such systems is considered. External influence of the environment on the average nanosystem is…

统计力学 · 物理学 2011-03-21 J. Carrete , L. M. Varela , L. J. Gallego

We derive a large-scale hydrodynamic equation, including diffusive and dissipative effects, for systems with generic static position-dependent driving forces coupling to local conserved quantities. We show that this equation predicts…

统计力学 · 物理学 2021-12-10 Joseph Durnin , Andrea De Luca , Jacopo De Nardis , Benjamin Doyon

In this paper, we present a Lagrangian formalism for nonequilibrium thermodynamics. This formalism is an extension of the Hamilton principle in classical mechanics that allows the inclusion of irreversible phenomena in both discrete and…

数学物理 · 物理学 2015-10-06 François Gay-Balmaz , Hiroaki Yoshimura

Studies of mesoscopic structures have now become a leading and rapidly evolving research field ranging from physics, chemistry, and mineralogy to life sciences. The increasing miniaturization of devices with length scales of a few…

介观与纳米尺度物理 · 物理学 2023-10-25 Giorgio Sonnino

We characterise the nonequilibrium stationary state of a generic multivariate Ornstein-Uhlenbeck process involving $N$ degrees of freedom. The irreversibility of the process is encoded in the antisymmetric part of the Onsager matrix. The…

统计力学 · 物理学 2018-12-19 Claude Godrèche , Jean-Marc Luck

It is shown that Onsager's principle of the least dissipation of energy is equivalent to the maximum entropy production principle. It is known that solutions of the linearized Boltzmann equation make extrema of entropy production. It is…

Landauer's erasure principle is generalized to nondeterministic processes on systems having an arbitrary number of non-symmetrical logical states. The condition that the process is applied in the same way, irrespective of the initial…

统计力学 · 物理学 2009-04-03 S. Turgut
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