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We propose a free-energy based Monte-Carlo method to measure the volume of potential-energy basins in configuration space. Using this approach we can estimate the number of distinct potential-energy minima, even when this number is much too…

软凝聚态物质 · 物理学 2015-03-18 Ning Xu , Daan Frenkel , Andrea J. Liu

The volume is an important attribute of a convex body. In general, it is quite difficult to calculate the exact volume. But in many cases, it suffices to have an approximate value. Volume estimation methods for convex bodies have been…

计算几何 · 计算机科学 2014-01-03 Cunjing Ge , Feifei Ma , Jian Zhang

We report a new multicanonical Monte Carlo algorithm to obtain the density of states for physical systems with continuous state variables in statistical mechanics. Our algorithm is able to obtain a closed-form expression for the density of…

计算物理 · 物理学 2018-11-20 Alfred C. K. Farris , Ying Wai Li , Markus Eisenbach

A statistical method is derived for the calculation of thermodynamic properties of many-body systems at low temperatures. This method is based on the self-healing diffusion Monte Carlo method for complex functions [F. A. Reboredo J. Chem.…

其他凝聚态物理 · 物理学 2014-03-05 Fernando A. Reboredo , Jeongnim Kim

Soft porous crystals are flexible metal-organic frameworks that respond to physical stimuli such as temperature, pressure, and gas adsorption by large changes in their structure and unit cell volume. While they have attracted a lot of…

统计力学 · 物理学 2012-10-19 David Bousquet , François-Xavier Coudert , Anne Boutin

A Monte Carlo method based on a density-of-states sampling is proposed for study of arbitrary statistical mechanical ensembles in a continuum. A random walk in the two-dimensional space of particle number and energy is used to estimate the…

软凝聚态物质 · 物理学 2009-11-07 Qiliang Yan , Roland Faller , Juan J. de Pablo

The nonequilibrium work fluctuation theorem provides the way for calculations of (equilibrium) free energy based on work measurements of nonequilibrium, finite-time processes and their reversed counterparts by applying Bennett's acceptance…

统计力学 · 物理学 2010-04-26 Aljoscha M. Hahn , Holger Then

By using a full many-body approach, we calculate the excitation energy, the effective mass and the density profile of soliton states in a three dimensional Bose gas of hard spheres at zero temperature. The many-body wave function used to…

量子气体 · 物理学 2015-11-05 Riccardo Rota , Stefano Giorgini

In simulations of crystals, unlike liquids or gases, it may happen that the properties of the studied system depend not only on the volume of the simulation cell but also on its shape. For such cases it is desirable to change the shape of…

计算物理 · 物理学 2022-10-04 A. Baumketner

The computational cost in evaluation of the volume of a body using numerical integration grows exponentially with dimension of the space $n$. The most generally applicable algorithms for estimating $n$-volumes and integrals are based on…

数值分析 · 数学 2021-06-21 Arun I. , Murugesan Venkatapathi

Calculating one-body density profiles in equilibrium via particle-based simulation methods involves counting of events of particle occurrences at (histogram-resolved) space points. Here we investigate an alternative method based on a…

软凝聚态物质 · 物理学 2018-11-07 Daniel de las Heras , Matthias Schmidt

A method for calculating the pressure tensor in constant-volume Monte Carlo simulations of convex bodies is presented. In contrast to other approaches, the method requires only an isotropic scaling of the simulation box, and the counting of…

统计力学 · 物理学 2009-11-11 Michael P. Allen

The rational function approximation method, density functional theory, and NVT Monte Carlo simulation are used to obtain the density profiles of multicomponent hard-sphere mixtures near a planar hard wall. Binary mixtures with a size ratio…

统计力学 · 物理学 2007-06-06 Alexandr Malijevsky , Santos B. Yuste , Andres Santos , Mariano Lopez de Haro

Recent studies into the properties of quantum statistical ensembles in high-dimensional Hilbert spaces have encountered difficulties associated with the Monte-Carlo sampling of quantum superpositions constrained by the energy expectation…

量子物理 · 物理学 2015-05-27 Frank Hantschel , Boris V. Fine

Path-Integral-Monte-Carlo simulation has been used to calculate the properties of a two-dimensional (2D) interacting Bose system. The bosons interact with hard-core potentials and are confined to a harmonic trap. Results for the density…

统计力学 · 物理学 2007-05-23 Stefan Heinrichs , William J. Mullin

Zero- and two-dimensional crystal defects form in open statistical ensembles, such as the grand canonical, that are usually inaccessible with conventional simulation techniques. This longstanding challenge is overcome with a new Hamiltonian…

材料科学 · 物理学 2026-01-16 Flynn Walsh , Babak Sadigh , Joseph T. McKeown , Timofey Frolov

We present density response estimators for Monte Carlo simulations that are based on a reweighting procedure, where the samples of an unperturbed system are used to estimate the properties of a system perturbed by an external harmonic…

Selective adsorption in a two-dimensional model of a binary hard-disk mixture on patterned adhesive surfaces is studied using grand canonical Monte Carlo simulations. The two species have equal diameters and equal bulk chemical potentials,…

软凝聚态物质 · 物理学 2026-05-21 Nazar Kukarkin , Taras Patsahan

The spectral representation separates the contributions of geometrical arrangement (topology) and intrinsic constituent properties in a composite. The aim of paper is to present a numerical algorithm based on the Monte Carlo integration and…

其他凝聚态物理 · 物理学 2007-05-23 Enis Tuncer

The basic problem in equilibrium statistical mechanics is to compute phase space average, in which Monte Carlo method plays a very important role. We begin with a review of nonlocal algorithms for Markov chain Monte Carlo simulation in…

统计力学 · 物理学 2007-05-23 Jian-Sheng Wang
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