相关论文: Surface tension model for surfactant solutions at …
The effects of line tension on the morphology of a sessile droplet placed on top of a convex spherical substrate are studied. The morphology of the droplet is determined from the global minimum of the Helmholtz free energy. The contact…
We study spreading of a droplet, with insoluble surfactant covering its capillary surface, on a textured substrate. In this process, the surfactant-dependent surface tension dominates the behaviors of the whole dynamics, particularly the…
Surface tension is a macroscopic manifestation of the cohesion of matter, and its value $\sigma_\infty$ is readily measured for a flat liquid-vapor interface. For interfaces with a small radius of curvature $R$, the surface tension might…
We carry out the calculation of the surface tension for a model electrolyte to first order in a cumulant expansion about a free field theory equivalent to the Debye-H\"uckel approximation. In contrast with previous calculations, the surface…
We have analyzed the mechanical properties of surfactant loaded tensionless balanced liquid/liquid interfaces using self-consistent field theory implementing a coarse grained model. Such a tensionless state, as occurring in microemulsions,…
Charged colloidal monolayers at the interface between water and air (or oil) are used in a large number of chemical, physical and biological applications. Although a considerable experimental and theoretical effort has been devoted in the…
The structure and stability of the convective flow generated by a source located at the water surface containing an insoluble surfactant layer are experimentally investigated. Application of a few types of source, which differ in the force…
By means of extensive equilibrium molecular dynamics simulations we have investigated, the behavior of the interfacial tension $\gamma$ of two immiscible symmetrical Lennard-Jones fluids. This quantity is studied as function of reduced…
We introduce a novel method for calculating the size of the critical nucleus and the value of the surface tension in systems with first order phase transition. The method is based on classical nucleation theory, and it consists in studying…
We propose a nonlocal model for surface tension. This model, in combination with the Landau-Lifshitz-Navier-Stokes equations, describes mesoscale features of the multiphase flow, including the static (pressure) tensor and curvature…
We report the flow dynamics of two shear-banding wormlike micellar solutions with distinct surfactant chemistries in a Taylor-Couette (TC) setup following a startup shear. The solutions, formulated with CTAB/NaSal and CPyCl/NaSal, exhibit…
In this paper we study the main surface characteristics which control the foamability of solutions of various surfactants. Experiments with anionic, cationic and nonionic surfactants with different head groups and chain lengths are…
Fluid three-phase equilibria, with phases $\alpha, \beta, \gamma$, are studied close to a tricritical point, analytically and numerically, in a mean-field density-functional theory with two densities. Employing Griffiths' scaling for the…
A micelle consists of monolayer of lipid molecules containing hydrophilic head and hydrophobic tail. These amphiphilic molecules in aqueous environment aggregate spontaneously into monomolecular layer held together due to hydrophobic effect…
Dynamic surface tension measurements play a critical role in interfacial activities for liquids with varying viscosities. Understanding the rate at which the interface attains the equilibrium, for surface tension measurements, after the…
Following up a recent paper on grafted sliding polymer layers (Macromolecules 2005, 38, 1434-1441), we investigated the influence of the sliding degree of freedom on the self-assembly of sliding polymeric surfactants that can be obtained by…
The Martini model, a coarse-grained forcefield for biomolecular simulations, has experienced a vast increase in popularity in the past decade. Its building-block approach balances computational efficiency with high chemical specificity,…
In this paper, using an unified approach, estimates are given of the magnitude of the surface tension of water for planar and curved interfaces in the pairwase interaction approximation based on the Lennard-Jones potential. It is shown that…
Using a hydrodynamic lattice-gas model, we study interface growth in a binary fluid with various concentrations of surfactant. We find that the interface is smoothed by small concentrations of surfactant, while microemulsion droplets form…
The paper focuses on a model describing the spreading of an insoluble surfactant on a thin viscous film with capillary effects taken into account. The governing equation for the film height is degenerate parabolic of fourth order and…