相关论文: Quantum Confinement in Hydrogen Bond

We calculate the effect of a spatially dependent effective mass (SPDEM) [adapted from R. N. Costa Filho et al. Phys. Rev. A., \textbf{84} 050102 (2011)] on an electron and hole confined in a quantum well (QW). In the work of Costa Filho et…

Understanding the influence of vibrational motion of the atoms on electronic transitions in molecules constitutes a cornerstone of quantum physics, as epitomized by the Franck-Condon principle of spectroscopy. Recent advances in building…

Using a single-band model, the lowest transition energy was analysed between the lowest unoccupied molecular orbital (LUMO) of the conduction band and the highest occupied molecular orbital (HOMO) of the valence band. We focus on…

Atoms start behaving as waves rather than classical particles if confined in spaces commensurate with their de Broglie wavelength. At room temperature this length is only about one angstrom even for the lightest atom, hydrogen. This…

The physical nature and the correct definition of hydrogen bond (H-bond) are considered.\,\,The influence of H-bonds on the thermodynamic, kinetic, and spectroscopic properties of water is analyzed.\,\,The conventional model of H-bonds as…

We demonstrate an effective method for calculating bound-to-continuum cross-sections by examining transitions to bound states above the ionization energy that result from placing the system of interest within an infinite spherical well.…

In this work, we investigate the influence of torsion, Aharonov-Bohm flux, and external magnetic fields on the linear and nonlinear optical properties of a confined quantum system. The confinement potential is not assumed a priori, but…

The thermodynamics of a homopolymeric chain with both Van der Waals and highly-directional hydrogen bond interaction is studied. The effect of hydrogen bonds is to reduce dramatically the entropy of low-lying states and to give raise to…

We report on the observation of confinement-induced resonances in strongly interacting quantum-gas systems with tunable interactions for one- and two-dimensional geometry. Atom-atom scattering is substantially modified when the s-wave…

In developing our previous contribution (arXiv:1804.00889) we have numerically found the bound state energy and correspondent wave function of the two electrons confined to move in a quantum well placed close to the gate electrode.…

We propose a new type of hybrid systems formed by conventional semiconductor nanostructures with the addition of remote insulating layers, where the electron-hole interaction is enhanced by combining quantum and dielectric confinement over…

The variational method is used to study the hard confinement of a two-particle quantum system in two potential models, the Cornell potential and the global potential, with Dirichlet-type boundary conditions at various cut-off radii. The…

The Hawking effect -- the spontaneous emission of correlated quanta from horizons -- can be observed in laboratory systems where an acoustic horizon forms when a fluid transitions from subcritical to supercritical flow. Although most…

We study a partially ionized hydrogen plasma by means of quantum molecular dynamics, which is based on wave packets. We introduce a new model which distinguishes between free and bound electrons. The free electrons are modelled as Gaussian…

The covalent-like characteristics of hydrogen bonds offer a new perspective on intermolecular interactions. Here, using density functional theory and post-Hartree-Fock methods, we reveal that there are two bonding molecular orbitals (MOs)…

We present results on electron transport in quasi-one dimensional (1D) quantum wires in GaAs/AlGaAs heterostructures obtained using an asymmetric confinement potential. The variation of the energy levels of the spatially quantized states is…

We demonstrate that the confinement of half-quantized vortices (HQVs) in coherently coupled Bose-Einstein condensates (BECs) simulates certain aspects of the confinement in $SU(2)$ quantum chromodynamics (QCD) in 2+1 space-time dimensions.…

Scaling down the GaN channel in a double heterostructure AlGaN/GaN/AlGaN High Electron Mobility Transistor (HEMT) to the thicknesses on the order of or even smaller than the Bohr radius confines electrons in the quantum well even at low…

This study presents the confinement influences of Aharonov-Bohm-flux (AB-flux), electric and magnetic fields directed along $z$-axis and encircled by quantum plasmas, on the hydrogen atom. The all-inclusive effects result to a strongly…

Photodetachment of H$^-$ near a potential barrier is studied. A new formula is presented for the cross sections induced by a barrier. The new formula describes two quantum effects near barrier tops. For energies near and above barrier tops,…