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In this study we use non-equilibrium thermodynamics to systematically derive a phase-field model of a polyelectrolyte gel coupled to a hydrodynamic model for a salt solution surrounding the gel. The governing equations for the gel account…

软凝聚态物质 · 物理学 2022-03-02 Giulia L. Celora , Matthew G. Hennessy , Andreas Münch , Barbara Wagner , Sarah L. Waters

The article explores the ion flux response of a capacitor configuration to an alternating voltage. The model system comprises a symmetric binary electrolyte confined between plan-parallel capacitor plates. The AC response is investigated…

化学物理 · 物理学 2018-10-03 Sonja Babel , Michael Eikerling , Hartmut Löwen

Mean-field electrostatics is used to calculate the bending moduli of an electric double layer for fixed surface charge density of a macroion in a symmetric 1:1 electrolyte. The resulting expressions for bending stiffness, Gaussian modulus,…

软凝聚态物质 · 物理学 2018-08-06 Guilherme Volpe Bossa , Bjorn K. Berntson , Sylvio May

We compute effective energies of thin bilayer structures composed by soft nematic elastic-liquid crystals in various geometrical regimes and functional configurations. Our focus is on order-strain interaction in elastic foundations composed…

偏微分方程分析 · 数学 2021-03-12 Pierluigi Cesana , Andres A Leon Baldelli

A parallel plate capacitor containing an electrolytic solution is the simplest model of a supercapacitor, or electric double layer capacitor. Using both analytical and numerical techniques, we solve the Poisson-Nernst-Planck equations for…

软凝聚态物质 · 物理学 2025-10-02 Ivan Palaia , Adelchi J. Asta , Megh Dutta , Patrick B. Warren , Benjamin Rotenberg , Emmanuel Trizac

We study a system of nonlinear partial differential equations modeling the electrokinetics of a nematic electrolyte material consisting of various ion species suspended in a nematic liquid crystal within a bounded domain in two or three…

偏微分方程分析 · 数学 2026-05-19 Hengrong Du , Fizay-Noah Lee , Gieri Simonett

We identify a possible mechanism of the plasmon instabilities in periodically gated two-dimensional electron systems with a modulated electron density (plasmonic crystals) under direct current. The instability occurs due to the amplified…

介观与纳米尺度物理 · 物理学 2017-01-06 Aleksandr S. Petrov , Dmitry Svintsov , Victor Ryzhii , Michael S. Shur

We study the dynamics of ionic liquids in a thin slit pore geometry. Beginning with the classical and dynamic density functional theories for systems of charged hard spheres, an asymptotic procedure leads to a simplified model which…

软凝聚态物质 · 物理学 2021-10-15 Ruben J. Tomlin , Tribeni Roy , Toby L. Kirk , Monica Marinescu , Dirk Gillespie

We use the hyperbolic subdiffusion equation with fractional time derivatives (the generalized Cattaneo equation) to study the transport process of electrolytes in media where subdiffusion occurs. In this model the flux is delayed in a…

统计力学 · 物理学 2009-11-13 Tadeusz Kosztolowicz , Katarzyna D. Lewandowska

The derivation of Warburg's impedance presented in several books and scientific papers is reconsidered. It has been obtained by assuming that the total electric current across the sample is just due to the diffusion, and that the external…

介观与纳米尺度物理 · 物理学 2016-11-23 Giovanni Barbero

Conducting Polymer Dendrites (CPD) are truly inspiring for unconventional electronics that shapes topological circuitries evolving upon an application. Driven by electrochemical processes, an electrochemical impedance rules signal…

应用物理 · 物理学 2024-07-02 Antoine Baron , Enrique Hernández-Balaguera , Sébastien Pecqueur

In this study, the physics of sheath formation in a collisional two-electron temperature plasma in the presence of an oblique external magnetic field has been investigated. At first, a comparative study among the fluid electron model,…

等离子体物理 · 物理学 2022-08-29 G. Sharma , R. Paul , K. Deka , R. Moulick , S. Adhikari , S. S. Kausik , B. K. Saikia

Within a dipolar Poisson-Boltzmann theory including electrostatic correlations, we consider the effect of explicit solvent structure on solvent and ion partition confined to charged nanopores. We develop a relaxation scheme for the solution…

软凝聚态物质 · 物理学 2015-10-28 Sahin Buyukdagli

We analyze the simplest problem of electrochemical relaxation in more than one dimension - the response of an uncharged, ideally polarizable metallic sphere (or cylinder) in a symmetric, binary electrolyte to a uniform electric field. In…

材料科学 · 物理学 2009-11-11 Kevin T. Chu , Martin Z. Bazant

A new modeling way of describing the continuous absorption of electromagnetic (EM) radiation in dense partially ionized hydrogen plasma is tested in this work. It is shown that the obtained results give a possibility of calculating spectral…

太阳与恒星天体物理 · 物理学 2012-08-14 A. A. Mihajlov , N M Sakan , V. A. Sreckovic , Y. Vitel

The dependence of the actual/effective ionic concentration on the nominal salt concentration is experimentally investigated for aqueous solutions of NaCl and KCl. The actual ionic bulk density is determined by means of the impedance…

化学物理 · 物理学 2022-04-04 G. Barbero , N. G. Fytas , I. Lelidis , J. V. da Silva Andrade , F. C. M. Freire , A. J. Santana

The model of gas-discharge nonneutral electron plasma has been considered, in which the electron density is limited by non-linear processes initiated by diocotron instability and it does not depend on the mechanism of electron transport…

等离子体物理 · 物理学 2013-11-19 N. A. Kervalishvili , G. N. Kervalishvili

The time-dependent, mean-field Newns-Anderson model for a spin-polarised adsorbate approaching a metallic surface is solved in the wide-band limit. Equations for the time-evolution of the electronic structure of the adsorbate-metal system…

材料科学 · 物理学 2009-11-11 M. S. Mizielinski , D. M. Bird , M. Persson , S. Holloway

In a recent Letter [T.~Dornheim \emph{et al.}, Phys.~Rev.~Lett.~\textbf{125}, 085001 (2020)], we have presented the first \emph{ab initio} results for the nonlinear density response of electrons in the warm dense matter regime. In the…

等离子体物理 · 物理学 2021-06-08 Tobias Dornheim , Zhandos Moldabekov , Jan Vorberger

Plasmons in two-dimensional electron systems with nonparabolic bands, such as graphene, feature strong dependence on electron-electron interactions. We use a many-body approach to relate plasmon dispersion at long wavelengths to Landau…

介观与纳米尺度物理 · 物理学 2013-12-19 L. S. Levitov , A. V. Shtyk , M. V. Feigelman