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Field-induced self-organized patterning in ultrathin (< 100 nm) polymer films produces resolutions of the order of 10 {\mu}m or more because of the high energy penalty for the surface deformations on small scales. We propose here a very…

软凝聚态物质 · 物理学 2010-09-28 Ankur Verma , Ashutosh Sharma

Dewetting of thin polystyrene films deposited onto silicone wafers at temperatures close to the glass transition exhibits unusual dynamics and front morphologies. Here, we present a new theoretical approach of these phenomena taking into…

软凝聚态物质 · 物理学 2007-05-23 Elie Raphael , Thomas Vilmin

The morphological paths towards equilibrium droplets during the late stages of the dewetting process of a liquid film from a liquid substrate is investigated experimentally and theoretically. As liquids, short chained polystyrene (PS) and…

软凝聚态物质 · 物理学 2012-12-07 Stefan Bommer , Sebastian Jachalski , Dirk Peschka , Ralf Seemann , Barbara Wagner

The stability of thin liquid films on a surface depends on the excess free energy of the system involving various short-range and long-range interactions. In an unstable condition, thin liquid films may dewet into multiple small-sized…

软凝聚态物质 · 物理学 2022-03-24 Bidisha Bhatt , Shivam Gupta , Vasudevan Sumathi , Sivasurender Chandran , Krishnacharya Khare

The instability, dynamics and morphological transitions of patterns in thin liquid films on periodic striped surfaces (consisting of alternating less and more wettable stripes) are investigated based on 3-D nonlinear simulations that…

软凝聚态物质 · 物理学 2009-11-07 K. Kargupta , A. Sharma

Liquid films of nanometric thickness are prone to spinodal dewetting driven by disjoining pressure, meaning that a non-wetting liquid film of homogeneous thickness in the range of tens of nanometers will spontaneously break into droplets.…

流体动力学 · 物理学 2025-04-11 Tilman Richter , Paolo Malgaretti , Jens Harting

Ultrathin metal films exhibit liquid-like instabilities, rupturing via surface diffusion far below their melting points. This behavior constrains thermal budgets for advanced integrated circuits and emerging 2D-crystal devices. Here, we…

The fluid dynamics of the classical dewetting instability in ultrathin films is a non-linear process. However, the physical manifestation of the instability in terms of characteristic length and time scales can be described by a linearized…

材料科学 · 物理学 2015-05-13 N. Shirato , H. Krishna , R. Kalyanaraman

When a liquid film lies on a non-wettable substrate, the configuration is unstable and the film then retracts from a solid substrate to form droplets. This phenomenon, known as dewetting, commonly leads to undesirable morphological changes.…

An experimental investigation is reported on the effect of shear on the bursting of molten ultra-thin polymer films embedded in an immiscible matrix. By using an optical microscope coupled with a shearing hotstage, the dewetting dynamics,…

软凝聚态物质 · 物理学 2022-03-15 Anna Dmochowska , Jorge Peixinho , Cyrille Sollogoub , Guillaume Miquelard-Garnier

Ultrathin polymer films that are produced e.g. by spin-coating are believed to be stressed since polymers are 'frozen in' into out-of-equilibrium configurations during this process. In the framework of a viscoelastic thin film model, we…

软凝聚态物质 · 物理学 2011-03-01 Falko Ziebert , Elie Raphael

We study the deformation and dewetting of liquid films under impinging gas jets using experimental, analytical and numerical techniques. We first derive a reduced-order model (a thin-film equation) based on the long-wave assumption and on…

流体动力学 · 物理学 2020-12-02 C. J. Ojiako , R. Cimpeanu , H. Bandulasena , R. Smith , D. Tseluiko

Sub-100 nm polymeric spherical plano-convex nano-lens arrays are fabricated using short electron beam exposures to selectively modify the ultrathin (< 30 nm) polymer films, followed by their intensified self-organized dewetting under an…

软凝聚态物质 · 物理学 2011-09-20 Ankur Verma , Ashutosh Sharma

Solid-state dewetting is the process by which thin solid films break up and retract on a substrate, forming nanostructures. While dewetting of single-crystalline films is understood as a surface-energy-driven process mediated by surface…

In this paper we present a theoretical model for the dewetting of ultra-thin polymer films. Assumming that the shear-thinning properties of these films can be described by a Cross-type constitutive equation, we analyze the front morphology…

软凝聚态物质 · 物理学 2009-11-07 F. Saulnier , E. Raphael , P. -G. de Gennes

A mathematical model is developed to analyze the growth/decay rate of surface perturbations of an ultrathin metal film on an amorphous substrate (SiO_{2}). The formulation combines the approach of Mullins [J. Appl. Phys. v30, 77, 1959] for…

材料科学 · 物理学 2015-06-25 Christopher Favazza , Ramki Kalyanaraman , Radhakrishna Sureshkumar

The advances in new technologies have prompted the need for functional systems smaller than the gyration radius of polymer chains. Thus, understanding how nanoconfinement affects polymer properties has been the focus of a lot of research…

软凝聚态物质 · 物理学 2010-07-27 Fabrice Cousin , Jérémie Gummel , Daniel Clemens , Isabelle Grillo , François Boué

Hydrodynamic pattern formation (PF) and dewetting resulting from pulsed laser induced melting of nanoscopic metal films have been used to create spatially ordered metal nanoparticle arrays with monomodal size distribution on…

Thin films and van der Waals heterostructures derived from two-dimensional solids offer enormous potential for a broad range of novel, energy efficient devices, however, their use is currently hampered by slow, labor-intensive fabrication…

Dewetting of ultra-thin polymer films near the glass transition exhibits unexpected front morphologies [G. Reiter, Phys. Rev. Lett., 87, 186101 (2001)]. We present here the first theoretical attempt to understand these features, focusing on…

软凝聚态物质 · 物理学 2009-11-07 F. Saulnier , E. Raphael , P. -G. de Gennes
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