相关论文: Ceria co-doping: Synergistic or average effect?
Ceria (CeO$_2$) is a material of significant technological importance. A detailed understanding of the material's defect physics and chemistry is key to understanding and optimizing its properties. Here, we report a hybrid…
Co-doping of Ce-doped LaBr$_3$ with Ba, Ca, or Sr improves the energy resolution that can be achieved by radiation detectors based on these materials. Here, we present a mechanism that rationalizes of this enhancement that on the basis of…
Here we present linear and circular polarized soft x-ray absorption spectroscopy (XAS) data at the Ce $M_{4,5}$ edges of the electron (Ir) and hole-doped (Re) Kondo semiconductor CeOs$_2$Al$_{10}$. Both substitutions have a strong impact on…
Silicate bioceramics have attracted significant attention in medical applications, particularly in hard tissue regeneration, because of their controllable chemical, physical, and biological functionalities, while ensuring biocompatibility.…
Eutectics of Sapphire/Yttrium-Aluminum garnet and Ce-doped Sapphire/Yttrium-Aluminum garnet (Ce up to 1 at.%) with a Chinese script microstructure were obtained by the method of horizontal directional crystallization in a carbon-containing…
We report a systematic study on the effect of partial substitution of Sc$^{3+}$ by Ti$^{4+}$ in Sr$_{2}$ScFeAsO$_{3}$, Ca$_{2}$ScFeAsO$_{3}$ and Sr$_{3}$Sc$_{2}$Fe$_{2}$As$_{2}$O$_{5}$ on their electrical properties. High level of doping…
Cerium oxide (ceria, CeO2) is one of the most promising mixed ionic and electronic conducting materials. Previous atomistic analysis has covered widely the effects of substitution on oxygen vacancy migration. However, an in-depth analysis…
We report the structural, magnetic and electrical transport properties of Y$_2$Ir$_{2-x}$Cr$_x$O$_7$ pyrochlore iridates. The chemical doping leads to order of magnitude enhancement of electrical conductivity. The introduction of Cr3+ at…
We studied the optical conductivity of electron doped Pr{1-x)Ce(x)CuO(4) from the underdoped to the overdoped regime. The observation of low to high frequency spectral weight transfer reveals the presence of a gap, except in the overdoped…
We report superconductivity in polycrystalline samples of the 1038-type compounds (Ca$_{1-x}$RE$_x$)$_{10}$(FeAs)$_{10}$(Pt$_3$As$_8$) up to T$_c$ = 35 K with RE = Y, La-Nd, Sm, Gd-Lu. The critical temperatures are independent of the…
Ceria has proven to be an excellent ion-transport and ion-exchange material when used in polycrystalline form and with a high-concentration of aliovalent doped cations. Despite its widespread application, the impact of atomic-scale defects…
We have performed x-ray absorption spectroscopy (XAS) and x-ray magnetic circular dichroism (XMCD) studies of the diluted ferromagnetic semiconductor Zn$_{1-\textit{x}}$Cr$_\textit{x}$Te doped with iodine (I) or nitrogen (N), corresponding…
The hybridization between the localized 4$f$ level ($f$) with conduction ($c$) states in $\gamma$-Ce upon cooling has been previously revealed in single crystalline thin films experimentally and theoretically, whereas its influence on the…
Using functional renormalization group we investigated possible superconductivity in doped Sr$_2$IrO$_4$. In the electron doped case, a $d^*_{x^2-y^2}$-wave superconducting phase is found in a narrow doping region. The pairing is driven by…
A mean field calculation of the $T\to 0$ limit of the Hall conductance of electron-doped cuprates such as $Pr_{2-x}Ce_xCuO_{4+\delta}$ is presented. The data are found to be qualitatively consistent with the reconstruction of the Fermi…
The effects of chlorine (Cl) and zinc (Zn) co-doping on the electronic structure and optical properties of the zinc blende ({\gamma}) phase of copper iodide ({\gamma}-CuI) scintillator material are investigated by using first-principles…
We report the thermoelectric properties (Seebeck coefficient, thermal conductivity, and electrical resistivity) of lightly doped single crystals of (001)-oriented SrTiO3 (STO). Hall effect measurements show that electron doping around 10^-5…
We report on resistivity and Hall measurements in thin films of the electron-doped superconducting cuprate Pr$_{2-x}$Ce$_{x}$CuO$_{4\pm\delta}$. Comparisons between x = 0.17 samples subjected to either ion-irradiation or oxygenation…
Fluorite CeO$_2$ doped with group IV elements is studied within the DFT and DFT+U framework. Concentration dependent formation energies are calculated for Ce$_{1-x}$Z$_x$O$_2$ (Z= C, Si, Ge, Sn, Pb, Ti, Zr, Hf) with $0\leq x \leq 0.25$ and…
Recent investigations have shown that highly oxygen defective cerium oxides generate non-classical electrostriction that is superior to lead-based ferroelectrics. In this work, we report the effect of field-assisted spark plasma sintering…