相关论文: The critical compressibility factor of fluids from…
We show how to obtain the critical compressibility factor $Z_c$ for simple and associative Lennard-Jones fluids using the critical characteristics of the Ising model on different lattices. The explanation for the results on the critical…
The interpretation of the linear character of the observable classic rectilinear diameter law and the linear character of the Zeno-line (unit compressibility line Z=1) on the basis of global isomorphism between Ising model (Lattice Gas) and…
In this communication we show that the surface tension of the real fluids of the Lennard-Jones type can be obtained from the surface tension of the lattice gas (Ising model) on the basis of the global isomorphism approach developed earlier…
The approach of global isomorphism between the fluid and the Ising model is applied to obtain an expression for the surface tension of the Lennard-Jones fluid on the basis of the information about the Ising model. This is done in a broad…
In this paper we apply the global isomorphism approach [V.~L. Kulinskii, J. Phys. Chem. B \textbf{114} 2852 (2010)] between the Lennard-Jones fluids and Lattice Gas model to the study of the liquid-vapor equilibrium for the systems with the…
The dimensionless value of critical compressibility factor in the van der Waals theory of gas-liquid critical point is a universal constant, $Z_\text{c} = 0.375$. Experimentally measured values of this quantity for simple fluids are…
A fluctuating non-ideal fluid at its critical point is simulated with the Lattice Boltzmann method. It is demonstrated that the method, employing a Ginzburg-Landau free energy functional, correctly reproduces the static critical behavior…
Liquid-gas equilibrium is considered using the global isomorphism with the Ising-like (lattice gas) model. Such an approach assumes the existence of the order parameter in terms of which the symmetry of binodal is restored not only in the…
The gas-liquid phase transition of the three-dimensional Lennard-Jones particles system is studied by molecular dynamics simulations. The gas and liquid densities in the coexisting state are determined with high accuracy. The critical point…
Molecular dynamic simulations for systems with $D=2,3$ Lennard-Jones-like interactions are studied. In the model, we assume that, at long distances, the two-body attractive potential decays as $r^{-\alpha}$. Thermodynamic extensivity…
Using the approach formulated in the previous papers of the author, a consistent procedure is developed for calculating non-classical asymptotic power terms in the total and the direct correlation functions of a critical fluid. Analyzing…
We show that, along the critical isobar, the complete scaling results in a unique leading scaling qualitatively distinct to that arising from the simple and the revised scalings. This is verified by a complete-field finite-time scaling…
The phase behavior of fluids near weakly attractive substrates is studied by computer simulations of the coexistence curve of a Lennard-Jones (LJ) fluid confined in a slitlike pore. The temperature dependence of the density profiles of the…
We analyze the interrelation between the coexistence curve of the Lennard-Jones fluid and the Ising model in two and three dimensions within the global isomorphism approach proposed earlier [V. L. Kulinskii, J. Phys. Chem. B \textbf{114}…
Critical phenomena in real fluids demonstrate a combination of universal features caused by the divergence of long-range fluctuations of density and nonuniversal (system-dependent) features associated with specific intermolecular…
A Lorentz gas may be defined as a system of fixed dispersing scatterers, with a single light particle moving among these and making specular collisions on encounters with the scatterers. For a dilute Lorentz gas with open boundaries in $d$…
We introduce a nonequilibrium off--lattice model for anisotropic phenomena in fluids. This is a Lennard--Jones generalization of the driven lattice--gas model in which the particles' spatial coordinates vary continuously. A comparison…
Critical properties of lattice gases with nearest-neighbor exclusion are investigated via the adaptive-window Wang-Landau algorithm on the square and simple cubic lattices, for which the model is known to exhibit an Ising-like phase…
A Landau-Ginzburg functional of two order parameters (charge-density $\phi$ and mass-density deviation $\eta$) is developed in order to yield a field theory relevant to ionic lattice gases as well as a family of off-lattice models of ionic…
The unified geometrical interpretation of the linear character of the Zeno-line (unit compressibility line Z=1) and the rectilinear diameter is proposed. We show that recent findings about the properties of the Zeno-line and striking…