相关论文: On the theoretical description of weakly charged s…
We consider the interactions between two uncharged planar macroscopic surfaces immersed in an electrolyte solution which are induced by interfacial selectivity. These forces are taken into account by introducing a depletion free-energy…
An image system for a point charge outside a dielectric sphere is presented for all complex values of relative permittivity $\epsilon=\epsilon'+i\epsilon''$. The standard image integral solution of a point charge outside a dielectric sphere…
Poisson electrodynamics is the low-energy limit of a rank-one noncommutative gauge theory. It admits a closed formulation in terms of a Poisson structure on the space-time manifold and reproduces ordinary classical electrodynamics in the…
Ions in ionic liquids and concentrated electrolytes reside in a crowded, strongly-interacting environment, leading to the formation of discrete layers of charges at interfaces. Here, we propose a continuum theory that captures the…
We consider the nonlinear Poisson-Boltzmann equation in the context of electrostatic models for a biological macromolecule, embedded in a bounded domain containing a solution of an arbitrary number of ionic species which is not necessarily…
We derive and implement a suitable boundary condition for the kinetic description of the electrons inside a plasma, which takes into account microphysical processes inside the wall. It is based on the surface scattering kernel, which…
Plane wave density functional theory codes generally assume periodicity in all three dimensions. This causes difficulties when studying charged systems, for instance energies per unit cell become infinite, and, even after being renormalised…
The separation of solids in adhesive contact, or the fracture of solid bodies, often results in the emission of high energy photons, e.g., visible light and X-rays. This is believed to be related to charge separation. We propose that the…
Surface effects on the electronic energy loss of charged particles entering a metal surface are investigated within linear-response theory, in the framework of time-dependent density functional theory. Interesting phenomena occur in the…
A concentrated suspension of lamellar colloidal particles (e. g. clay) is modelled by considering a single, uniformly charged, finite platelet confined with co- and counterions to a Wigner-Seitz (WS) cell. The system is treated within…
This article focuses on the Vlasov-Poisson system with point charges in bounded convex domains, accounting the interactions of point charges with the self-consistent electric field and the boundary, which were not addressed in the previous…
Class-S theories are four-dimensional N=2 supersymmetric field theories constructed by the reduction of a (2,0) six-dimensional theory on a punctured Riemann surface C (called the UV curve). A basic degeneration limit of the surface C is…
We consider the long time evolution of a quantum particle weakly interacting with a phonon field. We show that in the weak coupling limit the Wigner distribution of the electron density matrix converges to the solution of the linear…
The consequences of source charge and surface modulation are studied within the framework of the Poisson-Boltzmann theory of electrolyte solutions. Through a consideration of various examples, it is found that inherent modulation can lead…
We develop a strong-coupling perturbation theory for the extended Bose-Hubbard model with on-site and nearest-neighbor boson-boson repulsions on ($d > 1$)-dimensional hypercubic lattices. Analytical expressions for the ground-state phase…
Realistic charged macromolecules are characterized by discrete (rather than homogeneous) charge distributions. We investigate the effects of surface charge discretization on the counterion distribution at the level of mean-field theory…
We use the functional integral technique of Edwards and Lenard to solve the statistical mechanics of a one dimensional Coulomb gas with boundary interactions leading to surface charging. The theory examined is a one dimensional model for a…
We extend our previous study of surface tension of ionic solutions and apply it to the case of acids (and salts) with strong ion-surface interactions. These ion-surface interactions yield a non-linear boundary condition with an effective…
This review explores the number of mean-field constructions for ions whose structure goes beyond the point-charge description, a representation used in the standard Poisson-Boltzmann equation. The exploration is motivated by a body of…
Brushes formed by arm-tethered starlike polyelectrolytes may exhibit internal segregation into weakly and strongly extended populations (stratified two-layer structure) when strong ionic intermolecular repulsions induce stretching of the…