相关论文: Coherent Control of Vibrational State Population i…
An analytical theory is developed for radiationless transitions in molecules characterized by nonequilibrium populations of their vibrational modes. Several changes to the standard transition-state framework follow from nonequilibrium…
Coherent control over photoelectron wavepackets, via the use of polarization-shaped laser pulses, can be understood as a time and polarization-multiplexed process. In this work, we investigate this multiplexing via computation of the…
The cross-Kerr effect is studied for two pulses propagating in an atomic medium in a tripod configuration, dressed by a strong standing wave coupling beam. Nonlinear phase shifts for both transmitted and reflected beams are calculated…
Coherent population transfer between nuclear states using x-ray laser pulses is studied. The laser pulses drive two nuclear transitions between three nuclear states in a setup reminding of stimulated Raman adiabatic passage used for atomic…
A full set of vibrationally-resolved cross sections for electron impact excitation of NO(X2{\Pi}, v) molecules is calculated from ab initio molecular dynamics, in the framework of the local-complex-potential approach. Electron-vibration…
Experiments have shown that the internal vibrational state of a molecule can affect the intensity of high harmonic light generated from that molecule. This paper presents a model which explains this modulation in terms of interference…
Enantioselective photochemistry provides access to unique molecular structures and functions, with deep implications for fundamental science and industrial applications. Current methods for highly enantioselective photochemistry critically…
The soft character of organic materials leads to strong coupling between molecular nuclear and electronic dynamics. This coupling opens the way to control charge transport in organic electronic devices by inducing molecular vibrational…
We study the nonlinear and resonant process of two-photon ionization of atoms (He and H) in a pump-probe scheme. The pump pulse prepares the quantum system in a superposition of the ground state and an excited bound state. By varying the…
Vibrational polaritons, hybrid light-matter states formed between molecular vibrations and infrared (IR) cavity modes, provide a novel approach for modifying chemical reaction pathways and energy transfer processes. For vibrational…
There are two types of two-photon transitions in molecular aggregates, that is, non-local excitations of two monomers and local double excitations to some higher excited intra-monomer electronic state. As a consequence of the inter-monomer…
This theoretical paper presents numerical calculations for photoassociation of ultracold cesium atoms with a chirped laser pulse and detailed analysis of the results. In contrast with earlier work, the initial state is represented by a…
The methods producing cold molecules from cold atoms tend to leave molecular ensembles with substantial residual internal energy. For instance, Cs2 molecules initially formed via photoassociation of cold Cs atoms are in several vibrational…
The on-demand selective population transfer between states in multilevel quantum systems is a challenging problem with implications for a wide-range of physical platforms including photon and exciton-polariton Bose- Einstein condensates…
We investigate the dynamics of molecular photoexcitation by unchirped femtosecond laser pulses using RbCs as a model system. This study is motivated by a goal of optimizing a two-color scheme of transferring vibrationally-excited ultracold…
We evaluate the shifts imparted to vibrational and rotational levels of a linear molecule by a nonresonant laser field at intensities of up to 10^12 W/cm^2. Both types of shift are found to be either positive or negative, depending on the…
We study the population transfer between resonance states for a time-dependent loop around exceptional points in spectra of the hydrogen atom in parallel electric and magnetic fields. Exceptional points are well-suited for population…
We study quantum control techniques, specifically Adiabatic Rapid Passage (ARP) and Gradient Ascent Pulse Engineering (GRAPE), for transferring atoms trapped in an optical lattice between different vibrational states. We compare them with…
We present a model describing the use of ultra-short strong pulses to control the population of the excited level of a two-level quantum system. In particular, we study an off-resonance excitation with a few cycles pulse which presents a…
Coherent population trapping is shown to occur in a driven symmetric double-well potential in the strong-field regime. The system parameters have been chosen to reproduce the $0^{-}\leftrightarrow 3^{+}$ transition of the inversion mode of…