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We report the effects of variation in length on the electronic structure of CdSe nanorods derived from atomic clusters and passivated by fictitious hydrogen atoms. These nanorods are augmented by attaching gold clusters at both the ends to…

介观与纳米尺度物理 · 物理学 2017-09-13 Deepashri Saraf , Anjali Kshirsagar

In this paper we present new results on electronic emission of Gold Nanoparticles (GNPs) using X-ray photoelectron spectroscopy (XPS) and compare them to the gold bulk electron emission. This subject has undergone new interest within the…

In order to control and tailor the properties of nanodots, it is essential to separate the effects of quantum confinement from those due to the surface, and to gain insight into the influence of preparation conditions on the dot physical…

材料科学 · 物理学 2009-10-31 Laurent Pizzagalli , Giulia Galli , John E. Klepeis , Francois Gygi

We predict general trends for surface segregation in a binary metal cluster based on the difference between the atomic properties of the constituent elements. Considering the attractive and repulsive contributions of the cohesive energy of…

材料科学 · 物理学 2008-05-12 Juan Andrés Reyes-Nava , José Luis Rodríguez-López , Umapada Pal

In the process of molecular dynamics simulation studies of gold nanowires an interesting structure is discovered. This is a finite double-wall nanowire with a large empty core similar to single-wall and double-wall carbon nanotubes. The…

材料科学 · 物理学 2007-05-23 G. Bilalbegovic

We report on the crystallographic structure of penta-twinned gold nanoparticles. Although gold typically exhibits a face-centered cubic (fcc) lattice, other phases have been reported in some nanoscale systems. We show that the…

We report an easy and broadly applicable method for the controlled self-assembly of atomically precise Au32(nBu3P)12Cl8 nanoclusters into micro-crystals. This enables the determination of emergent optoelectronic properties resulting from…

In this work, the structural and magnetic properties of the gold-coated FePt nanoparticles synthesized from high-temperature solution phase are presented. The amount of gold was optimized to obtain most of the FePt particles coated. The…

材料科学 · 物理学 2009-11-26 P. de la Presa , M. Multigner , M. P. Morales , T. Rueda , E. Fernandez-Pinel , A. Hernando

In this paper, the interaction of few tens of atoms containing gold nanoclusters with two dimensional nanosheets of transition metal dichalcogenides nanosheets has been explored. The gold nanoclusters have been synthesized using chemical…

材料科学 · 物理学 2020-01-30 Arun Singh Patel , Anirban Chakraborti , Praveen Mishra

The performance of gold nanoparticles (NPs) in applications depends critically on the structure of the NP-solvent interface, at which the electrostatic surface polarization is one of the key characteristics that affects hydration, ionic…

化学物理 · 物理学 2021-09-20 Zhujie Li , Victor G. Ruiz , Matej Kanduč , Joachim Dzubiella

Deep understanding of plasmonic nanoparticles (PNPs)-light interaction over semiconductors surface shows great promises in enhancing their optoelectronic devices efficiency beyond the conventional limit. However, PNP-light interaction…

应用物理 · 物理学 2018-10-01 Kanika Arora , Vishal Kumar , Mukesh Kumar

Gold nanostructures have important applications in nanoelectronics, nano-optics as well as in precision metrology due to their intriguing opto-electronic properties. These properties are governed by the bulk band structure but to some…

We study the role of gold droplets in the initial stage of nanowire growth via the vapor liquid solid method. Apart from serving as a collections center for growth species, the gold droplets carry an additional crucial role that necessarily…

The search for new ultra strong materials has been a very active research area. With relation to metals, a successful way to improve their strength is by the creation of a gradient of nanograins (GNG) inside the material. Recently, R.…

We have studied complexes of gold atoms and imidazole (C$_3$N$_2$H$_4$, abbreviated Im) produced in helium nanodroplets. Following the ionization of the doped droplets we detect a broad range of different Au$_m$Im$_n^+$ complexes, however…

The geometric and electronic structures of NaN, CuN, and AgN metal clusters are systematically studied based on the density functional theory over a wide range of cluster sizes 2=<N=<75. A remarkable similarity is observed between the…

材料科学 · 物理学 2015-05-13 Masahiro Itoh , Vijay Kumar , Tadafumi Adschiri , Yoshiyuki Kawazoe

Experimental results showing huge negative differential conductance in gold-hydrogen molecular nanojunctions are presented. The results are analyzed in terms of two-level system (TLS) models: it is shown that a simple TLS model cannot…

介观与纳米尺度物理 · 物理学 2008-02-19 A. Halbritter , P. Makk , Sz. Csonka , G. Mihaly

Surface structure affects the growth, shape and properties of nanoparticles. In wet chemical syntheses, metal additives and surfactants are used to modify surfaces and guide nanocrystal growth. To understand this process, it is critical to…

The combination of nanodiamonds with plasmonic metal particles is being explored for synergic effects that can enhance biosensing and antibacterial treatments, energy harvesting, photocatalysis, and quantum centres. Here we systematically…