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相关论文: Valence Instability of YbCu$_2$Si$_2$ through its …

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We investigate the Yb valence instabilities in the strongly correlated YbPd compound using resonant X-ray emission spectroscopy as a function of pressure across the charge-order (CO) transition. At a low temperature (T = 30 K) in the CO…

The valence state of Yb ions in beta-YbAlB4 and its polymorph alpha-YbAlB4 has been investigated by using X-ray absorption and emission spectroscopy in SPring-8 at temperatures from 2 to 280 K. The observed Yb valence is 2.78 +- 0.01 in…

强关联电子 · 物理学 2013-08-09 Y. H. Matsuda , T. Nakamura , K. Kuga , S. Nakatsuji , S. Michimura , T. Inami , N. Kawamura , M. Mizumaki

The pressure-temperature phase diagram of an intermediate-valence compound YbPd was revealed via simultaneous ac-calorimetry and electrical resistivity measurements. Two successive structural phase transition temperatures, $T_1$ = 125 K and…

Simultaneous resistivity and a.c.-specific heat measurements have been performed under pressure on single crystalline CeCu2Si2 to over 6 GPa in a hydrostatic helium pressure medium. A series of anomalies were observed around the pressure…

强关联电子 · 物理学 2007-05-23 A. T. Holmes , D. Jaccard , K. Miyake

Similar to transitions in a range of correlated quantum materials, the valence transition exhibits a strong coupling to the crystal lattice, rendering it highly sensitive to stress tuning. In the present work, we determine the effect of…

强关联电子 · 物理学 2025-08-07 Caitlin I. O'Neil , Michelle Ocker , Kristin Kliemt , Cornelius Krellner , Elena Gati

A resonant inelastic x-ray scattering study of the electronic structure of the semiconductor cuprous oxide, $\rm Cu_2O$, is reported. When the incident x-ray energy is tuned to the Cu K-absorption edge, large enhancements of the spectral…

材料科学 · 物理学 2012-06-18 Young-June Kim , J. P. Hill , H. Yamaguchi , T. Gog , D. Casa

It has been known that the elemental Yb, a divalent metal at mbient pressure, becomes a mixed-valent metal under external pressure, with its valence reaching ~2.6 at 30 GPa. In this work, infrared spectroscopy has been used to probe the…

强关联电子 · 物理学 2015-06-25 H. Okamura , K. Senoo , M. Matsunami , T. Nanba

We present a dynamical mean field theory study of the valence transition ($f^{14} \to f^{13}$) in elemental, metallic Yb under pressure. Our calculations reproduce the observed valence transition as reflected in the volume dependence of the…

强关联电子 · 物理学 2010-05-12 E. R. Ylvisaker , J. Kuneš , A. K. McMahan , W. E. Pickett

We report electrical resistivity, ac magnetic susceptibility and X-ray absorption spectroscopy measurements of intermediate valence YbNi$_{3}$Ga$_{9}$ under pressure and magnetic field. We have revealed a characteristic pressure-induced Yb…

Temperature dependence of the X-ray absorption near-edge structure (XANES) spectra at the Pr $L_{3}$- and Tb $L_{3}$-edges was measured for the (Pr$_{1-y}$Tb$_{y})_{0.7}$Ca$_{0.3}$CoO$_{3}$ system, in which a metal-insulator (MI) and…

材料科学 · 物理学 2013-05-01 H. Fujishiro , T. Naito , D. Takeda , N. Yoshida , T. Watanabe , K. Nitta , J. Hejtmanek , K. Knizek , Z. Jirak

We report on the study of the response to high pressures of the electronic and magnetic properties of several Sm-based compounds, which span at ambient pressure the whole range of stable charge states between the divalent and the trivalent.…

We have performed pressure dependent X-ray diffraction and resonant X-ray emission spectroscopy experiments on USb$_2$ to further characterize the AFM-FM transition occurring near 8 GPa. We have found the magnetic transition coincides with…

Yb$_2$Si$_2$Al may be a prototype for exploring different aspects of the Shastry-Sutherland lattice, formed by planes of orthogonally coupled Yb ions. Measurements of the magnetic susceptibility find incoherently fluctuating Yb$^{3+}$…

We report measurements of the physical properties and electronic structure of the hexagonal compounds Yb2Ni12Pn7 (Pn = P, As) by measuring the electrical resistivity, magnetization, specific heat and partial fluorescence yield x-ray…

We report a comprehensive structural and valence study of the intermediate valent materials YbNiGa$_{4}$ and YbNiIn$_{4}$ under pressures up to 60 GPa. YbNiGa$_{4}$ undergoes a smooth volume contraction and shows steady increase in…

The resonant inelastic x-ray scattering (RIXS) was measured in an insulating SrCuO$_{2}$ with changing the incident photon energy ($h\nu$) near the Cu $1s$ absorption edge (K-edge). Complex structures and their dependences on the momentum…

Unconventional quantum critical phenomena observed in Yb-based periodic crystals such as YbRh$_2$Si$_2$ and $\beta$-YbAlB$_4$ have been one of the central issues in strongly correlated electron systems. The common criticality has been…

强关联电子 · 物理学 2017-03-14 Shinji Watanabe , Kazumasa Miyake

High pressure x-ray diffraction up to 30 GPa and resonant emission x-ray spectroscopy and partial fluorescence yield x-ray absorption spectroscopy up to 52 GPa were used to study how the structural and electronic properties of UTe$_2$…

In order to probe the changes in the valence state and magnetic properties of Eu metal under extreme pressure, x-ray absorption near-edge spectroscopy, x-ray magnetic circular dichroism and synchrotron M\"ossbauer spectroscopy experiments…

We present results of magnetic susceptibility and thermal expansion measurements performed on high-quality single crystals of EuPd$_2$(Si$_{1-x}$Ge$_x$)$_2$ for 0 $\leq$ x $\leq$ 0.2 and temperatures 2 K $\leq T \leq$ 300 K. Data were taken…

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