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For arbitrary values n and l quantum numbers, we present the solutions of the 3-dimensional Schrodinger wave equation with the pseudoharmonic potential via SU(1,1) Spectrum Generating Algebra (SGA) approach. The explicit bound state…

化学物理 · 物理学 2011-05-12 K. J. Oyewumi , K. D. Sen

We present a new computational method for the determination of energy levels in four-particle systems like H$_2$, HD, and HeH$^+$ using explicitly correlated exponential basis functions and analytic integration formulas. In solving the…

化学物理 · 物理学 2018-02-14 Krzysztof Pachucki , Jacek Komasa

The main motivation for this work is the exploration of rotational-vibrational states corresponding to electronic excitations in a pre-Born-Oppenheimer quantum theory of molecules. These states are often embedded in the continuum of the…

化学物理 · 物理学 2018-10-15 Edit Mátyus

The nonrelativistic variational calculation of a complete set of ro-vibrational states in the H$_2^+$ molecular ion supported by the ground $1s\sigma$ adiabatic potential is presented. It includes both bound states and resonances located…

原子物理 · 物理学 2020-11-03 Vladimir I. Korobov

In this work, the bound state problem of some diatomic molecules in the Tietz-Wei potential with varying shapes is correctly solved by means of path integrals. Explicit path integration leads to the radial Green's function in closed form…

量子物理 · 物理学 2019-12-02 A. Khodja , A. Kadja , F. Benamira , L. Guechi

Quantum mechanical scalar particle with polarizability is considered in the presence of the Coulomb field. Separation of variables is performed with the use of Wigner $D$-functions, the radial system of 15 equations is reduced to a single…

数学物理 · 物理学 2011-09-16 V. Kisel , G. Krylov , E. Ovsiyuk , M. Amirfachrian , V. Red'kov

We calculate the bound state spectrum of the highly excited valence electron in the heavy alkali atoms solving the radial Schr\"odinger eigenvalue problem numerically with an accurate spectral collocation algorithm that applies also for a…

量子物理 · 物理学 2016-07-14 Ali Sanayei , Nils Schopohl

The leading nonadiabatic corrections to rovibrational levels of a diatomic molecule are expressed in terms of three functions of internuclear distance: corrections to the adiabatic potential, the effective nuclear mass, and the effective…

化学物理 · 物理学 2015-05-13 Krzysztof Pachucki , Jacek Komasa

We present an accurate theoretical determination of rovibrational energy levels of the hydrogen molecule and its isotopologues in its electronic ground state. We consider all significant corrections to the Born-Oppenheimer approximation,…

A variational solution to the rovibrational problem in curvilinear vibrational coordinates has been implemented and used to investigate the nuclear motions in several linear triatomic molecules, like HCN, OCS, and HCP. The dependence of the…

化学物理 · 物理学 2011-11-15 Leonid Shirkov , Tatiana Korona , Robert Moszynski

The approximate analytical bound state solution of the Schr\"odinger equation for the Manning-Rosen potential is carried out by taking a new approximation scheme to the orbital centrifugal term. The Nikiforov-Uvarov method is used in the…

量子物理 · 物理学 2012-03-14 Sameer M. Ikhdair

This is the first in a series of articles in which we study the rotating Morse potential model for diatomic molecules in the tridiagonal J-matrix representation. Here, we compute the bound states energy spectrum by diagonalizing the finite…

化学物理 · 物理学 2011-11-10 I. Nasser , M. S. Abdelmonem , H. Bahlouli , A. D. Alhaidari

The pseudospectral method is a powerful tool for finding highly precise solutions of Schr\"{o}dinger's equation for few-electron problems. We extend the method's scope to wave functions with non-zero angular momentum and test it on several…

原子物理 · 物理学 2013-05-29 Paul E. Grabowski , David F. Chernoff

We examine the impact of the combination of a static electric field and a non resonant linearly polarized laser field on an asymmetric top molecule. Within the rigid rotor approximation, we analyze the symmetries of the Hamiltonian for all…

化学物理 · 物理学 2015-05-28 J. J. Omiste , R. González-Férez , P. Schmelcher

Investigations of the exactly solvable excitation spectra of two-electron quantum dots with a parabolic confinement, for different values of the parameter R_W expressing the relative magnitudes of the interelectron repulsion and the…

介观与纳米尺度物理 · 物理学 2009-01-23 Constantine Yannouleas , Uzi Landman

We have developed a simple method to solve anharmonic oscillators equations. The idea of our method is mainly based on the partitioning of the potential curve into (n+1) small intervals, solving the Schr\"odinger equation in each…

量子物理 · 物理学 2008-12-23 F. Maiz , M. Nasr

We consider the radial Schr\" odinger equation with the pseudo-Gaussian potential. By making an ansatz to the solution of the eigenvalue equation for the associate Hamiltonian, we arrive at the general exact eigenfunction. The values of…

量子物理 · 物理学 2015-12-29 Felix Iacob , Lute Marina

Exact solution of Schrodinger equation for the Mie potential is obtained for an arbitrary angular momentum. The energy eigenvalues and the corresponding wavefunctions are calculated by the use of the Nikiforov-Uvarov method. Wavefunctions…

量子物理 · 物理学 2008-01-28 Ramazan Sever , Mahmut Bucurgat , Cevdet Tezcan , Ozlem Yesiltas

In this study, we obtain the approximate analytical solutions of the radial Schr\"{o}dinger equation for the Deng-Fan diatomic molecular potential by using exact quantization rule approach. The wave functions have been expressed by…

化学物理 · 物理学 2015-04-09 Babatunde. J. Falaye , Sameer M. Ikhdair , Majid Hamzavi

The non-relativistic three-body Schr\"odinger equation of the heteronuclear molecular ion HD$^+$ is solved in perimetric coordinates using the Lagrange-mesh method. Energies and wave functions of the four lowest vibrational bound or…

原子与分子团簇 · 物理学 2015-06-16 Horacio Olivares Pilón , Daniel Baye