相关论文: Clausius versus Sackur-Tetrode entropies
To illustrate Boltzmann's construction of an entropy function that is defined for a microstate of a macroscopic system, we present here the simple example of the free expansion of a one dimensional gas of non-interacting point particles.…
Statistical mechanics explains thermodynamics in terms of (quantum) mechanics by equating the entropy of a microstate of a closed system with the logarithm of the number of microstates in the macrostate to which it belongs, but the question…
Quantum mechanics is derived as an application of the method of maximum entropy. No appeal is made to any underlying classical action principle whether deterministic or stochastic. Instead, the basic assumption is that in addition to the…
In this document we are interested in entropy. Entropy is multiple, the idea is to describe the definition proposed by the physicist Clausius. Indeed, Clausius exposes in 1865 the second principle of thermodynamics and also proposes the…
Free energy and entropy are examined in detail from the standpoint of classical thermodynamics. The approach is logically based on the fact that thermodynamic work is mediated by thermal energy through the tendency for nonthermal energy to…
The Bousso entropy bound, in its generalized form, is investigated for the case of perfect fluids at local thermodynamic equilibrium and evidence is found that the bound is satisfied if and only if a certain local thermodynamic property…
A definition of the thermodynamic entropy based on the time-dependent probability distribution of the macroscopic variables is developed. When a constraint in a composite system is released, the probability distribution for the new…
We review recent developments on the thermodynamics of black holes in extended phase space, where the cosmological constant is interpreted as thermodynamic pressure and treated as a thermodynamic variable in its own right. In this approach,…
We explore a recently introduced quantum thermodynamic entropy $S^Q_{univ}$ of a pure state of a composite system-environment computational "universe" with a simple system $\mathcal{S}$ coupled to a constant temperature bath $\mathcal{E}$.…
In this work the non-additive entropy is examined. It appears in isolated particle systems composed of few components. Therefore, the mixing of isolated particle systems S=S1+S2 has been studied. Two cases are considered T1=T2 and T1\leqT2,…
A quantum statistical expression for the entropy of a nonequilibrium system is defined so as to be consistent with Gibbs' relation, and is shown to corresponds to dynamical variable by introducing analogous to the Heisenberg picture in…
Starting from an algebraic approach of quantum physics it has been shown via the Tomita-Takesaki theorem and the KMS condition that the canonical density matrix contains the dynamics of the system provided we use a rescaling of time. In…
Applying Clausius relation with energy-supply defined by the unified first law of thermodynamics formalism to the apparent horizon of a massive cosmological model proposed lately, the corrected entropic formula of the apparent horizon is…
In this work we revisit the concept of chemical potential $\mu$ in both classical and quantum gases from a perspective of Equilibrium Statistical Mechanics (ESM). Two new results regarding the equation of state $\mu=\mu(n,T)$, where $n$ is…
Temperature is introduced as a derived concept from energy and entropy. We consider two sub-systems in equilibrium for several configurations. The equality of temperature of the sub-systems is obtained from the equilibrium condition. The…
In economics, construction of perfect models in a way that would be comparable to the standards customary in physical sciences is generally not feasible. In particular, the observed value for an economic equilibrium may deviate…
The basic thermodynamic quantities for a non-interacting scalar field in a periodic potential composed of either a one-dimensional chain of Dirac $\delta$-$\delta^\prime$ functions or a specific potential with extended compact support are…
A pure quantum state can fully describe thermal equilibrium as long as one focuses on local observables. Thermodynamic entropy can also be recovered as the entanglement entropy of small subsystems. When the size of the subsystem increases,…
By using entropy and entropy production, we calculate the steady flux of some phenomena. The method we use is a competition method, $S_S/\tau+\sigma={\it maximum}$, where $S_S$ is system entropy, $\sigma$ is entropy production and $\tau$ is…
A question that is currently highly debated is whether the microcanonical entropy should be expressed as the logarithm of the phase volume (volume entropy, also known as the Gibbs entropy) or as the logarithm of the density of states…